在苯酐-尿素法基础上,采用氯化铵作为酸性助剂参与缩合反应工艺,制备酞菁蓝颜料.讨论了酸性助剂对酞菁蓝颜料的收率、质量及其在水基体系中的分散性、分散稳定性的影响.优化的缩合反应条件为:以氯化铵作为酸性助剂,苯酐的加入量为25%(摩尔分数),所得颜料的收率可达到98%,且颗粒疏松,色光鲜艳;同时该颜料在水基体系中更易研磨分散,颜料色浆颗粒细小且粒径分布均匀,贮存稳定性较优.
参考文献
[1] | 张东江,张合杰.铜酞菁蓝颜料的加工技术简析[J].上海染料,2011(03):9-13. |
[2] | 张心亚,魏霞,陈焕钦.水性涂料的最新研究进展[J].涂料工业,2009(12):17-23,27. |
[3] | GLOS M;HRENS H A .Waterborne pigment formulations[P].US,0247347,2006-11-02. |
[4] | Edwin Baez;N. Quazi;I. Ivanov .Stability study of nanopigment dispersions[J].Advanced Powder Technology: The internation Journal of the Society of Powder Technology, Japan,2009(3):267-272. |
[5] | SLIVER J A;ROBERTS C C .Method of preparing aqueous pigment dispersions[P].US,0081553,2013-04-04. |
[6] | BERGE C T .Aqueous pigment dispersions based on alternating polyurethane dispersants[P].WO,088122,2013-01-24. |
[7] | Yi-Fen Lan;Jiang-Jen Lin .Clay-assisted dispersion of organic pigments in water[J].Dyes and Pigments,2011(1):21-27. |
[8] | Fu, S.;Du, C.;Zhang, M.;Tian, A.;Zhang, X. .Preparation and properties of polymer-encapsulated phthalocyanine blue pigment via emulsion polymerization[J].Progress in Organic Coatings: An International Review Journal,2012(2/3):149-154. |
[9] | 郑少琴.铜酞菁生产中晶体颗粒的控制[J].河北化工,2008(02):45-47. |
[10] | PARK JAI WON;LEE HYENSU;JUNG KISUCK .Process of preparing product based on copper phthalocyanine (CuPc) particles[P].WO,084824,2012-06-28. |
[11] | KOBAYASHI T .The metal-ligand vibrations in the infrared spectra of various metal phthalocyanines[J].Spectrochimca Acta Part A:Molecular Spectroscopy,1970,26(6):1305-1311. |
[12] | 黄永祥.不同晶型的铜酞菁制备与X射线衍射仪的测定研究[J].化工时刊,2006(05):1-3. |
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