分别采用无皂乳液聚合法和分步乳液聚合法,使用过硫酸钾(KPS)为引发剂、聚乙烯吡咯烷酮(PVP)为稳定剂、十二烷基硫酸钠(SDS)为乳化剂制得单分散PS微米球和纳米球.讨论了引发剂、稳定剂、乳化剂等因素对PS球粒径大小的影响.研究表明,在一定范围内随着KPS、PVP、SDS用量的增加,PS球粒径逐渐变小,而粒径分布不变.通过调整KPS、PVP、SDS的用量,可以在10～1000nm范围内实现PS球的可控制备.
参考文献
| [1] | Lei ZB;Xiao Y;Dang LQ;You WS;Hu GS;Zhang J .Nickel-catalyzed fabrication of SiO2, TiO2/graphitized carbon, and the resultant graphitized carbon with periodically macroporous structure[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(3):477-484. |
| [2] | Raimundo D S;Salcedo W J .[J].Phys Stat Sol (c) 1,2004,S1:S62-S65. |
| [3] | Li S;Zheng JT;Zhao Y;Liu Y .Preparation of a three-dimensional ordered macroporous titanium dioxide material with polystyrene colloid crystal as a template[J].Journal of Applied Polymer Science,2008(6):3903-3908. |
| [4] | Geun Seok Chai;In Sun Shin;Jong-Sung Yu .Synthesis of Ordered, Uniform, Macroporous Carbons with Mesoporous Walls Templated by Aggregates of Polystyrene Spheres and Silica Particles for Use as Catalyst Supports in Direct Methanol Fuel Cells[J].Advanced Materials,2004(22):2057-2061. |
| [5] | Zhiyong Wang;Nicholas S.Ergang;Mohammed A.Al-Daous;Andreas Stein .Synthesis and Characterization of Three-Dimensionally Ordered Macroporous Carbon/Titania Nanoparticle Composites[J].Chemistry of Materials,2005(26):6805-6813. |
| [6] | Sun J;Li YY;Dong H;Zhan P;Tang CJ;Zhu MW;Wang ZL .Fabrication and light-transmission properties of monolayer square symmetric colloidal crystals via controlled convective self-assembly on 1D grooves[J].Advanced Materials,2008(1):123-128. |
| [7] | Ou JL;Chang CP;Sung Y;Ou KL;Tseng CC;Ling HW;Ger MD .Uniform polystyrene microspheres decorated with noble metal nanoparticles formed without using extra reducing agent[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2007(1/3):36-41. |
| [8] | Fu M;Zhou J;Xiao QF;Li B;Zong RL;Chen W;Zhang J .ZnO nanosheets with ordered pore periodicity via colloidal crystal template assisted electrochemical deposition[J].Advanced Materials,2006(8):1001-1004. |
| [9] | Zhang J H;Chen Z;Wang Z L et al.[J].Materials Letters,2003,57:4466-4470. |
| [10] | Du X;He JH .Facile size-controllable syntheses of highly monodisperse polystyrene nano- and microspheres by polyvinylpyrrolidone-mediated emulsifier-free emulsion polymerization[J].Journal of Applied Polymer Science,2008(3):1755-1760. |
| [11] | Hu, XF;Zhang, JY;Yang, WT .Preparation of transparent polystyrene nano-latexes by an UV-induced routine emulsion polymerization[J].Polymer,2009(1):141-147. |
| [12] | Ge HL;Song YL;Jiang L;Zhu DB .One-step preparation of polystyrene colloidal crystal films with structural colors and high hydrophobicity[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(4):1539-1543. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%