通过述评纳米洋葱状富勒烯的结构、制备、生长机理、纯化、修饰及性能,指出:纳米洋葱状富勒烯具有独特的中空笼状及同心壳层结构,是富勒烯家族的一个重要成员,具有许多特殊性能,有望在能源材料、高性能、高温耐磨材料、超导材料和生物医用材料等领域得到广泛的应用.
As an important member of the fullerene family,nano onion-like fullerenes (NOLFs) have a unique hollow cage and concentric shell structure,which endow them with some special properties.Based on these properties,many potential applications,such as energy storage materials,high-performance and high-temperature wear-resistance materials,superconductive materials and biomaterials,have been widely proposed.This review summarizes some of the major achievements in the field of NOLFs,including structure,preparation,growth mechanism,purification,functionalization,and properties.Possible applications are also suggested.
参考文献
| [1] | Ugarte D .Curling and closure of graphitic networks under electron-beam irradiation[J].Nature,1992,359(6397):707-709. |
| [2] | N. Sano;H. Wang;I. Alexandrou;M. Chhowalla;K. B. K. Teo;G. A. J. Amaratunga;K. Iimura .Properties of carbon onions produced by an arc discharge in water[J].Journal of Applied Physics,2002(5):2783-2788. |
| [3] | Chhowalla M.;Wang H.;Sano N.;Teo KBK.;Lee SB.;Amaratunga GAJ. .Carbon onions: Carriers of the 217.5 nm interstellar absorption feature - art. no. 155504[J].Physical review letters,2003(15):5504-0. |
| [4] | Henrard L.;Rudolf P.;Hevesi K.;Caudano R.;Lambin P. Cabioc'h T.;Malengreau F. .Electron-energy-loss spectroscopy of plasmon excitations in concentric-shell fullerenes[J].Physical Review.B.Condensed Matter,1999(8):5832-5836. |
| [5] | Pichler T;Knupfer M;Golden M S et al.Cabioc'h T,Electronic structure and optical propeaies of concentric-shell fullerenes from electron-energy-loss spectroscopy in transmission[J].Physical Review B,2001,63(1-5):155415. |
| [6] | Chen C P;Chang T H;Wang T F .Synthesis of magnetic nanocomposite particles[J].Ceramics International,2002,28(08):925-930. |
| [7] | Lee GH.;Huh SH.;Jeong JW.;Ri HC. .Excellent magnetic properties of fullerene encapsulated ferromagnetic nanoclusters[J].Journal of Magnetism and Magnetic Materials,2002(3):404-411. |
| [8] | 葛爱英,许并社,王晓敏,李天保,韩培德,刘旭光.洋葱状富勒烯电磁特性的研究[J].物理化学学报,2006(02):203-208. |
| [9] | Atsushi Hirata;Masaki Igarashi;Takahiro Kaito .Study on solid lubricant properties of carbon onions produced by heat treatment of diamond clusters or particles[J].Tribology International,2004(11/12):899-905. |
| [10] | Street K W;Marchetti M;Vandar W R L et al.Evaluatioh of the tribological behavior of nano-onions in Krytox 143AB[J].Tribology Letters,2004,16(1-2):143-149. |
| [11] | N. Matsumoto;L. Joly-Pottuz;H. Kinoshita .Application of onion-like carbon to micro and nanotribology[J].Diamond and Related Materials,2007(4/7):1227-1230. |
| [12] | 王晓敏,郭俊杰,贾虎生,刘旭光,市野濑英喜,许并社.金属/洋葱状富勒烯的HRTEM与光学性能研究[J].电子显微学报,2005(04):265. |
| [13] | 王晓敏 .纳米洋葱状富勒烯的大量制备和性能研究[D].太原理工大学,2005. |
| [14] | 杨晓伟,郭俊杰,王晓敏,刘旭光,许并社.Pt/洋葱状富勒烯催化剂的表征及生成机理研究[J].物理化学学报,2006(08):967-971. |
