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  4. 稀土镁基AB3型贮氢电极合金的研究进展

材料导报, 2005, 19(10): 107-112.

稀土镁基AB3型贮氢电极合金的研究进展

周增林 1, , 宋月清 2, , 崔舜 3,

1.北京有色金属研究总院粉末冶金及特种材料研究所,北京,100088

2.北京有色金属研究总院粉末冶金及特种材料研究所,北京,100088

3.北京有色金属研究总院粉末冶金及特种材料研究所,北京,100088

关键词： AB3型贮氢合金 , 稀土 , 镁

Development of Rare-earth Mg-based AB3-type Hydrogen-storage Electrode Alloys

综述了稀土镁基AB3型贮氢电极合金的研究进展.分别从合金结构、热力学、成分及制备方法等方面进行总结,认识到循环稳定性差是AB3型贮氢电极合金目前存在的最主要问题,并就如何改善合金循环稳定性的问题进行了讨论.稀土镁基AB3型贮氢合金的贮氢量高于传统的稀土基AB5型贮氢合金,有望成为新一代的贮氢电极合金材料.

参考文献

[1] Sakai T;Miyamura H;Kuriyama N et al.Metal hydride anodes for nickel-hydrogen secondary battery[J].Journal of the Electrochemical Society,1990,137:795.
[2] Feng F;Geng M;Northwood D;Oa review .Electrochemical behaviour of intermetallic-based metal hydrides used in Ni/metal hydride MH batteries[J].International Journal of Hydrogen Energy,2001,26:725.
[3] 雷永泉;万群;石定康.新能源材料[M].天津:天津大学出版社,2000:52.
[4] Kadir K;Sakai T;Uehara I .Synthesis and structure determination of a new series of hydrogen storage alloys; RMg2 Ni9 R= La, Ce, Pr, Nd, Sm and Gd built form MgNi2 Lavestype layers alternating with AB5 layers[J].Journal of Alloys and Compounds,1997,257:115.
[5] Kohno T.;Yoshida H. .Hydrogen storage properties of new ternary system alloys: La_2MgNi_9, La_5Mg_2Ni_(23), La_3MgNi_(14)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(2):L5-L7.
[6] Kadir K;Sakai T;Uehara I .Structural investigation and hydrogen storage capacity of LaMg2Ni9 and La0.65 Ca0.35 Mg1.32 Ca0. 68 Ni9 of the AB2C9 type structure[J].Journal of Alloys and Compounds,2000,302:112.
[7] Chen J;Takeshita H T;Tanaka H et al.Hydriding properties of LaNi3 and CaNi3 and their substitutes with PuNi3-type structure[J].Journal of Alloys and Compounds,2000,302:304.
[8] Liao B;Lei Y Q et al.Effect of the La/Mg ratio on the structure and electrochemical properties of Lax Mg3-x Ni9 x= 1.6 ～ 2.2 hydrogen storage electrode alloys for nickelmetal hydride batteries[J].Journal of Power Sources,2004,129:358.
[9] Tang R;Liu L Q et al.Study on the microstructure and the electrochemical properties of Ml0.7 Mg0. 2 Ni2. 8 Co0. 6 hydrogen storage alloy[J].International Journal of Hydrogen Energy,2003,28:815.
[10] 刘永锋,应窕,潘洪革.新型稀土镁基贮氢电极合金的结构与性能[J].材料研究学报,2003(04):380-388.
[11] 唐睿,张朝晖,刘丽琴,朱杰武,柳永宁.La1.3CaMg0.7Ni9储氢合金[J].中国有色金属学报,2004(01):51-54.
[12] Liang J;Ma X F;Tang J K et al.Formation and structure of LaNi2 intermetallic compound under high pressure[J].Intermetallics,2003,11:875.
[13] Kadir K;Kuriyama N;Sakai T et al.Structural investigation and hydrogen capacity of CaMg2 Ni9: a new phase in the AB2C9 system isostructural with LaMg2 Ni9[J].Journal of Alloys and Compounds,1999,284:145.
