聚对苯乙烯撑(PPV)由于具有优良的光电性质,是研究最多也是最有希望的光伏材料之一.然而单纯PPV作为光伏材料存在对太阳光利用率不高、载流子迁移率较低、稳定性不高等缺陷,制约了其实际应用.因此在围绕提高光伏效率和材料稳定性等基础上,近几年出现了大量PPV改性光伏材料.分析了新型PPV的各种改性措施的目的和相应的分子结构修饰方法,同时探讨了PPV光伏材料尚存在的问题和它作为高分子光电池材料的发展前景.
参考文献
| [1] | Breeze AJ;Schlesinger Z;Carter SA;Tillmann H;Horhold HH .Improving power efficiencies in polymer - polymer blend photovoltaics[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(2/3):263-271. |
| [2] | Hou Jianhui;Yang Chunhe;Qiao Jing et al.Synthesis and photovoltaic properties of the copolymers of 2-methoxy-5-(2prime -ethylhexyloxy)-l,4-phenylene vinylene and 2,5-thienylene-vinylene[J].Synthetic Metals,2005,150(03):297. |
| [3] | Egbe DAM;Kietzke T;Carbonnier B;Muhlbacher D;Horhold HH;Neher D;Pakula T .Synthesis, characterization, and photophysical, electrochemical, electroluminescent, and photovoltaic properties of yne-containing CN-PPVs[J].Macromolecules,2004(24):8863-8873. |
| [4] | Reyes-Reyes M;Kim K;Carroll DL .High-efficiency photovoltaic devices based on annealed poly(3-hexylthiophene) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C-61 blends[J].Applied physics letters,2005(8):3506-1-3506-3-0. |
| [5] | Karg S;Riess W;Dyakonov V et al.Electrical and optical characterization of poly(phenylene-vinylene) light emitting diodes[J].Synthetic Metals,1993,54(1-3):427. |
| [6] | Christoph J. Brabec;Sean E. Shaheen;Christoph Winder;N. Serdar Sariciftci;Patrick Denk .Effect of LiF/metal electrodes on the performance of plastic solar cells[J].Applied physics letters,2002(7):1288-1290. |
| [7] | Lu SL;Yang MJ;Luo J;Cao Y;Bai FL .Novel alternating dioctyloxyphenylene vinylene-benzothiadiazole copolymer: Synthesis and photovoltaic performance[J].Macromolecular chemistry and physics,2005(6):664-671. |
| [8] | Colladet K;Nicolas M;Goris L et al.Low-band gap polymers for photovoltaic applications[J].Thin Solid Films,2004,451-452:7. |
| [9] | Thompson B C;Kim Y G;Reynolds J R et al.Spectral broadening in MEH-PFV:PCBM-based photovoltaic devices via blending with a narrow band gap cyanovinylenedioxythiophene polymer[J].Macromolecules,2005,38(13):5359. |
| [10] | Huang Hongmin;He Qingguo;Lin Hongzhen et al.Properties of an alternating copolymer and its applications in LEDs and photovoltaic cells[J].Thin Solid Films,2005,477(1-2):7. |
| [11] | Huo Lijun;Hou Jianhui;He Chang et al.Synthesis,characterization and photovoltaic properties of poly {[1 prime,4 prime-bis-(thienyl-vinyl)]-2-methoxy-5-(2prime-ethylhexyloxy)-1,4-phenylene-vinylene}[J].Synthetic Metals,2006,156(2-4):276. |
| [12] | Anantharaman Dhanabalan;Jeroen K. J. van Duren;Paul A. van Hal .Synthesis and Characterization of a Low Bandgap Conjugated Polymer for Bulk Heterojunction Photovoltaic Cells[J].Advanced functional materials,2001(4):255-262. |
| [13] | Hui C S;Wong H L;Kwong C Y et al.Fabrication of photovoltaic cell from rhenium containing polymer[J].PROCEEDINGS OF SPIE-THE INTERNATIONAL SOCIETY FOR,2004,5215:254. |
| [14] | Mikkel Jorgensen;Frederik C.Krebs .Stepwise Unidirectional Synthesis of Oligo Phenylene Vinylenes with a Series of Monomers.Use in Plastic Solar Cells[J].The Journal of Organic Chemistry,2005(15):6004-6017. |
| [15] | Yu G.;Heeger AJ. .CHARGE SEPARATION AND PHOTOVOLTAIC CONVERSION IN POLYMER COMPOSITES WITH INTERNAL DONOR ACCEPTOR HETEROJUNCTIONS[J].Journal of Applied Physics,1995(7):4510-4515. |
| [16] | Halls J J M;Walsh C A;Greenham N C et al.Efficient photodiodes from interpenetrating polymer networks[J].Nature,1995,376:498. |