| [15] | Bingshe Xu;Xiaowei Yang;Xiaomin Wang .A novel catalyst support for DMFC: Onion-like fullerenes[J].Journal of Power Sources,2006(1):160-164. |
| [16] | GUO Junjie,YANG Xiaowei,YAO Yanli,WANG Xiaomin,LIU Xuguang,XU Bingshe.Pt/onion-like fullerenes as catalyst for direct methanol fuel cell[J].稀有金属（英文版）,2006(z1):305-308. |
| [17] | S.A. Maksimenko;V.N. Rodionova;G.Ya. Slepyan .Attenuation of electromagnetic waves in onion-like carbon composites[J].Diamond and Related Materials,2007(4/7):1231-1235. |
| [18] | Iijima S .Direct observation of the tetrahedral bonding in graphitized carbon black by high-resolution electronmicroscopy[J].Journal of Crystal Growth,1980,50(03):675-683. |
| [19] | Xu B S;Tanaka S I.Pt cluster bonding and fullerene formation in HRTEM[A].北京,1995:A33-A34. |
| [20] | Xu B S;Tanaka S I.Multiple-nulei onion-like fullerenes cultivated by electron beam irradiation[M].Cambridge,1997:355-360. |
| [21] | Xu B S;Tanka S I .Formation of giant onion-like fullerenes under Al nanoparficles by electron irradiation[J].Acta Materials,1998,46(15):5249-5257. |
| [22] | 郭俊杰,王晓敏,李天保,刘旭光,许并社,市野濑英喜.水下电弧放电法制备洋葱状富勒烯[J].新型炭材料,2006(02):171-175. |
| [23] | 李天保,刘光焕,刘旭光,许并社,市野濑英喜.内包铁洋葱状富勒烯的合成和表征[J].材料热处理学报,2005(03):28-30. |
| [24] | Sano N;Wang H;Chhowalla M et al.Synthesis of carbon'onions'in water[J].Nature,2001,414(6863):506-507. |
| [25] | 许并社,闫小琴,王晓敏,市野濑英喜,解思深.电弧放电中纳米洋葱状富勒烯生成机理的研究[J].材料热处理学报,2001(04):9-12. |
| [26] | 王晓敏,许并社,刘旭光,市野濑英喜.纳米金属微粒催化制备的洋葱状富勒烯的结构表征[J].新型炭材料,2004(03):209-213. |
| [27] | 许并社,王晓敏,韩培德,贾虎生,刘旭光,市野濑英喜.富勒烯形貌的多样性及超微观结构[J].电子显微学报,2004(06):613-617. |
| [28] | 章海霞,王晓敏,刘旭光,王海英,许并社.氧化物催化电弧法制备洋葱状富勒烯的研究[J].电子显微学报,2004(04):375-375. |
| [29] | 王晓敏,刘旭光,李天保,张艳,许并社.洋葱状富勒烯的拉曼散射[J].物理化学学报,2004(07):731-734. |
| [30] | 章海霞,王晓敏,王海英,刘旭光,许并社.电弧法制备洋葱状富勒烯的工艺研究[J].新型炭材料,2004(01):61-64. |
| [31] | 刘雯,杨永珍,张艳,刘旭光,王晓敏,许并社.液苯介质放电制备洋葱状富勒烯[J].新型炭材料,2007(01):84-87. |
| [32] | B. Xu;J. Guo;X. Wang .Synthesis of carbon nanocapsules containing Fe, Ni or Co by arc discharge in aqueous solution[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(13):2631-2634. |
| [33] | Guo JJ;Wang XM;Yao YL;Yang XW;Liu XG;Xu BS .Structure of nanocarbons prepared by arc discharge in water[J].Materials Chemistry and Physics,2007(2/3):175-178. |
| [34] | Wang XM;Xu BS;Liu XG;Jia HS;Hideki I .The Raman spectrum of nano-structured onion-like fullerenes[J].Physica, B. Condensed Matter,2005(3/4):277-281. |
| [35] | Oku T;Nailta I;Nishiwaki A .Formation,atomic structural optimization and electronic stnlctures of tetrahedral carbon onion[J].Diamond and Related Materials,2004,13(4-8):1337-1341. |
| [36] | Noriaki Sano;Hiroshi Akazawa;Takeyuki Kikuchi .Separated synthesis of iron-included carbon nanocapsules and nanotubes by pyrolysis of ferrocene in pure hydrogen[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(11):2159-2162. |
| [37] | 李天保,许并社,韩培德,张艳,王晓敏,刘旭光,市野濑英喜.洋葱状富勒烯的CCVD法制备及其形貌特征[J].新型炭材料,2005(01):23-27. |
| [38] | 李天保,许并社,韩培德,张艳,刘旭光.内包碳化铁洋葱状富勒烯的合成和表征[J].高等学校化学学报,2005(07):1222-1224. |
| [39] | 张凌,杨晓伟,王晓敏,李天保,刘旭光,许并社.环己烷制备内包金属洋葱状富勒烯的研究[J].材料导报,2007(01):148-149. |
