欢迎登录材料期刊网

材料期刊网

高级检索

利用射频等离子体增强化学气相沉积(RF-PECVD)技术,以B2H6为掺杂剂,在玻璃衬底上制备了厚度为40nm左右的p型微晶硅薄膜.为获得高电导率高晶化率的薄膜,采用正交实验法对衬底温度、氢稀释比及硼烷掺杂比等主要沉积参数进行初步优化.Raman光谱和电导率测试结果表明:(1)在实验选取的参数范围内,衬底温度是影响薄膜暗电导率和晶化率的最主要因素,其次是氢稀释比,硼烷掺杂比的影响相对较小;(2)通过正交优化,获得了暗电导率为2.05S·cm-1、晶化率为86%的p型微晶硅薄膜.

参考文献

[1] 汪昌州,杨仕娥,卢景霄.硅基薄膜太阳电池窗口材料的研究进展[J].材料导报,2007(01):14-17.
[2] Das D;Jana M .Development of highly conducting p-type μc-Si:H films from minor diborane doping in highly hydrogenated SiH4plasma[J].Materials Letters,2004,58:980.
[3] Hou GF;Xue JM;Guo QC;Sun J;Zhao Y;Geng XH;Li YG .Formation mechanism of incubation layers in the initial stage of microcrystalline silicon growth by PECVD[J].Chinese physics,2007(2):553-557.
[4] 侯国付,薛俊明,袁育杰,张德坤,孙建,张建军,赵颖,耿新华.采用高压RF-PECVD法制备高电导、高晶化率的p型微晶硅材料[J].人工晶体学报,2007(01):85-88.
[5] 汪昌州,杨仕娥,陈永生,杨根,郜小勇,卢景霄.硼掺杂对μc-Si:H薄膜微结构和光电性能的影响[J].人工晶体学报,2007(01):123-128.
[6] Voz C.;Bertomeu J.;Soler D.;Fonrodona M.;Andreu J.;Peiro D. .Optimisation of doped microcrystalline silicon films deposited at very low temperatures by hot-wire CVD[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2000(0):278-283.
[7] Droz C;Vallat-Sauvain E;Bailat J.[A].Munich,Germany,2001:2917.
[8] Pankove J I;Carlson D E;Berkeyheiser J E et al.Neutralization of shallow acceptor levels in silicon by atomic hydrogen[J].Physical Review Letters,1983,51:2224.
[9] Deleo G G;Fowler W B .Hydrogen-acceptor pairs in silicon:silicon:Pairing effect on the hydrogen vibrational frequency[J].Physical Review B,1985,31:6861.
[10] Chang K J;Chadi D J .Theory of hydrogen passivation of shallow-level dopants in crystalline silicon[J].Physical Review Letters,1988,60:1422.
[11] Filonovich SA;Ribeiro M;Rolo AG;Alpulm P .Phosphorous and boron doping of nc-Si : H thin films deposited on plastic substrates at 150 degrees C by Hot-Wire Chemical Vapor Deposition[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(5):576-579.
[12] Kondo M.;Fujiwara H.;Matsuda A. .Fundamental aspects of low-temperature growth of microcrystalline silicon[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):130-134.
[13] Dewarrat R.;Robertson J. .Surface diffusion of SiH3 radicals and growth mechanism of a-Si : H and microcrystalline Si[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):11-15.
[14] Chen H;Gullanar M H;Shen W Z .Effects of high hydrogen dilution on the optical and electrical properties in B-doped nc-Si:H thin films[J].Journal of Crystal Growth,2004,260:91.
[15] Kitagawa T.;Matsuda A.;Kondo M. .In situ observation of low temperature growth of crystalline silicon using reflection high-energy electron diffraction[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2000(Pt.A):64-68.
[16] Hay P. Jeffrey;Kress Joel D.;Martin Richard L.;Boehm Randall C. .Theoretical studies of H2 desorption processes in chemical vapor deposition of boron-doped silicon surfaces[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,1999(1/3):175-192.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%