Comparison of the Molecular Interaction Volume Model with the Wagner Formulae in the Zn-Pb-In and Zn-Sn-Cd-Pb Dilute Solutions

材料科学技术（英文）, 2004, 20(3): 279-284.

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1.School of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming,650093, China

2.School of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming,650093, China

3.School of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming,650093, China

4.School of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming,650093, China

5.School of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming,650093, China

基金项目: This work was supported by the Joint Fund of the National Natural Science Foundation of China and Baoshan Steel Complex of Shanghai under(50274039)

Comparison of the Molecular Interaction Volume Model with the Wagner Formulae in the Zn-Pb-In and Zn-Sn-Cd-Pb Dilute Solutions

Keywords： Activity

The coordination numbers in the molecular interaction volume model (MIVM) can be calculated from the common physical quantities of pure liquid metals. A notable feature of the model lie in its capability to predict the thermodynamic properties of solutes in the Zn-Pb-ln and Zn-Sn-Cd-Pb dilute solutions using only the binary infinite dilute activity coefficients, and the predicted values are in good agreement with the experimental data of the dilute solutions.

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Comparison of the Molecular Interaction Volume Model with the Wagner Formulae in the Zn-Pb-In and Zn-Sn-Cd-Pb Dilute Solutions

参考文献