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为了解决尖晶石锰酸锂(LiMn2O4)电池正极在高温下容量降低过快的问题,通过简单方法将NiO包覆到LiMn2O4粉体表面,并对包覆前后LiMn2 O4粉体材料的结构、形貌和相应正极材料的电化学性能进行了研究.结果表明:NiO包覆LiMn2 O4粉体后其晶体结构没有发生改变,表面呈现钟乳石状突起;与包覆前相比,NiO包覆LiMn2 O4粉体后的正极材料的循环性能和倍率性能分别提高了8.79%和14.04%.

参考文献

[1] 赵智泉,刘庆雷,黄大成,周凤羽,刘元超,张荻.锂离子电池负极用硅/碳纳米复合材料制备方法和性能的研究进展[J].机械工程材料,2012(09):1-7.
[2] 见姬,周文娟,徐国祥,艾娟,付花荣.锂离子电池正极材料行业分析[J].科技情报开发与经济,2014(04):146-149.
[3] 黄可龙;王兆翔;刘素琴.锂离子电池原理与关键技术[M].北京:化学工业出版社,2008
[4] SU L W;JING Y;ZHOU Z .Li ion battery materials with core-shell nanostructures[J].Nanoscale,2011,3:3967-3983.
[5] AMATUCCI G;PASQUIER A D;BLYR A et al.The elevated temperature performance of the LiMn2O4/C system:failure and solutions[J].Electrochimica Acta,1999,45:255259.
[6] Takayuki Aoshima;Kenji Ohahara;Chikara Kiyohara .Mechanisms of manganese spinels dissolution and capacity fade at high temperature[J].Journal of Power Sources,2001(0):377-380.
[7] Ragupathy Pitchai;Velmurugan Thavasi;Subodh G. Mhaisalkar .Nanostructured cathode materials: a key for better performance in Li-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(30):11040-11051.
[8] Xia YY.;Yoshio M.;Zhou YH. .CAPACITY FADING ON CYCLING OF 4 V LI/LIMN2O4 CELLS[J].Journal of the Electrochemical Society,1997(8):2593-2600.
[9] 江剑兵,杜柯,曹雁冰,彭忠东,胡国荣.机械活化氧化法制备锰酸锂及其性能研究[J].功能材料,2014(08):8120-8123.
[10] KOMABA S;KUMAGAI N;KATAOKA Y .Influence of manganese(Ⅱ),cobalt(Ⅱ),and nickel(Ⅱ) additives in electrolyte on performance of graphite anode for lithium-ion bat teries[J].Electrochimica Acta,2002,47:1229-1239.
[11] Xifei Li;Youlong Xu;Chunlei Wang .Suppression of Jahn-Teller distortion of spinel LiMn_2O_4 cathode[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):310-313.
[12] J. Darul;W. Nowicki;C. Lathe .Observation of phase transformations in LiMn2O4 under high pressure and at high temperature by in situ X-ray diffraction measurements[J].Radiation Physics and Chemistry,2011(10):1014-1018.
[13] Hosono, E;Kudo, T;Honma, I;Matsuda, H;Zhou, HS .Synthesis of Single Crystalline Spinel LiMn2O4 Nanowires for a Lithium Ion Battery with High Power Density[J].Nano letters,2009(3):1045-1051.
[14] Wei YJ;Yan LY;Wang CZ;Xu XG;Wu F;Chen G .Effects of Ni doping on [MnO6] octahedron in LiMn2O4[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(48):18547-18551.
[15] Luo JY;Cheng L;Xia YY .LiMn2O4 hollow nanosphere electrode material with excellent cycling reversibility and rate capability[J].Electrochemistry communications,2007(6):1404-1409.
[16] HWANG B J;TSAI Y W;SANTHANAM R et al.Evolution of local electronic and atomic structure of Co-doped LiMn2O4 cathode material for lithium rechargeable batteries[J].Journal of Power Sources,2003,123:206-215.
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