以固体氧化物燃料电池(SOFC)金属连接体为研究对象,分析了SUS 430铁素体不锈钢和Haynes 230合金在阴极气氛(空气)中模拟SOFC的高温氧化行为.利用薄膜X射线衍射技术研究了合金氧化物的相组成及演化过程,通过扫描电镜观察分析了合金氧化物表面的微观形貌和厚度.结果表明,两种合金的表面均形成了多层氧化物,它们依次为基体/Cr2O3/MnCr2O4尖晶石相.两种氧化物相分别形成于不同的氧化动力学阶段.氧化动力学外推和氧化物面比电阻估算结果表明,两种合金的高温氧化和导电性能均可满足作为SOFC金属连接体的使用要求.
参考文献
| [1] | Singh P;Minh N Q .Solid Oxide Fuel Cells:Technology Status[J].International Journal of Applied Ceramic Technology,2004,1(01):5-15. |
| [2] | Foger K;Love J G .Fifteen Years of SOFC Development in Australia[J].Solid State Ionics,2004,174(1-4):119-126. |
| [3] | Zhu W Z;Deevi S C .Development of Interconnect Materials for Solid Oxide Fuel Cells[J].Materials Science and Engineering,2003,348(1-2):227-243. |
| [4] | Yasuda I.;Hishinuma M. .ELECTROCHEMICAL PROPERTIES OF DOPED LANTHANUM CHROMITES AS INTERCONNECTORS FOR SOLID OXIDE FUEL CELLS[J].Journal of the Electrochemical Society,1996(5):1583-1590. |
| [5] | Xsouza S De;Visco S J;Jonghe LC De .Reduced-Temperature Solid Oxide Fuel Cell Based on YSZ Thin-Film Electrolyte[J].Journal of the Electrochemical Society,1997,144(03):L35-L37. |
| [6] | Y.J. Leng;S.H. Chan;K.A. Khor;S.P. Jiang .Performance evaluation of anode-supported solid oxide fuel cells with thin film YSZ electrolyte[J].International journal of hydrogen energy,2004(10):1025-1033. |
| [7] | Huang KQ.;Goodenough JB.;Tichy R. .Superior perovskite oxide-ion conductor; strontium- and magnesium-doped LaGaO3: III, Performance tests of single ceramic fuel cells[J].Journal of the American Ceramic Society,1998(10):2581-2585. |
| [8] | Meulenberg WA.;Uhlenbruck S.;Wessel E.;Buchkremer HP.;Stover D. .Oxidation behaviour of ferrous alloys used as interconnecting material in solid oxide fuel cells[J].Journal of Materials Science,2003(3):507-513. |
| [9] | W.Z.Zhu;S.C.Deevi .Opportunity of metallic interconnects for solid oxide fuel cells: a status on contact resistance[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2003(6):957-972. |
| [10] | Brylewski T.;Maruyama T.;Przybylski K.;Nanko M. .Application of Fe-16Cr ferritic alloy to interconnector for a solid oxide fuel cell[J].Solid state ionics,2001(2):131-150. |
| [11] | Marasco A L;Young D J .The Oxidation of Iron-ChromiumManganese Alloys at 900 ℃[J].Oxidation of Metals,1991,36(1-2):157-174. |
| [12] | England D;Virkar A .Oxidation Kinetics of Some NickelBased Superalloy Foils and Electronic Resistance of the Oxide Scale Formed in Air[J].Journal of the Electrochemical Society,1999,146:3196-3202. |
| [13] | England D;Virkar A .Oxidation Kinetics of Some NickelBased Superalloy Foils in Humidified Hydrogen and Electronic Resistance of the Oxide Scale Formed[J].Journal of the Electrochemical Society,2001,A148:330-338. |
| [14] | PU Jian;LI Jian;HUA Bing et al.Oxidation Kinetics and Phase Evolution of a Fe-16Cr Alloy in Simulated SOFC Cathode Atmosphere[J].Journal of Power Sources,2006,158(01):354-360. |
| [15] | LI Jian;PU Jian;HUA Bing et al.Oxidation Kinetics of Haynes 230 Alloy in Air at Temperatures Between 650 and 850 ℃[J].Journal of Power Sources,2006,159(01):641-685. |
| [16] | Lobnig R E;Schmidt H P;Hennesen K .Diffusion of Cations in Chromia Layers Grown on Iron-Base Alloys[J].Oxidation of Metals,1992,37(1-2):81-93. |
| [17] | Samsonov G V.The Oxide Handbook[M].New York:IFI/Plenum,1973 |
| [18] | Virkar A V;England Diane M .Solid Oxide Fuel Cell Iinterconnecter[P].US 6054231,2000-04-15. |
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