采用料浆包渗法,以SiO2粉为Si源,纯Al粉为还原剂,NaF和NH4Cl作为复合活化剂,Al2O3为惰性添加剂,蛋白质(鸡蛋清)为粘结剂,在Cu表面预先镀Ni层随后900℃、12h表面渗Si,制备渗Si层.分别研究了CeO2和Al粉含量对渗Si层组织和摩擦性能的影响.结果表明:当铝粉含量20%时,CeO2含量由3%增加到6%,渗层组织为Ni2Si+ NiSi相;当CeO2含量6%时,铝粉含量由20%增加到30%,渗层组织变化过程:Ni2Si+ NiSi→NiAl→Ni2Al3相,包渗过程由渗硅向渗铝转变;两种渗层的最小摩擦系数都约为纯铜的1/5.
参考文献
[1] | 孙远敬,岳立新,张雅玲.纯铜多元共渗及热处理工艺研究[J].煤矿机械,2006(06):1021-1022. |
[2] | 张毅,田保红,陈小红,高颖颖,刘平,李炎.纯铜稀土催渗渗铝及其内氧化[J].铸造技术,2006(03):255-257. |
[3] | 刘森林,石子源,王德庆,丁志敏,赵键.纯铜表面镍硼合金涂层的制备[J].大连铁道学院学报,2005(04):62-65. |
[4] | 袁庆龙,苏永安,徐重.纯铜双层辉光离子渗镍研究[J].真空科学与技术学报,2004(01):40-42. |
[5] | 张跃飞,陈飞,苏永安,潘俊德,徐重.纯铜加弧辉光离子渗钛的研究[J].金属热处理,2002(04):27-28. |
[6] | Bateni S M R;Mirdamadi F;Ashrafizadeh J A et al.Oxidation behaviour of titanium coated substrate[J].Surface and Coatings Technology,2001,139(2-3):192-199. |
[7] | Datta M K;Pabi S K;Murty B S et al.Thermal stability of nanocrystalline Ni silicides synthesized by mechanical alloying[J].Materials Science and Engineering A,2000,284:219-225. |
[8] | Wang HM.;Wang CM.;Cai LX. .Wear and corrosion resistance of laser clad Ni2Si/NiSi composite coatings[J].Surface & Coatings Technology,2003(2/3):202-208. |
[9] | Cai LX;Wang HM;Wang CM .Corrosion resistance of laser clad Cr-alloyed Ni2Si/NiSi intermetallic coatings[J].Surface & Coatings Technology,2004(2/3):294-299. |
[10] | 王春敏,蔡良续,王华明.激光熔覆Ni-Si金属硅化物复合材料涂层显微组织与耐蚀性[J].中国有色金属学报,2002(z1):183-187. |
[11] | Yoon JK.;Kim GH.;Byun JY.;Lee JK.;Kim JS.;Hong KT. .Kinetics of chemical vapor deposition of Si on Ni substrates from a SiCl4-H-2 gas precursor mixture[J].Surface & Coatings Technology,2003(1):65-71. |
[12] | Yoon JK.;Byun JY.;Kim GH.;Lee JK.;Yoon HS.;Hong KT. .Formation process and microstructural evolution of Ni-silicide layers grown by chemical vapor deposition of Si on Ni substrates[J].Surface & Coatings Technology,2003(2/3):241-248. |
[13] | 王红星,李迎光.Al含量对Cu基Ni镀层表面渗Si层组织和力学性能的影响[J].材料工程,2010(02):52-57. |
[14] | Wonhee Lee;Jinhyung Lee;Joong Dae Bae .SYNTHESES OF Ni_2Si, Ni_5Si_2, AND NiSi BY MECHANICAL ALLOYING[J].Scripta materialia,2001(1):97-103. |
[15] | Kim M T;Jung J S .Codeposition of Al and Si onto low carbon steel using silicon dioxide and aluminum and its hot temperature oxidation properties[J].Surface and Coatings Technology,2002,161(2-3):218-223. |
[16] | Pretorius R .Prediction of silicide formation and stability using heats of formation[J].Thin Solid Films,1996,290-291:477-484. |
[17] | Wang H X;Chu C L;Sheng X B et al.Effect Al content on microstructure and properties of an intermetallic Ni-Ti(Al) compound/Ni graded coating deposited on copper substrate[J].International Journal of Modern Physics B,2009,23(6-7):1916-1923. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%