采用助溶剂和硅烷偶联剂(Z-6040)对碱性硅溶胶进行复合改性后添加到聚丙烯酸酯乳液中制备SiO2/聚丙烯酸酯杂合乳液(Si/PAE),分别考查助溶剂的种类和用量对硅溶胶的溶胶-凝胶化(sol-gel)反应及复合涂层综合性能的影响,结果发现:异丙醇是合适的助溶剂,其最佳添加量为硅溶胶质量的10%.TEM测试和纳米粒径分析发现:助溶剂可以提高无机硅颗粒在杂合乳液中的分散能力,降低Si/PAE的平均粒径.傅里叶红外光谱(FT-IR)和原子力显微镜(AFM)分析说明:Si/PAE乳液在成膜过程中,助溶剂可驱使硅溶胶发生sol-gel反应,并在涂层表面富集含硅聚合物,Si/PAE的涂层结构平整且致密.TGA分析发现:Si/PAE涂层具有较好的热稳定性.
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