C和Pt/Al2O3的顺序递增.在载体为酸性的催化剂Pt/Al2O3和Pt/HUSY上有利于烃的生成;在多元醇水相重整制氢反应中,产物氢的选择性和产率随碳数增加而降低;在葡萄糖水相重整制氢反应中,产物氢的选择性和收率随其浓度增加而降低,烃选择性在葡萄糖浓度为4.6%时最高,这与葡萄糖的缩合和降解等副反应有关.果糖比葡萄糖更难发生水相重整制氢反应.与低级糖麦芽糖和葡萄糖相比,在多糖淀粉的重整制氢反应中氢选择性和收率较高.
参考文献
[1] | Roper H .Renewable raw materials in Europe - Industrial utilisation of starch and sugar [Review][J].Starch: International Journal for the Investigation, Processing and Use of Carbohydrates and their Derivatives: Internationale Zeitschrift fur die Erforschung, Verarbeitung und Verwendung von Kohlenhydraten und deren Derivaten,2002(3/4):89-99. |
[2] | Dunn S .[J].Lnt J Hydrogen Energy,2002,27:235. |
[3] | Choudhary T V;Goodman D W .[J].Catalysis Today,2002,77:65. |
[4] | Huber G W;Iborra S;Corma A .[J].Chemical Reviews,2006,106:4044. |
[5] | Fang Zh;Minowa T;Fang Ch;Smith R L Jr Inomata H Kozinski J A .[J].International Journal of Hydrogen Energy,2008,33:981. |
[6] | Chen G;Andries J;Spliethoff H .[J].Energy Conversion and Management,2003,44:2289. |
[7] | Woodward J;Orr M;Cordray K;Greenbaum E .[J].Nature,2000,405:1014. |
[8] | Cortright RD;Davda RR;Dumesic JA .Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water.[J].Nature,2002(6901):964-967. |
[9] | Davda RR;Shabaker JW;Huber GW;Cortright RD;Dumesic JA .A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):171-186. |
[10] | Xie F Zh;Chu X W;Hu H R;Qiao M H Yan Sh R Zhu Y L He H Y Fan K N Li H X Zong B N Zhang X X .[J].Journal of Catalysis,2006,241:211. |
[11] | Zhu L J;Guo P J;Chu X W;Yan Sh R Qiao M H Fan K N Zhang X X Zong B N .[J].Green Chemistry,2008,10:1323. |
[12] | 白赢,卢春山,马磊,陈萍,郑遗凡,李小年.Ce和Mg改性的γ-Al2O3负载Pt催化剂催化乙二醇水相重整制氢[J].催化学报,2006(03):275-280. |
[13] | Liu X H;Shen K;Wang Y G;Wang Y Q Guo Y L Guo Y Yong Zh L Lu G Zh .[J].Catalysis Communications,2008,9:2316. |
[14] | Tanksale A;Beltramini JN;Dumesic JA;Lu GQ .Effect of Pt and Pd promoter on Ni supported catalysts - A TPR/TPO/TPD and microcalorimetry study[J].Journal of Catalysis,2008(2):366-377. |
[15] | Pagliaro M;Ciriminna R;Kimura H;Rossi M,Pina C D .[J].Angewandte Chemie International Edition,2007,46:4434. |
[16] | Wen G D;Xu Y P;Ma H J;Xu Zh Sh Tian Zh J .[J].International Journal of Hydrogen Energy,2008,33:6657. |
[17] | Lehnert K;Claus P .[J].Catalysis Communications,2008,9:2543. |
[18] | Luo N J;Fu X W;Cao F H;Xiao T C Edwards P P .[J].FUEL,2008,87:3483. |
[19] | Iriondo A;Barrio V L;Cambra J F;Arias P L Guemez M B Navarro R M Sanchez-Sanchez M C Fierro J L G .[J].Topics in Catalysis,2008,49:46. |
[20] | Davda R R;Dumesic J A.[J].Chemical Communications,2004:36. |
[21] | Xu Y P;Tian Zh J;Wen G D;Xu Zh Sh Qu W Lin L W .[J].Chemistry Letters,2006,35:216. |
[22] | Tanksale A;Wong Y;Beltramini J N;Lu G Q .[J].International Journal of Hydrogen Energy,2007,32:717. |
[23] | Hashaikeh R;Butler I S;Kozinski J A .[J].Energy and Fuels,2006,20:2743. |
[24] | Wen G D;Xu Y P;Xu Zh Sh;Tian Zh J .[J].Catalysis Letters,2009,129:250. |
[25] | Valenzuela M B;Jones C W;Agrawal P K .[J].Energy and Fuels,2006,20:1744. |
[26] | Che M;Bennett C O .[J].Advances in Catalysis,1989,36:55. |
[27] | Kip B J;Duivenvoorden F B M;Koningsberger D C;Prins R .[J].Journal of Catalysis,1987,105:26. |
[28] | Luo N J;Cao F H;Zhao X;Xiao T C Fang D Y .[J].Fuel,2007,06:1727. |
[29] | Watanabe M;Aizawa Y;Iida T;Levy C Aida T M Inomata H .[J].Carbohydrate Research,2005,340:1931. |
[30] | Shabaker J W;Huber G W;Davda R R;Cortright R D Dumesic J A .[J].Catalysis Letters,2003,88:1. |
[31] | Corma A;Iborra S;Velty A .[J].Chemical Reviews,2007,107:2411. |
[32] | Khajavi S H;Kimura Y;Oomori T;Matsuno R Adachi S .[J].Journal of Food Engineering,2005,68:309. |
[33] | Oomori T;Khajavi S H;Kimura Y;Adachi S Matsuno R .[J].Biochemical Engineering Journal,2004,18:143. |
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