分别采用碱(NaOH)处理、异氰酸酯(MDI)处理以及NaOH+MDI处理的界面调控方法对竹纤维/聚乳酸复合材料界面进行调控.结果表明,3种界面调控均改善了竹纤维/聚乳酸复合材料界面粘接性能、拉伸强度、冲击强度和防水性能；界面调控后,复合材料的粘流活化能增加,而热流动性因竹纤维与聚乳酸交联变得困难；复合材料玻璃转化温度和结晶温度升高,熔融峰变窄；复合材料热降解温度升高,热稳定性增加.NaOH+MDI联合对竹纤维/聚乳酸复合材料界面调控效果最好,对复合材料的性能影响最显著.
参考文献
| [1] | Mohanty A K;Misra M;Hinrichsen G .Biofibers,biodegradable polymers and biocomposites:an overview[J].Macromolecular Materials and Engineering,9000,276:1-24. |
| [2] | Elisa Zini;Massimo Baiardo;Lidia Armelao;Mariastella Scandola .Biodegradable Polyesters Reinforced with Surface-Modified Vegetable Fibers[J].Macromolecular bioscience,2004(3):286-295. |
| [3] | Puglia D;Tomassucci A;Kenny J M .Processing,properties and stability of biodegradable composites based on Mater-Biw and cellulose fibres[J].Polymers For Advanced Technologies,2003,14:749-756. |
| [4] | Ohkita T;Lee SH .Crystallization behavior of poly(butylene succinate)/corn starch biodegradable composite[J].Journal of Applied Polymer Science,2005(3):1107-1114. |
| [5] | Seung-Hwan Lee;Tsutomu Ohkita;Kazuo Kitagawa .Eco-composite from poly(lactic acid) and bamboo fiber[J].Holzforschung,2004(5):529-536. |
| [6] | 曹勇,柴田 信一.甘蔗渣的碱处理对其纤维增强全降解复合材料的影响[J].复合材料学报,2006(03):60-66. |
| [7] | 华晋,赵志敏,余伟,王田虎.聚乳酸/木粉复合材料的力学及吸水性能研究[J].功能材料,2011(10):1762-1764,1767. |
| [8] | Shibata M;Ozawa K;Teramoto N et al.Biocomposites made from short abaca fiber and biodegradable polyester[J].Macromolecular Materials and Engineering,2003,288:35-43. |
| [9] | Luo S;Netravali A N .Interfacial and mechanical properties of environment-friendly ' green' composites made from pineapple fibers and poly(hydyoxybutyrate co-valerate) resin[J].Journal of Materials Science,1999,34:3709-3719. |
| [10] | B.S. Ndazi;S. Karlsson;J.V. Tesha .Chemical and physical modifications of rice husks for use as composite panels[J].Composites, Part A. Applied science and manufacturing,2007(3):925-935. |
| [11] | Ohkita T;Lee SH .Thermal degradation and biodegradability of poly (lactic acid)/corn starch biocomposites[J].Journal of Applied Polymer Science,2006(4):3009-3017. |
| [12] | Xun Lu;Ming Qiu Zhang;Min Zhi Rong .Self-reinforced melt processable composites of sisal[J].Composites science and technology,2003(2):177-186. |
| [13] | Mohanty A K;Khan M A;Hinrichsen G .Influence of chemical surface modification on the properties of biode gradable jute fabrics-polyester amide composite[J].Composites Part A:Applied Science and Manufacturing,2000,31:143-150. |
| [14] | E.T.N.BISANDA .The Effect of Alkali Treatment on the Adhesion Characteristics of Sisal Fibres[J].Applied composite materials,2000(5/6):331-339. |
| [15] | Y. Cao;S. Shibata;I. Fukumoto .Mechanical properties of biodegradable composites reinforced with bagasse fibre before and after alkali treatments[J].Composites, Part A. Applied science and manufacturing,2006(3):423-429. |
| [16] | A. A. Yussuf;I. Massoumi;A. Hassan .Comparison of Polylactic Acid/Kenaf and Polylactic Acid/Rise Husk Composites: The Influence of the Natural Fibers on the Mechanical, Thermal and Biodegradability Properties[J].Journal of polymers and the environment,2010(3):422-429. |
| [17] | Takashi Nishino;Koichi Hirao;Masaru Kotera .Kenaf reinforced biodegradable composite[J].Composites science and technology,2003(9):1281-1286. |
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