| [17] | S.C.Veenstra;W.J.H.Verhees;J.M.Kroon;M.M.Koetse;J.Sweelssen;J.J.A.M.Bastiaansen;H.F.M.Schoo;X.Yang;A.Alexeev;J.Loos;U.S.Schubert;M.M.Wienk .Photovoltaic Properties of a Conjugated Polymer Blend of MDMO-PPV and PCNEPV[J].Chemistry of Materials,2004(12):2503-2508. |
| [18] | Quist PAC;Savenije TJ;Koetse MM;Veenstra SC;Kroon JM;Siebbeles LDA .The effect of annealing on the charge-carrier dynamics in a polymer/polymer bulk heterojunction for photovoltaic applications[J].Advanced functional materials,2005(3):469-474. |
| [19] | Peeters E;van Hal P A;Knol J et al.Synthesis,photophysical properties,and photovoltaic devices of oligo (pphenylene vinylene)-fullerene dyads[J].Journal of Physical Chemistry B,2000,104(44):10174. |
| [20] | Ramos A M;Rispens M T;van Duren J K J et al.Photoinduced electron transfer and photovoltaic devices of a conjugated polymer with pendant fullerenes[J].Journal of the American Chemical Society,2001,123(27):6714. |
| [21] | Ramos A M;Rispens M T;Hummelen J C et al.A poly(p-phenylene ethynylene vinylene) with pendant fullerenes[J].Synthetic Metals,2001,119(1-3):171. |
| [22] | Stalmach U.;Videlot C.;van Hutten PF.;Hadziioannou G.;de Boer B. .Semiconducting diblock copolymers synthesized by means of controlled radical polymerization techniques[J].Journal of the American Chemical Society,2000(23):5464-5472. |
| [23] | Eckert Jean-Francois .Fullerene-Oligophenylenevinylene Hybrids: Synthesis, Electronic Properties, and Incorporation in Photovoltaic Devices[J].Journal of the American Chemical Society,2000(31):7467-7479. |
| [24] | Marleen H.van der Veen;Bert de Boer;Ulf Stalmach;Karin I.van de Wetering;Georges Hadziioannou .Donor-Acceptor Diblock Copolymers Based on PPV and C_(60) Synthesis,Thermal Properties,and Morphology[J].Macromolecules,2004(10):3673-3684. |
| [25] | Zhu D;Li Y;Wang S et al.Design,synthesis and properties of functional materials based on fullerene[J].Synthetic Metals,2003,133-134:679. |
| [26] | Schappel J;Schmidt K;Klemm E .Alternating pi-conjugated block copolymers with precise block length[J].Journal of Polymer Science, Part A. Polymer Chemistry,2005(16):3574-3587. |
| [27] | Silvia Luzzati;Markus Scharber;Marinella Catellani .Tuning of the photoinduced charge transfer process in donor--acceptor double-cable copolymers[J].Synthetic Metals,2003(3):731-733. |
| [28] | Sun SS. .Design of a block copolymer solar cell[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(2):257-264. |
| [29] | Sun S;Zhang C;Haliburton J et al.Organic solar cell optimizations in both space and energy regimes:Large open circuit voltage from a -DBAB-type block copolymer[J].PROCEEDINGS OF SPIE-THE INTERNATIONAL SOCIETY FOR,2005,5938:1. |
| [30] | Qiao J.;Yang CH.;He QG.;Bai FL.;Li YF. .Hyperbranched conjugated polymers for photovoltaic applications[J].Journal of Applied Polymer Science,2004(3):1459-1466. |
| [31] | Tang RP;Zhan'ao T;Cheng CX;Li YF;Xi F .Synthesis, electroluminescence, and photovoltaic properties of dendronized poly (p-phenylene vinylene) derivatives[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(14):5341-5350. |
| [32] | Yang Liu;Chunhe Yang;Yongjun Li;Yuliang Li;Shu Wang;Junpeng Zhuang;Huibiao Liu;Ning Wang;Xiaorong He;Yongfang Li;Daoben Zhu .Synthesis and Photovoltaic Characteristics of Novel Copolymers Containing Poly(phenylenevinylene)and Triphenylamine Moieties Connected at 1,7 Bay Positions of Perylene Bisimide[J].Macromolecules,2005(3):716-721. |
