运用拉伸、冲击、SEM、TEM和EDS等测试方法,对添加稀土镧和未添加稀土镧的Nb—Ti—Mo系管线钢进行研究,分析稀土元素和卷取温度对组织和性能的影响。结果表明:稀土元素镧能有效的改善夹杂物的形貌,在铸坯中形成由Al、Mn、O、S、La组成的复合夹杂物,并最终提高管线钢的低温冲击韧性;两种管线钢的强度均随着卷取温度的降低而升高,且添加稀土镧的Nb—Ti-Mo系管线钢的强度上升趋势更为显著;并且镧能够提高管线钢低温卷取时获得板条贝氏体的能力,精细结构中观察到有200—900nm的亚板条结构,M/A组元中马氏体为孪晶结构。
Nb-Ti-Mo pipeline steels with or without La addition were fabricated. Effects of rare earth La and coiling temperature on microstructure and mechanical properties of the steels were investigated by means of TEM, SEM and EDS analysis, and tensile and impact tests. The results show that the morphology of inclusions in the La-added steel is effectively refined and spherical complex inclusions of A1, Mn, O and S containing La are formed, which improves the low-temperture impact toughness of the steels. With the decreasing of the coiling temperature, strength of both steels with and without La increases, but the trend of the steel with La is more obvious. The addition of lanthanum can improve the formation of lath bainite for the steel at lower coiling temperature. Sub-lath structure of 200 - 900 nm is observed in the fine structure, and M/A components have the twin martensite structure.
参考文献
[1] | 杜则裕 .高强度管线钢X100的研究进展[J].焊接技术,2006,35(S):1-3. |
[2] | 潘家华.全球能源变换及管线钢的发展趋势[J].焊管,2008(01):9-11. |
[3] | 王龙妹.稀土元素在新一代高强韧钢中的作用和应用前景[J].中国稀土学报,2004(01):48-54. |
[4] | 刘晓,杨吉春,高学中.稀土对2Cr13不锈钢夹杂物的变质及对冲击韧性的影响[J].北京科技大学学报,2010(05):605-609. |
[5] | 张芳,杨吉春,刘亚辉.镧提高SS400钢力学性能作用机理研究[J].稀土,2009(05):44-49. |
[6] | 肖寄光,程慧静,王福明.稀土对船板钢组织及低温韧性的影响[J].稀土,2010(05):52-58. |
[7] | 孙昊,计云萍,陈林.稀土Ce对X65管线钢组织和性能的影响[J].过程工程学报,2010(02):240-244. |
[8] | 郭锋,林勤,孙学义.镧、磷在稀土碳锰纯净钢凝固过程中的偏析和相互作用[J].中国稀土学报,2004(z1):51-54. |
[9] | 陈冬火,林勤,郭锋,高平祥,王跃华,万恒瑜.高镧稀土添加剂在16Mn钢中的应用[J].北京科技大学学报,2004(06):600-603. |
[10] | 崔约贤;王长利.金属断口分析[M].哈尔滨:哈尔滨工业大学出版社,1998 |
[11] | Hong L L;ChengJ L;Mao FJ .Effect of rare earths on impact toughness of a low-carbon steel[J].Materials & Design,2011,5(33):306-312. |
[12] | 杜挺;韩其勇;王常珍.稀土碱土等元素的物理化学及在材料中的应用[M].北京:科学出版社,1995 |
[13] | 梁益龙,雷旻,陈伦军,张晓燕,高宏.稀土对GDL-1型贝氏体钢的显微组织及力学性能的影响[J].材料热处理学报,2006(06):95-98. |
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