| [40] | X. Wang;B. Xu;X. Liu .Synthesis of Fe-included onion-like Fullerenes by chemical vapor deposition[J].Diamond and Related Materials,2006(1):147-150. |
| [41] | Wang XM;Xu BS;Jia HS;Liu XG;Hideki I .HRTEM and Raman study of onion-like fullerenes encapsulated Fe[J].The journal of physics and chemistry of solids,2006(4):871-874. |
| [42] | BingShe Xu;TianBao Li;PeiDe Han .Several features of the iron-included onion-like fullerenes[J].Materials Letters,2006(16):2042-2045. |
| [43] | Yang Y;Liu X;Xu B .Fe-encapsulating carbon nano onionlike fullerenes from heavy oil residue[J].Journal of Materials Research,2008(5):1393-1397. |
| [44] | 杜爱兵,刘旭光,许并社.煤基纳米洋葱状富勒烯制备及其结构表征[J].无机材料学报,2005(04):779-784. |
| [45] | Liu X G;Du A B;Fu D J.Coal-derived onion-like fullerenes by radio frequency plasma[A].Korea,2005:101-102. |
| [46] | 符冬菊,刘旭光,杜爱兵,韩培德,贾虎生,许并社.微波等离子体法合成洋葱状富勒烯的研究[J].无机材料学报,2006(03):576-582. |
| [47] | Du Ai-bing;Liu Xu-guang;Fu Dong-ju et al.Onion-like fallerenes synthesis from coal[J].Fuel,2007,86(1-2):294-298. |
| [48] | Li Y.B.;Wei B.Q.;Liang J.;Yu Q.;Wu .Transformation of carbon nanotubes to nanoparticles by ball milling process[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(3):493-497. |
| [49] | Huang J Y;Yasuda H;Mori H .Highly curved nanostructures produced by ball milling[J].Chemical Physics Letters,1999,303(1-2):130-134. |
| [50] | Cabioch T.;Delafond J.;Riviere JP. .A NEW TECHNIQUE FOR FULLERENE ONION FORMATION[J].Journal of Materials Science,1995(19):4787-4792. |
| [51] | T. Cabioc'h;E. Thune;J. P. Riviere;S. Camelio;J. C. Girard;P. Guerin;M. Jaouen;L. Henrard;Ph. Lambin .Structure and properties of carbon onion layers deposited onto various substrates[J].Journal of Applied Physics,2002(3):1560-1567. |
| [52] | Cabioc'h T.;Jaouen M.;Thune E. .Carbon-onion thin-film synthesis onto silica substrates[J].Chemical Physics Letters,2000(1/2):202-205. |
| [53] | Bingshe Xu;Yantao Fan;Guanghuan Liu .Controlled growth of endohedral-metal carbon onions by pre-molding synthesis[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(9):1851-1853. |
| [54] | Weize Wu;Zhenping Zhu;Zhenyu Liu;Yaing Xie;Jing Zhang;Tiandou Hu .Preparation of carbon-encapsulated iron carbide nanoparticles by an explosion method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(2):317-321. |
| [55] | 王海英 .爆炸-真空热处理条件下纳米洋葱状富勒烯的形成[D].太原理工大学,2004. |
| [56] | Yi Lu;Zhenping Zhu;Zhenyu Liu .Carbon-encapsulated Fe nanoparticles from detonation-induced pyrolysis of ferrocene[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(2):369-374. |
| [57] | Kuzaetsov V L;Chuvilin A L;Butenko Y V et al.Onion-like carbon from ultra-disperse diamond[J].Chem Plays Lett,1994,222(04):343-348. |
| [58] | Ugarte D .High-temperature behavior of"fullerene black"[J].CARBON,1994,32(07):1245-1248. |
| [59] | 张艳,赵兴国,陆路,郭瑞萍,许并社.纳米洋葱状富勒烯的制备方法及生长机理[J].太原理工大学学报,2003(04):383-386. |
| [60] | 张艳,赵兴国,许并社.热处理制备碳纳米洋葱状富勒烯的研究[J].太原理工大学学报,2004(03):276-278. |
