For thermodynamically and kinetically controlled catalytic reactions, the influence of a membrane is discussed. For reactions operating near to the thermodynamic equilibrium, the conversion can be increased if one/all of the products is/are selectively removed in an extractor type membrane reactor. Examples are esterifications, dehydrogenations, and water dissociation using water, hydrogen, and oxygen selective membranes, respectively. For kinetically controlled reactions, i.e. reactions with a very negative free enthalpy, mainly the selectivity can be increased via the control of the partial pressure of the educts by dosing effects using distributor/contactor membrane reactors. Examples are partial oxidations and hydrogenations. In detail, the application of an oxygen transporting perovskite hollow fiber membrane with a nano-designed grain boundary structure in the hydrogen production by thermal water splitting and in the partial oxidation of hydrocarbons as case studies for thermodynamically and kinetically controlled reactions is discussed.
参考文献
| [1] | Koros WJ.;Shimidzu T.;Ma YH. .TERMINOLOGY FOR MEMBRANES AND MEMBRANE PROCESSES[J].Pure and Applied Chemistry,1996(7):1479-1489. |
| [2] | Dittmeyer R;Caro J;Ertl G;Knozinger H,Schüth F,Weitkamp J.Handbook of Heterogeneous Catalysis[M].Wiley-VCH,2008 |
| [3] | Caro J;Noack M .[J].Microporous and Mesoporous Materials,2008,115:215. |
| [4] | Caro J;Noack M;Kolsch P .[J].Adsorption-Journal of the International Adsorption Society,2005,11:215. |
| [5] | Lai S M;Martin-Aranda R;Yeung K L.[J].Chemical Communications,2003(02):218. |
| [6] | Lai S M;Ng C P;Martin-Aranda R;Yeung K L .[J].Microporous and Mesoporous Materials,2003,66:239. |
| [7] | Zhang X F;Lai E S M;Martin-Aranda R;Yeung K L .[J].Applied Catalysis A:General,2004,261:109. |
| [8] | Yeung K L;Zhang X F;Lau W N;Martin-Aranda R .[J].Catalysis Today,2005,110:26. |
| [9] | Lau W N;Yeung K L;Zhang X F;Martin-Aranda R .[J].Studies in Surface Science and Catalysis,2007,170:1460. |
| [10] | Illgen U;Schafer R;Noack M;Kolsch P Kühnle A Caro J .[J].Catalysis Communications,2001,2:339. |
| [11] | Schfer R;Noack M;Kolsch P;Stohr M Caro J .[J].Catalysis Today,2003,82:15. |
| [12] | Ciavarella P;Casanave D;Moueddeb H;Miachon S Fiaty K Dalmon J-A .[J].Catalysis Today,2001,67:177. |
| [13] | Uemiya S .[J].Topics in Catalysis,2004,29:79. |
| [14] | Ferreira-Aparicio P;Benito M;Kouachi K;Menad S .[J].Journal of Catalysis,2005,231:33114. |
| [15] | Tong J;Matsumura Y .[J].Catalysis Today,2006,111:147. |
| [16] | Itoh N;Xu W C;Hara S;Kakehida K Kaneko Y Igarashi A .[J].Industrial and Engineering Chemistry Research,2003,42:6576. |
| [17] | Rei M H;Yeh G T;Pan C W .[J].Catalysis Today,2004,97:167. |
| [18] | Chen Y;Xu H;Wang Y;Xiong G .[J].Catalysis Today,2006,118:136. |
| [19] | Chen Y;Xu H;Wang Y;Xiong G .[J].Chinese Journal of Catalysis,2006,27:772. |
| [20] | Jiang H;Wang H H;Schiestel T;Werth S Caro J .[J].Angewandte Chemie,2008,120:9481. |
| [21] | Balachandran U;Lee T H;Wang S;Dorris S E .[J].International Journal of Hydrogen Energy,2004,29:291. |
| [22] | Balachandran U;Lee T H;Dorris S E .[J].International Journal of Hydrogen Energy,2007,32:4451. |
| [23] | Chen C S;Feng S J;Ran S;Zhu D C,Lin W,Bouwmeester H J M .[J].Angewandte Chemie International Edition,2003,42:5196. |
| [24] | Wang H H;Tablet C;Schiestel T;Werth S Caro J .[J].Catalysis Communications,2006,7:907. |
| [25] | Koh A;Chen L;Johnson B;Khimyak T,Leong W,Lin J.[A].新加坡,2005 |
| [26] | Schiestel T;Kilgus M;Peter S;Caspary K J Wang H H Caro J .[J].Journal of Membrane Science,2005,258:1. |
| [27] | Caro J;Caspary KJ;Hamel C;Hoting B;Kolsch P;Langanke B;Nassauer K;Schiestel T;Schmidt A;Schomacker R .Catalytic membrane reactors for partial oxidation using perovskite hollow fiber membranes and for partial hydrogenation using a catalytic membrane contactor[J].Industrial & Engineering Chemistry Research,2007(8):2286-2294. |
| [28] | Chen C S;Feng S J;Ran S;Zhu D C,Lin W,Bouwmeester H J M .[J].Angewandte Chemie International Edition,2003,42:5196. |
