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在Ti6A14V合金表面激光熔覆原位合成了TiB2和TiC颗粒增强镍基复合涂层,通过X射线衍射仪、光学显微镜和扫描电镜以及能谱仪研究了添加2%(质量分数)Y2O3对涂层组织的影响。结果表明:未添加Y2O3的涂层由增强相、少量如CrB和基体组织组成;添加Y2O3后,涂层中增强相TiB2的尺寸显著细化且有新相Ni3Y生成,CrB化合物数量减少,涂层与基底形成冶金结合,且界面更平整、致密,成分过渡区有一定程度的缩小。

TiB2 and TiC particles reinforced Ni-based composite coatings were in-situ synthesized by laser cladding on Ti6A14V alloy surface. The effect of adding 2wt% Y2 O3 content on microstructure of the coating was studied by X-ray diffraction, optical microscopy, scanning electron microscopy and energy dispersive spectroscopy. The results show that the coating without Y2O3 consisted of reinforcement phases, a small quantity of CrB and the substrate. After adding Y2 O3, the size of reinforcement phase TiB2 was refined greatly and and a new phase Ni3 Y was found, and the number of CrB compound decreased. A metallurgical bonding was formed between the coating and substrate and the interface became smoother and more compact. The composition transition zone was reduced to a certain extent teeame.

参考文献

[1] 李军,李文戈,张慧颖.不锈钢基体上激光熔覆原位合成制备TiB2/WC增强镍基复合涂层[J].机械工程材料,2008(11):34-38.
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[3] 封延松,程西云.Y2O3对镍基碳化钛金属陶瓷熔覆层组织的影响[J].润滑与密封,2008(09):13-15.
[4] 赵高敏,王昆林,李传刚.稀土对Fe基合金激光熔覆层抗磨性能的影响[J].摩擦学学报,2004(04):318-321.
[5] 单际国,丁建春,任家烈.铁基自熔合金光束熔覆层的微观组织及强化机理[J].焊接学报,2001(04):1-4.
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