欢迎登录材料期刊网

材料期刊网

高级检索

采用电位阶跃技术研究在H2S和CO2共存的近中性溶液中套管钢/溶液界面和反应过程.应用数学模型分析界面反应中氢吸附过程、负离子脱附过程和氢吸收过程的变化规律.当阶跃电位为50 mV,界面反应由氢吸附过程控制,当阶跃电位超过50 mV,界面反应由负离子脱附过程控制.研究显示,在含50% H2S(pH=5.9)环境中,加入CO2提高了界面负离子脱附、氢吸附和氢吸收反应速率.

参考文献

[1] 沈琛,张忠铧,张春霞.高酸性腐蚀气田用BG2250-125镍基合金油管开发[J].中国工程科学,2010(10):35-38.
[2] 刘绘新,苏永平.川东气田油管腐蚀现象的基本特征[J].天然气工业,2000(05):77-78,79.
[3] Wandlowski T.;Lindsay SM.;Lampner D. .STRUCTURE AND STABILITY OF CYTOSINE ADLAYERS ON AU(111) - AN IN-SITU STM STUDY[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1996(2):215-226.
[4] S. Pronkin;Th. Wandlowski .Time-resolved in situ ATR-SEIRAS study of adsorption and 2D phase formation of uracil on gold electrodes[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2003(0):131-147.
[5] M. Hara;U. Linke;Th. Wandlowski .Preparation and electrochemical characterization of palladium single crystal electrodes in 0.1 M H{sub}2SO{sub}4 and HClO{sub}4 - Part I: low-index phases[J].Electrochimica Acta,2007(18):5733-5748.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%