多面体齐聚倍半硅氧烷（POSS）具有特殊的笼状结构,可从纳米尺度上起到对聚合物的改性作用。通过不同的方法将POSS分子引入到聚合物体系中去,以改善聚合物性能是聚合物改性的重要手段之一。文中从聚合方式上对含POSS聚合物的制备进行介绍,包括传统自由基聚合、活性聚合、缩聚聚合和开环聚合,并对合成的含POSS有机/无机聚合物的性能进行相关介绍。
In the last decade,polyhedral oligomeric silsesquioxanes（POSS） as an organicinorganic hybrid nano-phase material has got an increasing attention.As a special kind of modification agent with a cage-like structure,it can improve the properties of polymers greatly from a nano scale.So far,POSS could be easily introduced into the polymer system via different methods,such as copolymerization,grafting polymerization,cross-linking and so on.This review focused on the preparation process of POSS-containing polymers via copolymerization,which includes free radical polymerization,living polymerization,condensation polymerization and ring opening polymerization etc.Besides,the properties of POSS-containing polymers were discussed in this article.
参考文献
| [1] | 田丰,刘长军,高万玉,张彦军.分子内杂化纳米结构体多面体低聚倍半硅氧烷研究进展[J].高分子材料科学与工程,2007(04):24-28. |
| [2] | 何辉,袭锴,葛仁杰,贾叙东,余学海,陈庆民.笼型倍半硅氧烷（POSS）的合成及应用进展[J].高分子材料科学与工程,2008(04):5-9. |
| [3] | 王冠海,张黎明,何富安,陈旭东,祝方明,伍青.含多面低聚倍半硅氧烷新型杂化聚合物的合成[J].化学进展,2006(04):453-458. |
| [4] | Bizet S;Galy J;Gerard JF .Molecular dynamics simulation of organic-inorganic copolymers based on methacryl-POSS and methyl methacrylate[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(24):8219-8227. |
| [5] | Stephane Bizet;Jocelyne Galy;Jean-Francois Gerard .Structure-Property Relationships in Organic-Inorganic Nanomaterials Based on Methacryl-POSS and Dimethacrylate Networks[J].Macromolecules,2006(7):2574-2583. |
| [6] | Kohji Ohno;Satoshi Sugiyama;Kyoungmoo Koh .Living Radical Polymerization by Polyhedral Oligomeric Silsesquioxane-Holding Initiators: Precision Synthesis of Tadpole-Shaped Organic/Inorganic Hybrid Polymers[J].Macromolecules,2004(23):8517-8522. |
| [7] | 刘磊,王文平,揭晓晓,曹恒明,费明.星型POSS/PMMA复合材料的ATRP合成及其热性能研究[J].高分子学报,2010(01):10-14. |
| [8] | Hussain, H.;Tan, B.H.;Seah, G.L.;Liu, Y.;He, C.B.;Davis, T.P. .Micelle formation and gelation of (PEG-P(MA-POSS)) amphiphilic block copolymers via associative hydrophobic effects[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(14):11763-11773. |
| [9] | Zhang WA;Liu L;Zhuang XD;Li XH;Bai JR;Chen Y .Synthesis and Self-Assembly of Tadpole-Shaped Organic/Inorganic Hybrid Poly(N-isopropylacrylamide) Containing Polyhedral Oligomeric Silsesquioxane via RAFT Polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2008(21):7049-7061. |
| [10] | Tamaki R.;Choi JW.;Laine RM. .A polyimide nanocomposite from octa(aminophenyl)silsesquioxane[J].Chemistry of Materials,2003(3):793-797. |
| [11] | Choi JW.;Tamaki R.;Kim SG.;Laine RM. .Organic/inorganic imide nanocomposites from aminophenylsilsesquioxanes[J].Chemistry of Materials,2003(17):3365-3375. |
| [12] | Liu YH;Ni Y;Zheng SX .Polyurethane networks modified with octa(propylglycidyl ether) polyhedral oligomeric silsesquioxane[J].Macromolecular chemistry and physics,2006(20):1842-1851. |
| [13] | Zeng, K;Wang, L;Zheng, SX;Qian, XF .Self-assembly behavior of hepta(3,3,3-trifluoropropyl) polyhedral oligomeric silsesquioxane-capped poly(epsilon-caprolactone) in epoxy resin: Nanostructures and surface properties[J].Polymer,2009(2):685-695. |
| [14] | Ni Y;Zheng SX .Nanostructured thermosets from epoxy resin and an organic-inorganic amphiphile[J].Macromolecules,2007(19):7009-7018. |
| [15] | Yonghong Liu;Xingtian Yang;Weian Zhang .Star-shaped poly(epsilon-caprolactone)with polyhedral oligomeric silsesquioxane core[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(19):6814-6825. |
| [16] | Jong Hyun Lee;Young Gyu Jeong .Preparation and Characterization of Nanocomposites Based on Polylactides Tethered with Polyhedral Oligomeric Silsesquioxane[J].Journal of Applied Polymer Science,2010(2):1039-1046. |
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