合成了4-[对-(N-正丁基-N-苯基)苯胺基]-2,2′:6′,2″-三联吡啶钌配合物{[Ru(L)2](PF6)2},利用电化学沉积法在0.1mol/L Bu4 NClO4/CH3CN溶液中制备了导电聚[Ru(L)2]2+膜,并用SEM表征了膜的形貌.交流阻抗谱研究表明,聚合物膜的厚度随扫描圈数的增加而增大,光谱电化学方法研究表明聚[Ru(L)2]2+膜处于中性态是红色而在完全氧化态则几乎无色.研究了聚合物膜的电致变色性质,表明聚[Ru(L)2]2+膜是一种具有潜在应用价值的电致变色材料.
参考文献
| [1] | Helmut W. Heuer;Rolf Wehrmann;Stephan Kirchmeyer .Electrochromic Window Based on Conducting Poly(3,4-ethylenedioxythiophene)-Poly(styrene sulfonate)[J].Advanced Functional Materials,2002(2):89-94. |
| [2] | 傅相锴,罗伟.电子墨水技术的研究进展[J].功能材料,2005(10):1477-1481. |
| [3] | Mortimer RJ;Dyer AL;Reynolds JR .Electrochromic organic and polymeric materials for display applications[J].Displays: Technology and Applications,2006(1):2-18. |
| [4] | Heinig N F;Kharbanda N;Pynenburg M R .The growth of nickel nanoparticles on conductive polymer composite electrodes[J].Materials Letters,2008,62(15):2285. |
| [5] | Jens Peter Hermes;Meinhard Knoll .Doping front migration in intrinsically conductive polymers and its application[J].Electrochimica Acta,2009(17):4258-4261. |
| [6] | Tsirimpis, A;Kartsonakis, I;Danilidis, I;Liatsi, P;Kordas, G .Synthesis of conductive polymeric composite coatings for corrosion protection applications[J].Progress in Organic Coatings: An International Review Journal,2010(4):389-397. |
| [7] | 马慧荣,李梅,徐清钢,姚金水.导电聚吡咯的研究进展[J].山东轻工业学院学报（自然科学版）,2011(01):14-18. |
| [8] | Angelopoulos M;Astunas G E;Emer S P et al.Polyaniline solution,film and oxidation state[J].Molecular Crystals,1988,160(01):151. |
| [9] | Qiu, DF;Cheng, YX;Wang, LX .Oligoaniline-Functionalized terpyridine ligands and their ruthenium(II) complexes: synthesis, spectroscopic property and redox behaviors[J].Dalton transactions: An international journal of inorganic chemistry,2009(17):3247-3261. |
| [10] | 陈丽娴,卢彦婷,翁少煌,周剑章,林仲华.固态聚苯胺电致变色器件的制备和性能[J].高等学校化学学报,2009(03):557-562. |
| [11] | Dong, B;Xu, JK;Zheng, LQ;Hou, J .Electrode position of conductive poly(3-methoxythiophene) in ionic liquid microemulsions[J].Journal of Electroanalytical Chemistry,2009(1/2):60-66. |
| [12] | Qiu D F;Zhao Q;Bao X Y et al.Electropolyrnerization and characterization of an alternatively conjugated donoracceptor metallopolymer:Poly-[Ru (4′-(4-(Diphenylamino)phenyl)-2,2′:6′,2"-Terpyridine) 2]2+[J].Inorganic Chemistry Communications,2011,14(01):296. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%