形状记忆聚合物是一类新型的智能材料,环氧树脂是形状记忆聚合物中重要的一族,基于其卓越的性能,已广泛应用于空间可展开结构中.介绍了固化剂对环氧树脂热、机械以及形状记忆效应的影响,但由于环氧树脂最大的弱点是韧性差,固化后树脂脆,在低于其玻璃化转变温度弯曲变形时会发生脆性断裂,不能作为形状记忆树脂基体使用.重点综述了不同方法对环氧树脂基复合材料进行增韧,进而展望了环氧树脂的发展和应用前景.
参考文献
[1] | Samy A;Madbouly;Andreas Lendlein .Shape-memory polymer composites[J].Advances in Polymer Science,2010,226:41. |
[2] | Liu Y;Han C;Tan H .Thermal,mechanical and shape memory properties of shape memory epoxy resin[J].Materials Science and Engineering,2010,527(10-11):2510. |
[3] | Merline JD;Nair CPR;Ninan KN .Synthesis, characterization, curing and shape memory properties of epoxy-polyether system[J].Journal of Macromolecular Science. Pure and Applied Chemistry,2008(4):312-322. |
[4] | Cadogan D P;Scarborough S E;Lin J K.Shape memory composite development for use in Gossamer space inflatable structures[J].American Institute of Aeronautics and Astronautics,2002(1372):1. |
[5] | 王诗任,徐修成,过梅丽,贺鹏.EVA的形状记忆功能探讨[J].北京航空航天大学学报,2000(01):1-4. |
[6] | David P C;Stephen E S;John K L et al.Shape memory composite development for use in gossamer space inflatable structures[J].Am Institute Aeronaut Astronaut,2002,1372:1. |
[7] | 陈建君,姜志国,黄丽,李效玉.端胺基聚氨酯增韧环氧树脂的研究[J].北京化工大学学报(自然科学版),2006(06):66-70. |
[8] | Liu Yuyan;Han Chunmiao;Tan Huifeng et al.Organicmontomorillonite modified shape memory epoxy composite[J].Polymers For Advanced Technologies,2010,22(12):2017. |
[9] | 甘丽,孙志杰,顾轶卓,李敏,张佐光.升温与等温法非模型动力学研究环氧树脂固化反应[J].高分子学报,2010(08):1016-1022. |
[10] | 黄文,刘小青,朱锦,曹迁永.马来海松酸酐的合成及其作为环氧树脂固化剂的研究[J].化学通报(印刷版),2011(01):92-96. |
[11] | Sponton M;Ronda JC;Galia M;Cadiz V .Flame retardant epoxy resins based on diglycidyl ether of (2,5-dihydroxyphenyl)diphenyl phosphine oxide[J].Journal of Polymer Science, Part A. Polymer Chemistry,2007(11):2142-2151. |
[12] | Diane M. Feldkamp;Ingrid A. Rousseau .Effect of the Deformation Temperature on the Shape-Memory Behavior of Epoxy Networks[J].Macromolecular materials and engineering,2010(8):726-734. |
[13] | Beloshenko V A .Shape memory effect in the epoxy polymerthermoexpanded graphite system[J].Compos:Part A,2002,33:1001. |
[14] | 朱光明.形状记忆聚合物及其应用[M].北京:化学工业出版社,2002:39. |
[15] | 李郑发,王正道.形状记忆聚合物热力学本构模型研究进展[J].高分子材料科学与工程,2009(05):171-174. |
[16] | Nam Gyun Yun;Yong Gu Won;Sung Chul Kim .Toughening of epoxy composite by dispersing polysulfone particle to form morphology spectrum[J].Polymer Bulletin,2004,52:365. |
[17] | 王月菊,刘杰,杨建军,张建安,吴庆云,吴明元.聚氨酯改性环氧树脂胶黏剂的研究与应用进展[J].化学与黏合,2008(05):54-57. |
[18] | 常鹏善,左瑞霖,王汝敏,陈立新.一种液晶环氧增韧环氧树脂的研究[J].高分子学报,2002(05):682-684. |
[19] | 崔佳,曲敏杰,刘伟,李晶,张美玲,代新英,胡那.聚氨酯改性环氧树脂的研究[J].工程塑料应用,2009(02):24-27. |
[20] | Pollack S K;Mcpherson C A .Rubber-modified epoxies.Ⅰ.Transitions.and morphology[J].Journal of Applied Polymer Science,1981,26(03):889. |
[21] | 武渊博,李刚,黄智彬,李鹏.端环氧基丁腈橡胶增韧环氧树脂的结构与性能[J].玻璃钢/复合材料,2010(05):44-46,83. |
[22] | 尚蕾,黄奕刚,王建华,贾晓蓉.聚氨酯/环氧树脂互穿网络聚合物的性能研究[J].化学研究与应用,2005(04):552-553. |
[23] | 李芝华,任冬燕,郑子樵,李波.聚氨酯改性TDE-85/MeTHPA环氧树脂的力学性能研究[J].强激光与粒子束,2007(02):262-266. |
[24] | Park S;Jin J J .Toughness response of vinylester/epoxybased thermosets of interpenetrating network structure as a function of the epoxy resin formulation:Effects of the cy clohexylene linkage[J].Application of Polymer Science,2001,82:775. |
[25] | 胡巧玲,朱永群,付晏彬,俞晓薇.光固化型聚氨酯/环氧树脂IPN的制备与表征[J].高分子材料科学与工程,1999(05):172-175. |
[26] | Hsieh K H;Han J L;Yu C T et al.Phase separation in semi-interpenetrating polymer networks based on crosslinked poly(urethane) and linear poly(methyl methacrylate) containing iron,copper,and chromium chelates[J].Polymer,2001,42:2491. |
[27] | 张培培,陈有双,唐忠锋.聚氨酯改性环氧树脂的研究进展[J].高分子通报,2010(12):84-89. |
[28] | Yu HJ;Wang L;Shi Q;Jiang GH;Zhao ZR;Dong XC .Study on nano-CaCO3 modified epoxy powder coatings[J].Progress in Organic Coatings: An International Review Journal,2006(3):296-300. |
[29] | 张瑜,戴耀东,李江苏,孙浩,常树全.聚丙烯酸铅/环氧树脂辐射防护材料的制备及性能研究[J].高分子学报,2010(05):582-587. |
[30] | 孙宏伟,陈建峰.我国化工过程强化技术理论与应用研究进展[J].化工进展,2011(01):1-15. |
[31] | 贾润萍,陶丽,滕娜.等离子体诱导接枝聚合修饰碳纳米管及其环氧树脂复合材料[J].新型炭材料,2010(06):470-474. |
[32] | 刘诗飞,王永三,朱麟勇,李欣欣.聚醚多元醇对环氧树脂的增韧改性[J].功能高分子学报,2010(02):144-148. |
[33] | Liu Yuyan;Han Chunmiao;Tan Huifeng et al.Thermal,mechanical and shape memory properties of shape memory epoxy resin[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2010,527:2510. |
[34] | 郑修成,袁程远,赵文平,杨春艳,叶文豪,王向宇.介孔分子筛SBA-15的合成与表征[J].郑州大学学报(理学版),2008(01):101-106. |
[35] | 陈书文,王雁冰,黄志雄,张超.介孔SBA-15/环氧树脂复合材料的性能研究[J].武汉理工大学学报,2011(01):18-21. |
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