| [29] | Wang H H;Tablet C;Schiestel T;Werth S Caro J .[J].Catalysis Communications,2006,7:907. |
| [30] | Wang H H;Caro J;Werth S;Schiestel T .[J].Angewandte Chemie International Edition,2005,44:2. |
| [31] | Hamel C;Seidel-Morgenstern A;Schiestel T;Werth S Tablet C Caro J Wang H .[J].AICHE Journal,2006,52:3118. |
| [32] | Wang H H;Tablet C;Schiestel T;Caro J .[J].Catalysis Today,2006,118:98. |
| [33] | Wang H H;Cong Y;Yang W.[J].Chemical Communications,2002(14):1468. |
| [34] | Wang H H;Cong Y;Yang W .[J].Catalysis Letters,2002,84:101. |
| [35] | Rebeilleau M;van Veen A C;Farrusseng D;Rousset J Mirodatos C Shao Z Xiong G .[J].Studies in Surface Science and Catalysis,2004,147:655. |
| [36] | Rebeilleau M;Rosini S;van Veen A C;Farrusseng D Mirodatos C .[J].Catalysis Today,2005,104:131. |
| [37] | Akin FT.;Lin YS. .Selective oxidation of ethane to ethylene in a dense tubular membrane reactor[J].Journal of Membrane Science,2002(2):457-467. |
| [38] | Wang H H;Cong Y;Zhu X;Yang W .[J].Reaction Kinetics and Catalysis Letters,2003,79:351. |
| [39] | Wang H H;Tablet C;Schiestel T;Caro J .[J].Catalysis Today,2006,118:98. |
| [40] | Akin F T;Lin Y S .[J].Catalysis Letters,2002,78:239. |
| [41] | Lu Y;Dixon A G;Moser W R;Ma Y Balachandran U .[J].Catalysis Today,2000,56:297. |
| [42] | Wang H H;Cong Y;Zhu Y;Yang W .[J].Reaction Kinetics and Catalysis Letters,2003,79:351. |
| [43] | Wang H H;Tablet C;Caro J.[J].Journal of Membrane Science |
| [44] | Dyer PN.;Russek SL.;Taylor DM.;Richards RE. .Ion transport membrane technology for oxygen separation and syngas production[J].Solid state ionics,2000(1/2):21-33. |
| [45] | Wang H H;Cong Y;Yang W S .[J].Journal of Membrane Science,2002,210:259. |
| [46] | Tan X Y;Liu Y T;Li K .[J].AICHE Journal,2005,51:1991. |
| [47] | Liu SM;Gavalas GR .Oxygen selective ceramic hollow fiber membranes[J].Journal of Membrane Science,2005(1):103-108. |
| [48] | Van Hassel B A;Prasad R;Chen J;Lane J .[P].US 6*!565*!632,2003. |
| [49] | Armstrong P A;Bennet D L;Foster E P T;van Stein E E.Ceramic Membrane Development for Oxygen Supply to Gasification Applications[A].,2002 |
| [50] | Armstrong P A;Sorensen J;Foster E P T.ITM Oxygen: An Enabler for IGCC[A].,2003 |
| [51] | Armstrong P A;Bennet D L;Foster E P T;van Stein E E.ITM Oxygen for Gasification[A].,2004 |
| [52] | Bruun T.Design Issues for High Temperature Ceramic Membrane Reactors[A].Lahnstein,Germany,2004 |
| [53] | Vente JF;Haije WG;IJpelaan R;Rusting FT .On the full-scale module design of an air separation unit using mixed ionic electronic conducting membranes[J].Journal of Membrane Science,2006(1/2):66-71. |
| [54] | Tan X;Liu Y;Li K .[J].AICHE Journal,2005,51:1991. |
| [55] | Tan X;Liu Y;Li K .[J].Industrial and Engineering Chemistry Research,2005,44:61. |
| [56] | Liu S;Gavalas G R .[J].Journal of Membrane Science,2005,246:103. |
| [57] | Liu S;Gavalas G R .[J].Industrial and Engineering Chemistry Research,2005,44:7633. |
| [58] | Tong J H;Yang W S;Cai R;Zhu B C Lin L W .[J].Catalysis Letters,2002,78:129. |
| [59] | Schiestel T;Kilgus M;Peter S;Caspary K J Wang H H Caro J .[J].Journal of Membrane Science,2005,258:1. |
| [60] | Tablet C;Grubert G;Wang H H;Schiestel T Schroeder M Langanke B Caro J .[J].Catalysis Today,2005,104:126. |
| [61] | Caro J;Wang H H;Tablet C;Kleinert A Feldhoff A Schiestel T Kilgus M Kolsch P Werth S .[J].Catalysis Today,2006,118:128. |
| [62] | Martynczuk J;Arnold M;Wang H;Caro J;Feldhoff A .How (Ba0.5Sr0.5)(Fe0.8Zn0.2)O3-delta and (Ba0.5Sr0.5)(Co0.8Fe0.2)O3-delta perovskites form via an EDTA/citric acid complexing method[J].Advanced Materials,2007(16):2134-2140. |
| [63] | Caro J;Wang H H;Tablet C;Kleinert A Feldhoff A Schiestel T Kilgus M Kolsch P Werth S .[J].Catalysis Today,2006,118:128. |
| [64] | Arnold M;Martynczuk J;Efimov K;Wang H H Feldhoff A .[J].Journal of Membrane Science,2008,316:137. |
| [65] | Shao Z;Dong H;Xiong G;Cong Y Yang W .[J].Journal of Membrane Science,2001,183:181. |
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