分析了石墨烯的制备方法及其优缺点,为了实现大量生产石墨烯薄膜,提出了采用有机-无机转化方法制备石墨烯.将高分子量、低分子量分布的聚丙烯腈与二甲基亚砜配制成溶液,并制成分子结构为螺旋线性的截面形状为扁平的石墨烯薄膜带前驱体,前驱体经过热水、蒸汽牵伸(取向度高)、预氧化(环化和交联)和碳化(芳构化)后制成了石墨烯薄膜带.
参考文献
[1] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS .Graphene-based composite materials[J].Nature,2006(7100):282-286. |
[2] | 黄桂荣,陈建.石墨烯的合成与应用[J].炭素技术,2009(01):35-39. |
[3] | 黄毅,陈永胜.石墨烯的功能化及其相关应用[J].中国科学B辑,2009(09):887-896. |
[4] | 傅强,包信和.石墨烯的化学研究进展[J].科学通报,2009(18):2657-2666. |
[5] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666. |
[6] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
[7] | Meyer J C;Geim A K et al.The structure of suspended graphene sheets[J].Nature,2007,446(7131):60. |
[8] | Novoselov K S;Geim A K;Morozov S et al.Two-dimensional gas of massless Dirac fermions in graphene[J].Nature,2005,438(7065):197. |
[9] | Ni ZH;Wang HM;Kasim J;Fan HM;Yu T;Wu YH;Feng YP;Shen ZX .Graphene thickness determination using reflection and contrast spectroscopy[J].Nano letters,2007(9):2758-2763. |
[10] | Geim A K .Graphene:Status and prospects[J].Science,2009,324(5934):1530. |
[11] | Dato A;Radmilovic V;Lee ZH;Phillips J;Frenklach M .Substrate-free gas-phase synthesis of graphene sheets[J].Nano letters,2008(7):2012-2016. |
[12] | 杨永岗,陈成猛,温月芳,杨全红,王茂章.氧化石墨烯及其与聚合物的复合[J].新型炭材料,2008(03):193-200. |
[13] | Dikin, DA;Stankovich, S;Zimney, EJ;Piner, RD;Dommett, GHB;Evmenenko, G;Nguyen, ST;Ruoff, RS .Preparation and characterization of graphene oxide paper[J].Nature,2007(7152):457-460. |
[14] | Eda G;Fanchini G;Chhowalla M .Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material[J].Nature nanotechnology,2008(5):270-274. |
[15] | Choucair,Mohammad;Thordarson,Pall;Stride,John A. .Gram-scale production of graphene based on solvothermal synthesis and sonication[J].Nature nanotechnology,2009(1):30-33. |
[16] | 陈成猛,杨永岗,温月芳,杨全红,王茂章.有序石墨烯导电炭薄膜的制备[J].新型炭材料,2008(04):345-350. |
[17] | Tung, VC;Allen, MJ;Yang, Y;Kaner, RB .High-throughput solution processing of large-scale graphene[J].Nature nanotechnology,2009(1):25-29. |
[18] | Keun Soo Kim;Yue Zhao;Houk Jang;Sang Yoon Lee;Jong Min Kim;Kwang S. Kim;Jong-Hyun Ann;Philip Kim;Jae-Young Choi;Byung Hee Hong .Large-scale Pattern Growth Of Graphene Films For Stretchable Transparent Electrodes[J].Nature,2009(7230):706-710. |
[19] | 黄桂荣,陈建.化学分散法制备石墨烯及结构表征[J].炭素技术,2009(04):10-15. |
[20] | Li XL;Zhang GY;Bai XD;Sun XM;Wang XR;Wang E;Dai HJ .Highly conducting graphene sheets and Langmuir-Blodgett films[J].Nature nanotechnology,2008(9):538-542. |
[21] | Chong-an Di;Dacheng Wei;Gui Yu;Yunqi Liu;Yunlong Guo;Daoben Zhu .Patterned Graphene as Source/Drain Electrodes for Bottom-Contact Organic Field-Effect Transistors[J].Advanced Materials,2008(17):3289-3293. |
[22] | Wei, DC;Liu, YQ;Wang, Y;Zhang, HL;Huang, LP;Yu, G .Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties[J].Nano letters,2009(5):1752-1758. |
[23] | Wei, DC;Liu, YQ;Zhang, HL;Huang, LP;Wu, B;Chen, JY;Yu, G .Scalable Synthesis of Few-Layer Graphene Ribbons with Controlled Morphologies by a Template Method and Their Applications in Nanoelectromechanical Switches[J].Journal of the American Chemical Society,2009(31):11147-11154. |
[24] | Liying Jiao;Li Zhang;Xinran Wang;Georgi Diankov;Hongjie Dai .Narrow Graphene Nanoribbons From Carbon Nanotubes[J].Nature,2009(7240):877-880. |
[25] | 刘首鹏,周锋,金爱子,杨海方,马拥军,李辉,顾长志,吕力,姜博,郑泉水,王胜,彭练矛.人工裁剪制备石墨纳米结构[J].物理学报,2005(09):4251-4255. |
[26] | Yu-Jun Bai;Cheng-Guo Wang;Ning Lun .HRTEM microstructures of PAN precursor fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(9):1773-1778. |
[27] | Wang YX;Wang Q .Evaluation of carbonization tar in making high performance polyacrylonitrile-based carbon fibers[J].Journal of Applied Polymer Science,2007(2):1255-1259. |
[28] | Perret R;Ruland W .The microstructure of PAN-base carbon fibres[J].Journal of Appl Crystallog,1970,3(06):525. |
[29] | Bennett S C;Johnson D J .Electron-microscope studies of structural heterogeneity in PAN-based carbon fibres[J].CARBO,1979,17(01):25. |
[30] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%