为了改善玻璃纤维(GF)/乙烯基酯树脂(VER)复合材料的力学性能,将碳纳米管(CNTs)加入其中制得了碳纳米管/玻璃纤维/乙烯基酯树脂复合材料.然而,分别加入0.4wt％、0.8wt％、1.2wt％碳纳米管后,主要由基体贡献的层间剪切强度和纵向压缩强度分别从52.32MPa和258.34MPa下降到45.14MPa、50.11MPa、42.14MPa和240.99MPa、257.87MPa、235.27MPa,表明了碳纳米管的抗自由基效应对乙烯基酯树脂固化反应的抑制作用.通过添加另一种较高温分解的引发剂BPO进行补偿,其层间剪切强度和纵向压缩强度又分别提升到63.25MPa、70.35MPa、60.57MPa和299.12MPa、318.54MPa、280.11 MPa.动力机械热分析(DMA)也得到一致的结果,进一步证实了碳纳米管的抗自由基效应对复合材料力学性能的负面影响.
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