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多孔电极与流道内的水淹现象是制约质子交换膜(PEM)燃料电池性能提高的关键难题.传统的宏观两相模型普遍存在液态水饱和度预测值偏低的不足,而流道内气液两相雾状流的假设则是低估水淹程度的一个主要原因.本文提出了反映流道壁面浸润差异性的毛细压力流道拓展模型,并对低气速下燃料电池内的传热传质进行了模拟.计算结果表明,该模型克服了原有模型对饱和度预测值偏低的不足,不仅反映了液相水分布的贴壁效应,同时还可以考虑流道壁面差异的影响.

参考文献

[1] Ye Q;Van Nguyen T .Three-dimensional simulation of liquid water distribution in a PEMFC with experimentally measured capillary functions[J].Journal of the Electrochemical Society,2007(12):B1242-B1251.
[2] Zhang FY;Yang XG;Wang CY .Liquid water removal from a polymer electrolyte fuel cell[J].Journal of the Electrochemical Society,2006(2):A225-A232.
[3] Ahmet Turhan;Soowhan Kim;Marta Hatzell;Matthew M. Mench .Impact of channel wall hydrophobicity on through-plane water distribution and flooding behavior in a polymer electrolyte fuel cell[J].Electrochimica Acta,2010(8):2734-2745.
[4] Suman Basu;Jun Li;Chao-Yang Wang .Two-phase Flow And Maldistribution In Gas Channels Of A Polymer Electrolyte Fuel Cell[J].Journal of Power Sources,2009(2):431-443.
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