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聚苯胺(PANI)作为一种导电聚合物,具有良好的环境稳定性、易制备和应用广泛等特征,在不同领域备受关注.但由于PANI分子链上具有刚性骨架,分子间相互作用力大,导致其溶解、加工性能差,限制了聚苯胺的实际应用价值.本文主要探讨了PANI的化学改性方法,包括不同类型酸掺杂、聚苯胺磺化、共聚改性、柔性烷基链掺杂聚苯胺改性等,改善PANI的溶解性能和加工性能,拓宽PANI的应用领域,并提出聚苯胺化学改性的主要研究方向.

参考文献

[1] 康先进,范文玉,张彦英,钱余海,严川伟,孙超,宫骏.聚苯胺长效防腐水性环保涂料的研制及性能研究[J].中国腐蚀与防护学报,2012(05):393-396.
[2] 赵瑞瑞,朱利敏,钱江锋,杨汉西.苯胺-邻硝基苯胺共聚物--高比容量锂二次电池新型正极材料[J].电化学,2012(04):310-313.
[3] 王莎莎,芦姗,苏佳,郭正凯,李学敏,张雪华,何声太,贺涛.聚合时间对染料敏化太阳能电池中聚苯胺对电极结构和性能的影响[J].物理化学学报,2013(03):516-524.
[4] 王晓峰,尤政,阮殿波.聚苯胺在电化学电容器中的应用[J].化学物理学报,2005(04):635-640.
[5] 姜亚南,王鸿博,万玉芹,高卫东.PANI-HCl/PAN电磁屏蔽纳米纤维膜的制备与表征[J].化工新型材料,2013(07):122-124,130.
[6] 孙通,李晓霞,郭宇翔,赵纪金,马森,赵楠.不同酸掺杂聚苯胺的电化学聚合及性能[J].化工进展,2013(08):1870-1875.
[7] Saini P;Jalan R;Dhawan SK .Synthesis and characterization of processable polyaniline doped with novel dopant NaSIPA[J].Journal of Applied Polymer Science,2008(3):1437-1446.
[8] Moon HS.;Park JK. .Structural effect of polymeric acid dopants on the characteristics of doped polyaniline composites: Effect of hydrogen bonding[J].Journal of Polymer Science, Part A. Polymer Chemistry,1998(9):1431-1439.
[9] 李晶,郑敏刚,陈昶,隆泉,郑保忠.层层自组装制备PANI/CuTsPc复合薄膜及其性能研究[J].功能材料,2009(07):1115-1118.
[10] 李斌,柯强,彭晓峰,舒炼,王力明.水溶性磺化聚苯胺的合成研究[J].广州化工,2011(05):4-5,22.
[11] Moon HS.;Park JK. .Structural effect of polymeric acid dopants on the characteristics of doped polyaniline composites: Effect of hydrogen bonding[J].Journal of Polymer Science, Part A. Polymer Chemistry,1998(9):1431-1439.
[12] Yang, Y.;Min, Y.;Wu, J.-C.;Hansford, D.J.;Feinberg, S.E.;Epstein, A.J. .Synthesis and characterization of cytocompatible sulfonated polyanilines[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2011(12):887-892.
[13] Bhadra, S.;Kim, N.H.;Lee, J.H. .Synthesis of water soluble sulfonated polyaniline and determination of crystal structure[J].Journal of Applied Polymer Science,2010(4):2025-2035.
[14] 马利,汤琪.共聚态聚苯胺的合成及性能[J].高分子材料科学与工程,2003(06):76-79.
[15] Masdarolomoor F;Innis PC;Ashraf S;Kaner RB;Wallace GG .Nanocomposites of polyaniline/poly(2-methoxyaniline-5-sulfonic acid)[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(23):1995-2000.
[16] 马会茹,官建国,柳娜,卢国军,袁润章.PEG链段对聚乙二醇接枝聚苯胺结构与性能的影响[J].高分子学报,2006(01):92-96.
[17] 黄美荣,桂运能,李新贵.聚(N-烷基苯胺)膜的制备技术及性能与应用[J].电子元件与材料,2007(06):13-16.
[18] Chen SA.;Hwang GW. .WATER-SOLUBLE SELF-ACID-DOPED CONDUCTING POLYANILINE - STRUCTURE AND PROPERTIES[J].Journal of the American Chemical Society,1995(40):10055-10062.
[19] Massoumi, B.;Abdollahi, M.;Shabestari, S.J.;Entezami, A.A. .Preparation and characterization of polyaniline N-grafted with poly(ethyl acrylate) synthesized via atom transfer radical polymerization[J].Journal of Applied Polymer Science,2013(1):47-53.
[20] Hatamzadeh, M.;Mahyar, A.;Jaymand, M. .Chemical modification of polyaniline by N-grafting of polystyrenic chains synthesized via nitroxide-mediated polymerization[J].Journal of the Brazilian Chemical Society,2012(6):1008-1017.
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