常用金属表面缓蚀自组装膜及其研究方法

中国腐蚀与防护学报, 2012, 32(4): 273-284.

常用金属表面缓蚀自组装膜及其研究方法

基金项目: 国家自然科学基金(51001045)和湖北省自然科学基金(2009CDB347)资助

关键词：活性金属 , inhibitive self-assembled monolayers , assembling systems, influencing factors , characterization methods , null

INHIBITIVE SELF-ASSEMBLED MONOLAYERS ON SURFACES OF COMMONLY-USED METALS AND RELATED RESEARCH METHODS

WANG Hairen , JIANG Yan , QU Jun'e , LI Wenwei , CHEN Feng , ZHANG Qiang

Keywords： commonly-used active metals , 缓蚀自组装膜 , 自组装体系 , 影响因素 , 研究方法

简要介绍了常用活性金属表面主要涉及的缓蚀自组装膜体系以及缓蚀膜自组装行为的主要影响因素，并重点综述了电化学方法、谱学技术、显微镜技术以及接触角测试等研究方法在活性金属表面缓蚀自组装膜研究领域的应用。

Constructing inhibitive self-assembled monolayers on metal surfaces is a new kind of anticorrosion method developed in recent years. The research objects have been changed gradually from inert metals (such as gold and platinum) to commonly-used active metals and their alloys. In this paper, the mainly involved assembling systems for common active metals and the major influencing factors on the self-assembling behavior of inhibitor molecules are introduced, and the characterization methods for investigation of inhibitive self-assembled monolayers, including electrochemical means, spectroscopes, microscopes and contact angle measurement etc, are reviewed.

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