对3.5%NaCl溶液中新型含钪Al-Mg-Cu合金的应力腐蚀开裂宏观性能进行测试,并对裂纹尖端的成分与微观形貌进行分析.根据线弹性断裂力学理论,预制疲劳裂纹试样裂纹尖端处于平面应变状态,得到裂纹匀速扩展时的扩展速率、裂纹尖端应力强度因子以及应力腐蚀开裂强度因子的门槛值.扫描电镜及EDS分析表明:应力腐蚀开裂主要是沿晶扩展,预制裂纹与腐蚀介质中的溶解氧生成Al2O3,产生楔入力促使裂纹扩展;裂纹尖端基体主要发生阳极溶解反应,腐蚀产物以氯化铝为主.
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