The Raman spectra of 3% (mole fraction) Y2O3-ZrO2 (3Y) are obtained at different temperature from 77 K to 853 K. The results show that 260 cm-1 Eg and 460 cm-1 Eg modes on the spectra shift toward lower wave number with the increase of temperature; meanwhile, the continuity of the Half Width at Half Maximum (HWHM) and wave number (frequency) of Raman bands are broken and t-phase only partially transforms to m-phase at 523 K. Based on the experimental results, this paper discusses the t-phase lattice vibration of 3Y and presents the images of vibration displacement of six Raman-active modes for t-phase of ZrO2. The analysis indicates that there are diversities existing in the displacement of the atomic vibration of Raman-active modes because of their different symmetries at various temperature, which leads to the different change tendencies of Raman bands. Furthermore, the abrupt changes of some Raman-active modes indicating the atomic displacement are assumed to be the condensations of phonon modes in the t→m phase transition.
参考文献
[1] | GTeufer .[J].Acta Crystallographica,1962,15:1187. |
[2] | GKansal;AHHeuer .[J].Acta Materialia,1974,22(04):409. |
[3] | NNakanishi;TShigematsu .[J].MATERIALS TRANSACTIONS,1991,32(08):778. |
[4] | NNakanishi;TShigematsu;TFurukawa .[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1994,25(12):2647. |
[5] | WeizhongZHU;Tingquan LEI;Yu ZHOU .[J].Chinese Ceramic Society,1994,22(01):22. |
[6] | MPoulet;JPMathieu;Translated by ASimievic.Vebration Spectra Symmetry of Crystals[M].Gordon , Breach,Science Publishers,Inc,Chapt,1976:4-5. |
[7] | DCRoussean;RPBaumann;SPSPorto .[J].Journal of Raman Spectroscopy,1981,11(01):253. |
[8] | JCai;CRaptis;YSRaptis;EAnassakis .[J].Physical Review B,1995,51:201. |
[9] | DJKim .[J].American Ceramic Society Bulletin,1993,76(08):2106. |
[10] | DJKim .[J].American Ceramic Society Bulletin,1997,80(06):1453. |
[11] | DSteele;BEFFender .[J].Journal of Physics C:Solid State Physics,1974,7:1. |
[12] | PLi;IWChen .[J].Physical Review B,1993,48(14):10082. |
[13] | XiuhuaZHENG;Junwu SHEN .[J].Chinese Journal of Materials Research,1998,12(04):375. |
[14] | KNegita;HTakao .[J].Journal of Physics and Chemistry of Solids,1989,50(03):325. |
[15] | KNegita .[J].Acta Materialia,1989,37(01):313. |
[16] | APMirgorodsky;MBSmirnor .[J].Physical Review B,1995,52(13):9111. |
[17] | APMirgorodsky;MBSmirnor .[J].Physical Review B,1997,55(01):19. |
[18] | ApMirgorodsky;MBSmirnor .[J].Physical and Chemistry of Solids,1999,60:985. |
[19] | Pouvier;GLucazeau .[J].Journal of Physics and Chemistry of Solids,2000,61:569. |
[20] | AFeinerg;CHPerry .[J].Journal of Physics and Chemistry of Solids,1981,42:513. |
[21] | DMichel;MTVan Den Borre;AEnnaciri.[A].Advances in Ceramics The American Ceramic Society,Westerville,OH,1988:555-562. |
[22] | Morn;KHuang.Dynamical Theory of Crystal Lattices[M].Oxford University PressOsford,1954 |
[23] | SHChen .[J].Physical Review,1967,163:532. |
[24] | JFScott .[J].Reviews of Modern Physics,1974,46:83. |
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