| [61] | Selvan R.;Ganapathy S.;Pradeep T.;Unnikrishnan R. .Macroscopic synthesis and characterization of giant fullerenes[J].Chemical Physics Letters,2000(3-4):205-210. |
| [62] | Eser S.;Pradhan BK.;Altin O. .Formation of carbon nanotubes from jet fuel on superalloys at moderate temperature and high pressure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(10):1512-1515. |
| [63] | Grieco WJ.;Rainey LC.;Vander Sande JB.;Howard JB. .Fullerenic carbon in combustion-generated soot[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(4):597-614. |
| [64] | M.Pontier Johnson;J.B.Donnet;T.K.Wang;C.C.Wang;R.W.Locke;B.E.Brinson;T.Maarriott .A dynamic continum of nanostrucutred carbons in the combustion furnace[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(2):189-194. |
| [65] | Oku T;Kuno M;Kitahara H et al.Formation,atomic structures and properties of boron nitride and carbon nanocage fullemne materials[J].International Journal of Inorganic Materials,2001,3(07):597-612. |
| [66] | Yuki Kimura;Takeshi Sato;Chihiro Kaito .Production and structural characterization of carbon soot with narrow UV absorption feature[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(1):33-38. |
| [67] | Gorelik T.;Urban S.;Falk F.;Kaiser U.;Glatzel U. .Carbon onions produced by laser irradiation of amorphous silicon carbide[J].Chemical Physics Letters,2003(5-6):642-645. |
| [68] | G. Radhakrishnan;P.M. Adams;L.S. Bernstein .Plasma characterization and room temperature growth of carbon nanotubes and nano-onions by excimer laser ablation[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(19):7651-7655. |
| [69] | Song HH.;Chen XH. .Large-scale synthesis of carbon-encapsulated iron carbide nanoparticles by co-carbonization of durene with ferrocene[J].Chemical Physics Letters,2003(3-4):400-404. |
| [70] | Huaihe Song;Xiaohong Chen;Xuegang Chen;Songyuan Zhang;Hangquan Li .Influence of ferrocene addition on the morphology and structure of carbon from petroleum residue[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(15):3037-3046. |
| [71] | Zhao M;Song H H;Chen X H.Large-scale synthesis of onion-like carbon nanoparticles by carbonization of phenolic resin[J].Acta Materialia,2007 |
| [72] | 郁军,许并社,杨永珍,张艳,刘旭光.热处理脱油沥青制备内包金属纳米碳洋葱[J].材料热处理学报,2007(z1):296-298. |
| [73] | Saito Y;Yoshikawa T;Inagaki M .Growth and structure of graphitic tubules and polyhedral particles in arc-discharge[J].Chemical Physics Letters,1993,204(3-4):277-282. |
| [74] | 葛爱英 .纳米洋葱状寓勒烯的制备及其电磁特性的研究[D].太原:太原理工大学,2006. |
| [75] | 蔺娴 .纳米洋葱状富勒烯的制备及其表面化学修饰的研究[D].太原理工大学,2007. |
| [76] | Feng Ding;Arne Rosen;Eleanor E.B.Campbell;Lena K.L.Falk;Kim Bolton .Graphitic Encapsulation of Catalyst Particles in Carbon Nanotube Production[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(15):7666-7670. |
| [77] | 杨永珍 .重油残渣定向转化新型碳功能材料的研究[D].太原理工大学,2007. |
| [78] | Qiu JS.;Wang LN.;Tsang SC.;Zhou Y. .Formation of carbon nanotubes and encapsulated nanoparticles from coals with moderate ash contents[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(4):465-467. |