| [33] | Neuteboom EE.;Meskers SCJ.;van Hal PA.;van Duren JKJ.;Meijer EW. Janssen RAJ.;Dupin H.;Pourtois G.;Cornil J.;Lazzaroni R.;Bredas JL. Beljonne D. .Alternating oligo(p-phenylene vinylene)-perylene bisimide copolymers: Synthesis, photophysics, and photovoltaic properties of a new class of donor-acceptor materials[J].Journal of the American Chemical Society,2003(28):8625-8638. |
| [34] | Egbe DAM;Nguyen LH;Hoppe H;Muhlbacher D;Sariciftci NS .Side chain influence on electrochemical and photovoltaic properties of yne-containing poly(phenylene vinylene)s[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2005(17):1389-1394. |
| [35] | H.Hoppe;N.S.Sariciftci;D.A.M.Egbe;D.Muhlbacher .Photovoltaic action of conjugated polymer/fullerene bulk heterojunction solar cells using novel PPE-PPV copolymers[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(23):3462-3467. |
| [36] | Al-Ibrahim M;Konkin A;Roth HK;Egbe DAM;Klemm E;Zhokhavets U;Gobsch G;Sensfuss S .Phenylene-ethynylene/phenylene-vinylene hybrid polymers: optical and electrochemical characterization, comparison with poly [2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene vinylene] and application in flexible polymer solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1/2):201-210. |
| [37] | Sensfuss S;Al-Ibrahim M;Konkin A et al.Characterisation of potential donor acceptor pairs for polymer solar cells by ESR,optical and electrochemical investigations[J].PROCEEDINGS OF SPIE-THE INTERNATIONAL SOCIETY FOR,2004,5215:129. |
| [38] | Daniel Ayuk Mbi Egbe;Le Huong Nguyen;Niyazi Serdar Sariciftci;Benjamin Carbonnier;David Muhlbacher .Thiophene-containing poly(arylene-ethynylene)-alt-poly(arylene-vinylene)s:Synthesis,characterisation and optical properties[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(23):9585-9595. |
| [39] | Egbe D A M;Bader C;Nowotny J et al.Synthesis and characterization of three types of alkoxy-substituted hybrid PPV-PPE polymers:Potential candidates for photovoltaic applications[J].PROCEEDINGS OF SPIE-THE INTERNATIONAL SOCIETY FOR,2004,5215:79. |
| [40] | Mozer AJ;Denk P;Scharber MC;Neugebauer H;Sariciftci NS;Wagner P;Lutsen L;Vanderzande D;Kadashchuk A;Staneva R .Novel regiospecific MDMO-PPV polymers with improved charge transport properties for bulk heterojunction solar cells[J].Synthetic Metals,2005(1/3):81-84. |
| [41] | Mozer A J;Denk P;Scharber M C et al.Novel regiospecific MDMO-PPV copolymer with improved charge transport for bulk heterojunction solar cells[J].Journal of Physical Chemistry B,2004,108(17):5235. |
| [42] | Jorgensen M;Krebs F C .Synthesis of oligo phenylene vinylenes for organic photovoltaic cells[J].PROCEEDINGS OF SPIE-THE INTERNATIONAL SOCIETY FOR,2005,5938:1. |
| [43] | Geens W.;Aernouts T.;Poortmans J.;Hadziioannou G. .Organic co-evaporated films of a PPV-pentamer and C-60: model systems for donor/acceptor polymer blends[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2002(0):438-443. |
| [44] | Braun D;Heeger A J .Visible light emission from semiconducting polymer diodes[J].Applied Physics Letters,1991,58(18):1982. |
| [45] | Hou JH;Fan BH;Huo LJ;He C;Yang CH;Li YF .Poly(alkylthio-p-phenylenevinylene): Synthesis and electroluminescent and photovoltaic properties[J].Journal of Polymer Science, Part A. Polymer Chemistry,2006(3):1279-1290. |
| [46] | Ahn Y J;Kang G W;Lee C H et al.Photovoltaic properties of polymer-based solar cells[J].Synthetic Metals,2003,137(1-3):1447. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%