为了合理回收转炉钢渣中的铁,以临钢钢渣为原料,采用光谱半定量全分析、X衍射、扫描电镜、和电子探针等方法分析试样的物理化学和矿物特性,并对原渣的粒度和金属分布进行测定。结果表明:转炉钢渣中主要物相是硅酸二钙、硅酸三钙和熟石灰,含铁物相主要有金属态(Fe)、简单化合态(Fe2O3、Fe3O4、Fe2O3.nH2O和Fe-CO3等)、铁酸盐(2CaO.Fe2O3等)和固溶体(MgO.2FeO),全铁品位高达23.39%,分布比较分散;钢渣比较难磨且具有选择性破碎特性。研究结果为后续钢渣加工和综合利用提供了依据。
In order to recycle the iron resources in converter slag more reasonably,the tests were conducted on converter slag of Lin-fen Steel Limited Company as raw materials.The physicochemical and mineralogical properties of samples were analyzed by semiquantitative spectroscopic analysis,X-ray diffraction(XRD),scanning electron microscope(SEM) and electron-probe microanalyzer(EPMA),and the mineral phases and characteristics were studied,and the fineness of the ore grinding and the metal distribution ratio was determined by the grinding test.The results show that: the main phases are dicalcium silicate(C2S),tricalcium silicate(C3S) and hydrated lime in the slag;the phases of iron mainly comprised of metallic state(Fe),simplified combination(Fe2O3,Fe3O4,Fe2O3·nH2O and FeCO3 etc),ferrate(2CaO·Fe2O3 etc)and solid solution(MgO·2FeO);the content of the total iron is as high as 23.39% and dispersive in the steel slag;the slag is ground difficultly,and the grinding is processed selectively.The scientific basis would be provided for the subsequent processes and comprehensive utilization of slag.
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