[14] Kadir K;Sakai T;Uehara I .Structural investigation and hydrogen capacity of YMg2Ni9 and Y0. 5 Ca0. 5 MgCa Ni9 :new phase in the AB2C9 system isostructural with LaMg2Ni9[J].Journal of Alloys and Compounds,1999,287:264.
[15] Liao B;Lei Y Q;Lu G L et al.The electrochemical properties of LaxMg3-xNi9 x= 1. 0～2. 0 hydrogen storage alloys[J].Journal of Alloys and Compounds,2003,356-357:746.
[16] Pan H G;Jin Q W;Gao M X et al.An electrochemical study of La0.4 Ce0. 3 Mg0. 3 Ni2.975- x Mnx Co0. 525 x= 0. 1 ～ 0. 4 hydrogen storage alloys[J].Journal of Alloys and Compounds,2004,376:196.
[17] Pan H G;Jin Q W;Gao M X et al.Effect of the cerium content on the structural and electrochemical properties of the La0.7-xCexMg0. 3 Ni2. 875 Mn0.1 Co0. 525 x= 0～0. 5 hydrogen storage alloys[J].Journal of Alloys and Compounds,2004,373:237.
[18] Liu Y F;Pan H G;Gao M X et al.Effect of Co content on the structural and electrochemical properties of the La0. 7Mg0. 3Ni3. 4-xMn0.1Cox hydride alloys Ⅰ: the structure and hydrogen storage[J].Journal of Alloys and Compounds,2004,376:296.
[19] Liu Y F;Pan H G;Gao M X et al.Effect of Co content on the structural and electrochemical properties of the La0. 7 Mg0. 3 Ni3. 4-x Mn0. 1 Cox hydride alloys Ⅱ: Electrochemical properties[J].Journal of Alloys and Compounds,2004,376:304.
[20] Willems J J G .[J].Philips Journal of Research,1984,39(01):1.
[21] Liu Y F;Pan H G;Gao M X et al.The effect of Mn substitution for Ni on the structural and electrochemical properties of La0. 7 Mg0. 3 Ni2. 55-x Co0. 45 Mnx hydrogen storage electrode alloys[J].International Journal of Hydrogen Energy,2004,29:297.
[22] Liao B;Lei Y Q;Chen L X et al.A study on the structure and electrochemical properties of La2 Mg Ni0. 95 M0. 05 9 M =Co,Mn, Fe, Al, Cu, Sn hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2004,376:186.
[23] 廖彬,雷永泉,吕光烈,陈立新,葛红卫,潘洪革.La-Mg-Ni系AB3型贮氢电极合金的相结构与电化学性能[J].金属学报,2005(01):41-48.
[24] 刘永锋,潘洪革,高明霞,朱云峰,葛红卫,李寿权,雷永泉.稀土镁基贮氢电极合金的结构与电化学性能研究[J].金属学报,2003(06):666-672.
[25] Pan H G;Liu Y F;Wang Q D .An investigation on the structural and electrochemical properties of La0.7 Mg0. 3- Ni0. 85 Co0. 15 x x= 3.15 ～ 3.80 hydrogen storage electrode alloys[J].Journal of Alloys and Compounds,2003,351:228.
[26] Zhang Y H;Wang G Q;Dong X P et al.Investigation on the microstructure and electrochemical performances of La2 Mg Ni0. 85 Co0. 15 9 Bx x= 0 ～ 0.2 hydrogen storage electrode alloys prepared by casting and rapid quenching[J].Journal of Alloys and Compounds,2004,379:298.
[27] 张朝晖,唐睿,柳永宁.机械合金化在贮氢合金研究中的应用[J].电池,2004(01):62-63.
[28] 张海昌,墨伟,申元,杨化滨,周作祥,周杏弟.La0.7Mg0.3（Ni1-xCox）3.5 （0≤x≤0.5）储氢合金电化学性能[J].中国稀土学报,2004(05):712-714.
[29] 董小平,张羊换,王国清,王新林.La-Mg-Ni系贮氢合金的研究进展[J].金属功能材料,2004(06):29-34.
[30] 陈军;袁华堂.新能源材料[M].北京:化学工业出版社,2003:104.
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