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研究了乙烯-醋酸乙烯共聚物(EVA)/氢氧化镬(MH)无卤阻燃复合材料在光引发剂下的紫外光交联及其相关性能.采用凝胶含量测定、热延伸试验、UL-94垂直燃烧试验、极限氧指数、扫描电镜、热重分析、拉伸测试等表征了复合材料的交联度、阻燃性能、热性能和力学性能.凝胶含量和热延伸测试结果证明紫外光可以对复合材料快速交联.光照交联后,材料的拉伸强度得到明显提高,断裂伸长率略有下降;极限氧指数、热重分析、扫描电镜测试表明光交联的复合材料试样比未交联的试样具有更好的阻燃性能和热稳定性.

参考文献

[1] Shui-Yu Lu;Ian Hamerton .Recent developments in the chemistry of halogen-free flame retardant polymers[J].Progress in Polymer Science,2002(8):1661-1712.
[2] Ye, L.;Miao, Y.;Yan, H.;Li, Z.;Zhou, Y.;Liu, J.;Liu, H. .The synergistic effects of boroxo siloxanes with magnesium hydroxide in halogen-free flame retardant EVA/MH blends[J].Polymer Degradation and Stability,2013(4):868-874.
[3] Wang ZZ.;Hu Y.;Gui Z.;Zong RW. .Halogen-free flame retardation and silane crosslinking of polyethylenes[J].Polymer Testing,2003(5):533-538.
[4] Lei Ye;Qianghua Wu;Baojun Qu .Photocrosslinking and related properties of intumescent flame-retardant LLDPE/EVA/IFR blends[J].Polymers for advanced technologies,2012(5):858-865.
[5] J Lv;L QIU;B QU .Controlled synthesis of magnesium hydroxide nanoparticles with different morphological structures and related properties in flame retardant ethylene-vinyl acetate blends[J].Nanotechnology,2004(11):1576-1581.
[6] Dahong Yao;Baojun Qu;Qianghua Wu .Photoinitiated Crosslinking of Ethylene-Vinyl Acetate Copolymers and Characterization of Related Properties[J].Polymer engineering and science,2007(11):1761-1767.
[7] Ye, L;Wu, QH;Qu, BJ .Synergistic effects and mechanism of multiwalled carbon nanotubes with magnesium hydroxide in halogen-free flame retardant EVA/MH/MWNT nanocomposites[J].Polymer Degradation and Stability,2009(5):751-756.
[8] Weizhi Wang;Qianghua Wu;Baojun Qu .Mechanical Properties and Structural Characteristics of Dynamically Photocrosslinked PP/EPDM Blends[J].Polymer engineering and science,2003(11):1798-1805.
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