以Al+ Fe2O3+ BaO2+蔗糖+环氧树脂为反应体系、聚乙二醇为表面活性剂,运用将火焰喷涂技术与自蔓延高温合成技术(Self-propagating High-temperature Synthesis,缩写SHS)及快速冷却凝固技术相结合的自反应淬熄法,制备了空心复相陶瓷微珠.通过SEM、EDS、XRD等手段,研究了聚乙二醇的加入对团聚粉及制备的空心陶瓷微珠的影响.结果表明,与未加聚乙二醇相比,加入聚乙二醇后,团聚粉颗粒分布均匀,具有良好的流动性；所制备的空心微珠粒径趋于一致,成球率得到了明显提升,相结构中Fe3O4转变成了Fe2O3,且出现了具有尖晶石结构的BaFe2O4,这有助于提高空心微珠的吸波性能.
参考文献
| [1] | Klingman R M .Pyroplastid Particles,Composition and Method of Production[P].US:4 268 320,1981-05-19. |
| [2] | Geleil AS;Hall MM;Shelby JE .Hollow glass microspheres for use in radiation shielding[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2006(6/7):620-625. |
| [3] | Schmitt ML;Shelby JE;Hall MM .Preparation of hollow glass microspheres from sol-gel derived glass for application in hydrogen gas storage[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2006(6/7):626-631. |
| [4] | Liqiang Xu;Wanqun Zhang;Qing Yang .A novel route to hollow and solid carbon spheres[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(5):1090-1092. |
| [5] | Wang ZL.;Yin JS. .Graphitic hollow carbon calabashes[J].Chemical Physics Letters,1998(1/2):189-192. |
| [6] | Yukito Oda;Katsuya Fukuyama;Keiko Nishikawa;Seitaro Namba;Hideaki Yoshitake;Takashi Tatsumi .Mesocellular Foam Carbons:Aggregates of Hollow Carbon Spheres with Open and Closed Wall Structures[J].Chemistry of Materials,2004(20):3860-3866. |
| [7] | 娄鸿飞;王建江 .Al-Cr2O3配系空心陶瓷微珠吸波新材料[P].CN:201010050485.7,2010-10-05. |
| [8] | 娄鸿飞;王建江 .Al-TiO2配系空心陶瓷微珠吸波新材料[P].CN:201010050484.2,2010-10-05. |
| [9] | 娄鸿飞;王建江 .Al-CuO配系空心陶瓷微珠吸波新材料[P].CN:201010050483.8,2010-10-05. |
| [10] | 代维,薛屺,代莉,罗腾奘.制备陶瓷块体材料高分子分散剂的选择[J].中国科技信息,2011(08):44-45. |
| [11] | 张弘,刘曦,刘小晰,魏福林,A.S.Kamzin,贺德衍.交替溅射法制备BaM铁氧体薄膜的特性研究[J].人工晶体学报,2009(06):1380-1383,1393. |
| [12] | 盖国胜;陶珍东;丁明.粉体技术[M].北京:清华大学出版社,2009:647-648. |
| [13] | 刘兴重,刘小贝,周林涛.聚乙二醇柔性间隔基纳米SiO2增韧环氧树脂性能研究[J].武汉科技大学学报（自然科学版）,2008(02):186-188. |
| [14] | 娄鸿飞 .空心陶瓷微珠的制备及其吸波性能研究[D].石家庄:军械工程学院,2010. |
| [15] | Pullar R C;Taylor M D;Bhattacharya A K.A Halide Free Route to The Manufacture of Microstructurally Improved M ferrite (BaFe12O19 and SrFel2O19) fibers[J].Journal of the European Ceramic Society,2002(22):2039-2045. |
| [16] | 兰银辉,高学绪,乔袆,高静,包小倩.自蔓延高温合成钡铁氧体的研究[J].材料导报,2007(z1):333-335. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%