欢迎登录材料期刊网

材料期刊网

高级检索

由壳聚糖和聚乙烯醇的醋酸水溶液共混,流延成膜,然后用1mol/L的NaOH水溶液处理,成功制得具有互穿网络结构的壳聚糖/聚乙烯醇二元共混膜.采用红外光谱、X射线衍射和扫描电镜对共混膜进行了结构表征,并对共混膜的透光率、吸水率、保水率、力学性能、透水汽率、热稳定性等方面进行了测试.结果表明,共混膜中壳聚糖与聚乙烯醇具有良好的相容性,其中壳聚糖与聚乙烯醇分子间的作用力使共混膜理化性能得到了显著改善.

参考文献

[1] Bernkop S A;Hornof M;Guggi D .Thiolated chitosaus[J].European Journal of Pharmaceutics and Biopharmaceutics,2004,57(01):9.
[2] Kerec M;Bogataj M;Veranic P;Mrhar A .Permeability of pig urinary bladder wall: the effect of chitosan and the role of calcium.[J].European journal of pharmaceutical sciences,2005(1):113-121.
[3] Jessica D.Schiffman;Caroline L.Schauer .One-Step Electrospinning of Cross-Linked Chitosan Fibers[J].Biomacromolecules,2007(9):2665-2667.
[4] Luciano C;Felippe J P;Thatyane M N et al.Chitosan as a removing agent of β-lactnglobulin from membrane models[J].Langmuir,2008,24(08):4150.
[5] 陈莉,李世庚,肖飞,张爱华,姚康德.温敏性壳聚糖共聚膜的制备与细胞吸附/脱附行为[J].高等学校化学学报,2008(05):1061-1064.
[6] Park IK.;Yang J.;Jeong HJ.;Bom HS.;Harada I.;Akaike T.;Kim S.;Cho CS. .Galactosylated chitosan as a synthetic extracellular matrix for hepatocytes attachment[J].Biomaterials,2003(13):2331-2337.
[7] 李沁华,张文宇.聚乙烯醇-海藻酸钙复合材料制备及性质[J].暨南大学学报(自然科学与医学版),2001(03):81-85.
[8] Xu Caixia;Chen Riyao;Zheng Xi et al.Preparation of PVA-GA-CS/PVA-Fe-SA bipolar membran and its application inelectro-generation of 2,2-dimethyl-3-hydroxypropionic acid[J].Journal of Membrane Science,2008,307(02):218.
[9] Yeo JH;Lee KG;Kim HC;HYL;Kim AJ;Kim SY .The effects of Pva/chitosan/fibroin (PCF)-blended spongy sheets on wound healing in rats.[J].Biological & pharmaceutical bulletin,2000(10):1220-1223.
[10] Yingshan Zhou;Dongzhi Yang;Xiangmei Chen .Electrospun Water-Soluble Carboxyethyl Chitosan/Poly(vinyl alcohol)Nanofibrous Membrane as Potential Wound Dressing for Skin Regeneration[J].Biomacromolecules,2008(1):349-354.
[11] Kim D J;Park I S;Lee M H .Tensile strength of aqueousbased alumina tapes using a PVP-PVA-gelatin cobinder[J].Ceramics International,2005,31(04):577.
[12] Ho Minghua;Wang Darning;Hsyucjen Hsich et al.Preparation and characterization of RGD-immobilized chitosan scaffolds[J].Biomaterials,2005,26:3197.
[13] 叶易春,但卫华,曾睿,林海,米贞健,但年华,关林波.胶原与壳聚糖分子间的作用力[J].高分子材料科学与工程,2007(05):112-115.
[14] Ye YC;Dan WH;Zeng R;Lin H;Dan NH;Guan LB;Mi ZJ .Miscibility studies on the blends of collagen/chitosan by dilute solution viscometry[J].European Polymer Journal,2007(5):2066-2071.
[15] Sawatari Chie;Kondo Tetsuo .Interchain hydrogen bonds in blend films of poly(vinyl alcohol) and its derivatives with poly(ethylene oxide)[J].Macromolecules,1999(6):1949-1955.
[16] 柳明珠;程熔时;钱人元.聚乙烯醇水凝胶溶涨特性研究[J].高分子学报,1996(02):234.
[17] Weaver K D;Stuffer J O;Day D E .Preparation and properties of optically transparent,pressured-cured poly (methyl methacrylate) composities[J].Polymer Composites,1993,14(03):515.
[18] Mi FL;Shyu SS;Wu YB;Lee ST;Shyong JY;Huang RN .Fabrication and characterization of a sponge-like asymmetric chitosan membrane as a wound dressing.[J].Biomaterials,2001(2):165-173.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%