采用TG分析测试阻燃SEBS共混材料的热分解过程,并用Friedman微分法和非线性回归进行动力学分析,探讨其热分解机理.分析结果表明,膨胀型与金属氢氧化物阻燃的SEBS共混材料的热分解过程为多步平行反应,极限氧指数随分解活化能的提高而提高.极限氧指数LOI测试表明,两体系能有效阻燃SEBS共混材料.
参考文献
[1] | HOLDEN G;LEGGE N R.hermoplastic Elastomers[M].Hanser/Gardner Publications,1996 |
[2] | Fernandes VJ.;Fernandes NS.;Fonseca VM.;Araujo AS.;Silva DR. .Kinetic evaluation of decabromodiphenil oxide as a flame retardant for unsaturated polyester[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2002(1/2):283-288. |
[3] | Fernandes VJ.;Araujo AS.;Fonseca VM.;Fernandes NS.;Silva DR. .Thermogravimetric evaluation of polyester/sisal flame retarded composite[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2002(special issue si):71-77. |
[4] | 王雪峰,吴荣梁,孙春梅,王幸宜,苏勇.膨胀型类磷酸酯蜜胺盐阻燃剂的合成及应用研究[J].功能高分子学报,2004(04):630-634. |
[5] | WARNER B .[P].US 4341694,1982-07-27. |
[6] | FRIEDMAN H L .[J].Journal of Polymer Letters,1966,4:323-328. |
[7] | VYAZOVKIN S;WIGHT C A .[J].Thermochimica Acta,1999,340-341:53-68. |
[8] | LARCEY P A;REDFEN J P;BELL G M .[J].Fire and Materials,1995,19:283-284. |
[9] | 王正洲,范维澄,瞿保钧,邵宗龙,周树华.含氢氧化镁的阻燃硅烷交联聚乙烯[J].功能高分子学报,2000(01):77-80. |
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