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醋酸乙烯酯在聚合中容易发生链转移和链终止反应,所以实现醋酸乙烯酯的"活性"/可控自由基聚合是一个巨大的挑战.文中从不同的活性自由基聚合方法角度对醋酸乙烯酯的"活性"/可控自由基聚合研宄进行了综述.在众多活性自由基聚合方法中以黄原酸酯、二硫代胺基甲酸酯为链转移剂的RAFT聚合和以乙酰丙酮钴络合物为调控剂的钴调控自由基聚合真正实现了它的"活性"/可控自由基聚合.

参考文献

[1] Stenzel MH.;Cummins L.;Roberts GE.;Davis TR.;Vana P.;Barner-Kowollik C. .Xanthate mediated living polymerization of vinyl acetate: A systematic variation in MADIX/RAFT agent structure[J].Macromolecular chemistry and physics,2003(9):1160-1168.
[2] Chiefari J.;Ercole F.;Krstina J.;Jeffery J.;Le TPT. Mayadunne RTA.;Meijs GF.;Moad CL.;Moad G.;Rizzardo E.;Thang SH.;Chong YK. .Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process[J].Macromolecules,1998(16):5559-5562.
[3] Shu-Hui Qin;Kun-Yuan Qiu .A facile method for synthesis of ABA triblock copolymers with macro-iniferter technique[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(7):3033-3042.
[4] Granel C.;Teyssie P.;Jasieczek CB.;Shooter AJ.;Haddleton DM.;Hastings JJ.;Gigmes D.;Grimaldi S.;Tordo P.;Greszta D. Matyjaszewski K.;Jerome R. .Investigation of methyl methacrylate and vinyl acetate polymerization promoted by Al(Bu-i)(3)/2,2 '-bipyridine and Al(Bu-i)(3)/2,2 '-bipyridine/TEMPO complexes[J].Macromolecules,1998(21):7133-7141.
[5] Matyjaszewski K.;Frechet JMJ.;Leduc M.;Shigemoto T. .CONTROLLED/LIVING RADICAL POLYMERIZATION WITH DENDRIMERS CONTAINING STABLE RADICALS[J].Macromolecules,1996(12):4167-4171.
[6] Gillies MB.;Matyjaszewski K.;Norrby PO.;Pintauer T.;Poli R.;Richard P. .A DFT study of R-X bond dissociation enthalpies of relevance to the initiation process of atom transfer radical polymerization[J].Macromolecules,2003(22):8551-8559.
[7] Destarac M.;Franck X.;Zard SZ.;Charmot D. .Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2000(15):1035-1039.
[8] Charmot D.;Adam H.;Zard SZ.;Biadatti T.;Bouhadir G.;Corpart P. .Controlled radical polymerization in dispersed media[J].Macromolecular symposia,2000(0):23-32.
[9] Coote ML;Henry DJ .Computer-aided design of a destabilized RAFT adduct radical: Toward improved RAFT agents for styrene-block-vinyl acetate copolymers[J].Macromolecules,2005(13):5774-5779.
[10] Alexander Theis;Thomas P.Davis;Martina H.Stenzel;Christopher Barner-Kowollik .Probing the reaction kinetics of vinyl acetate free radical polymerization via living free radical polymerization (MADIX)[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(4):999-1010.
[11] Mien Bernard;Arnaud Favier;Thomas P.Davis;Christopher Barner-Kowollik;Martina H.Stenzel .Synthesis of poly(vinyl alcohol) combs via MADIX/RAFT polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(4):1073-1080.
[12] Bernard J;Favier A;Zhang L;Nilasaroya A;Davis TP;Barner-Kowollik C;Stenzel MH .Poly(vinyl ester) star polymers via xanthate-mediated living radical polymerization: From poly(vinyl alcohol) to glycopolymer stars[J].Macromolecules,2005(13):5475-5484.
[13] Adamy M.;van Herk AM.;Destarac M.;Monteiro MJ. .Influence of the chemical structure of MADIX agents on the RAFT polymerization of styrene[J].Macromolecules,2003(7):2293-2301.
[14] Michael J.Monteiro;Monique M.Adamy;Bastiaan J.Leeuwen;Alex M.van Herk;Mathias Destarac .A "Living" Radical ab Initio Emulsion Polymerization of Styrene Using a Fluorinated Xanthate Agent[J].Macromolecules,2005(5):1538-1541.
[15] Antoine Debuigne;Jean-Raphael Caille;Robert Jerome .Highly Efficient Cobalt-Mediated Radical Polymerization of Vinyl Acetate[J].Angewandte Chemie,2005(7):1101-1104.
[16] W.Ken Busfield;Clovia I.Zayas-Holdsworth;San.H.Thang .End-Functionalized Copolymers Prepared by the Addition-Fragmentation Chain-Transfer Method:Vinyl Acetate/Methacrylonitrile System[J].Journal of Polymer Science, Part A. Polymer Chemistry,2001(17):2911-2919.
[17] Iovu MC.;Matyjaszewski K. .Controlled/living radical polymerization of vinyl acetate by degenerative transfer with alkyl iodides[J].Macromolecules,2003(25):9346-9354.
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