采用基于密度泛函理论的第一性原理计算方法系统地对Aun(n≤8)吸附在MgO(001)表面的结构进行了详细的研究.分别给出了气相的Aun(n≤13)和吸附在MgO表面的Aun(n≤8)团簇的最稳定结构,比较了这两种情况下,Aun在结构、平均键长和磁矩方面的区别.结果表明,气相的Aun,在n≤13时团簇均为平面结构,而Aun吸附在MgO(001)表面上之后,从AU7就开始出现从平面结构向立体结构转变.吸附在MgO(001)表面上的Aun团簇在较小尺寸就发生二维到三维结构转变的原因可能是An键长与MgO(001)表面的晶格失配造成的.吸附在MgO(001)表面的团簇因受到表面极化而使得团簇上电荷分布发生变化,但是表面衬底和团簇之间的电荷转移量很小.
参考文献
[1] | Kroto H W;Heath J R;O'Brina S C et al.C60:Buckminsterfullerene[J].Nature,1985,318:162. |
[2] | Kratschmer W;Lamb L D;Fostiropoulos K et al.Solid C60:A new form of carbon[J].Nature,1990,347:354. |
[3] | Bokwon Yoon;Hannu Haekkinen;Uzi Landman;Anke S. Woerz;Jean-Marie Antonietti;Stephane Abbet;Ken Judai;Ueli Heiz .Charging Effects on Bonding and Catalyzed Oxidation of CO on Au_8 Clusters on MgO[J].Science,2005(5708):403-407. |
[4] | Valden M;Lai X;Goodman D W .Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties[J].Science,1998,281:11. |
[5] | Wang JG;Hammer B .Role of Au+ in supporting and activating Au-7 on TiO2(110)[J].Physical review letters,2006(13):6107-1-6107-4-0. |
[6] | Siris Laursen;Suljo Linic .Oxidation Catalysis by Oxide-Supported Au Nanostructures: The Role of Supports and the Effect of External Conditions[J].Physical review letters,2006(2):026101.1-026101.4. |
[7] | Kulawik M;Nilius N;Freund H J .Influence of the metal suhstrate on the adsorption properties of thin oxide layers:Au atoms on a thin alumina film on NiAI(110)[J].Physical Review Letters,2006,96:036103. |
[8] | Chang C M;Chou M Y .Alternative low-symmetry structure for 13-atom metal clusters[J].Physical Review Letters,2004,93:133401. |
[9] | Fa W;Luo CF;Dong JM .Bulk fragment and tubelike structures of Au-N (N=2-26)[J].Physical review, B. Condensed matter and materials physics,2005(20):5428-1-5428-4-0. |
[10] | Wang Jinlan;Wang Guanghou;Zhao Jijun .Density-functional study of Aun(n=2~20) clusters:Lowest-energy structures and electronic properties[J].Physical Review B,2002,66:035418. |
[11] | Eva M Fernández;Jos6 M Soler .Planar and cagelike structures of gold clusters:Density-functional pseudopotential calculations[J].Physical Review B,2006,73:235433. |
[12] | Li J;Li X .Au20:A tetrahedral cluster[J].Science,2003,299:864. |
[13] | 李文娟,周继承,朱金波.PSO-SA模拟金团簇的几何结构与基态能量[J].原子与分子物理学报,2007(05):911-915. |
[14] | Gu X;Ji M;Wei S H et al.Aun clusters n=(32,33,34,35):Cagelike structures of pure metal atoms[J].Physical Review B,2004,70:205401. |
[15] | Kohn W;Sham L J .Quantum density oscillations in an inhomogeneous electron gas[J].Physical Review,1965,137:A1697. |
[16] | Kohn W;Sham L J .Self-consistent equations including exchange and correlation effects[J].Physical Review,1965,140:A1133. |
[17] | Perdew J P;Chevary J A;Vosko S H et al.Atoms,molecules,solids,and surfaces:Applications of the generalized gradient approximation for exchange and correlation[J].Physical Review B,1992,46:16671. |
[18] | Kresse G.;Furthmuller J. .EFFICIENT ITERATIVE SCHEMES FOR AB INITIO TOTAL-ENERGY CALCULATIONS USING A PLANE-WAVE BASIS SET[J].Physical Review.B.Condensed Matter,1996(16):11169-11186. |
[19] | 李红红,王劼,李锐鹏,郭玉献,王锋,胡志伟.X射线磁性圆二色: MgO衬底铁单晶膜的轨道磁矩和自旋磁矩[J].科学通报,2005(12):1172-1175. |
[20] | Maxim Yulikov;Martin Sterrer;Markus Heyde;Hans-Peter Rust;Thomas Risse;Hans-Joachim Freund;Gianfranco Pacchioni;Andrea Scagnelli .Binding of Single Gold Atoms on Thin MgO(001) Films[J].Physical review letters,2006(14):146804.1-146804.4. |
[21] | Gianfranco Pacchioni;Livia Giordano;Matteo Baistrocchi .Charging of metal atoms on ultrathin MgO/Mo(001) films[J].Physical Review Letters,2005,94:1226104. |
[22] | Martin Sterrer;Thomas Risse;Markus Heyde;Hans-Peter Rust;Hans-Joachim Freund .Crossover from Three-Dimensional to Two-Dimensional Geometries of Au Nanostructures on Thin MgO(001) Films: A Confirmation of Theoretical Predictions[J].Physical review letters,2007(20):206103.1-206103.4. |
[23] | Molina M;Hammer B .Theoretical study of CO oxidation on Au nanoparticles supported by MgO(100)[J].Physical Review B,2004,69:155424. |
[24] | Michael Walter;Hakkinen H .Optical absorption of magnesia-supported gold clusters and nanoscale catalysts:Effects due to the support,clusters,and adsorhants[J].Physical Review B,2005,72:205440. |
[25] | Bogicevic A;Jennison D .Effect of oxide vacancies on metal island nucleation[J].Surface Science,2002,515:L481. |
[26] | Pentti Frondelius;Hannu Haekkinen;Karoliina Honkala .Adsorption of gold clusters on metal-supported MgO: Correlation to electron affinity of gold[J].Physical review, B. Condensed matter and materials physics,2007(7):073406.1-073406.4. |
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