| [79] | Jieshan Qiu;Yongfeng Li;Yunpeng Wang .High-purity single-wall carbon nanotubes synthesized from coal by arc discharge[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(11):2170-2173. |
| [80] | 鲍慧强,韩培德,李天保,贾虎生,刘旭光,许并社.洋葱状富勒烯的提纯研究[J].物理化学学报,2005(03):296-299. |
| [81] | 孙瑞平,刘光焕,李天保,韩培德,刘旭光,许并社.洋葱状富勒烯的制备与提纯[J].材料导报,2006(z1):206-207,210. |
| [82] | Vasilios Georgakilas;Drik M. Guldi;Raffaella Signorini;Renato Bozio;Maurizio Prato .Organic Functionalization and Optical Properties of Carbon Onions[J].Journal of the American Chemical Society,2003(47):14268-14269. |
| [83] | Arno S.Rettenbacher;Bevan Elliott;Armen Amirkhanian;Luis Echegoyen;Joan S.Hudson .Preparation and Functionalization of Multilayer Fullerenes (Carbon Nano-Onions)[J].Chemistry: A European journal,2006(2):376-387. |
| [84] | Rettenbacher AS;Perpall MW;Echegoyen L;Hudson J;Smith DW .Radical addition of a conjugated polymer to multilayer fullerenes (carbon nano-onions)[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(6):1411-1417. |
| [85] | Liu Y;Vander Wal RL;Khabashesku VN .Functionalization of carbon nano-onions by direct fluorination[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(4):778-786. |
| [86] | 许并社,孙瑞平,韩培德,李天保,王晓敏,刘旭光.洋葱状富勒烯的表面化学修饰[J].高等学校化学学报,2006(08):1404-1408. |
| [87] | Liu X G;Yang Y Z;Ji W Y.Purifieation and chemical modification of onion-like fullerenes[A].,2007 |
| [88] | Hou SM.;Zhang GM.;Zhao XY.;Xue ZQ.;Shi ZJ.;Gu ZN.;Tao CG. .Ultrahigh vacuum scanning probe microscopy studies of carbon onions[J].Physica, E. Low-dimensional systems & nanostructures,2001(2):300-304. |
| [89] | Tribological property of onion-like fullerenes as lubricant additive[J].Materials Letters,2008(15):2524-2527. |
| [90] | L. Joly-Pottuz;N. Matsumoto;H. Kinoshita;B. Vacher;M. Belin;G. Montagnac;J. M. Martin;N. Ohmae .Diamond-derived carbon onions as lubricant additives[J].Tribology International,2008(2):69-78. |
| [91] | Chai Y;Guo T;Jin C et al.Fullerenes with metals inside[J].J Plays Chem,1991,95(20):7564-7568. |
| [92] | Xu BS;Han P;Liang J;Liu XG;Bao HQ;Li TB;Chen MW;Ichinose H .Theoretical investigation of the reflectivity of fullerene-(C-60, C-70)/AlN multilayers in UV region[J].Solid State Communications,2005(6):353-356. |
| [93] | Huang YH.;Tanaka K.;Yamabe T.;Okada M. .ESTIMATION OF SUPERCONDUCTING TRANSITION TEMPERATURE IN METALLIC CARBON NANOTUBES[J].Physical Review.B.Condensed Matter,1996(9):5129-5132. |
| [94] | Subramoney S. .Novel nanocarbons - Structure, properties, and potential applications [Review][J].Advanced Materials,1998(15):1157-1171. |
| [95] | Philip Ball .Diamonds 'melted'inside an onion[J].Nature (News),2007,448(07):396-397. |
| [96] | Zhou JF;Shen ZY;Hou SM;Zhao XY;Xue ZQ;Shi ZJ;Gu ZN .Adsorption and manipulation of carbon onions on highly oriented pyrolytic graphite studied with atomic force microscopy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(6):3237-3241. |
| [97] | Huffman D R .Ten years of teaching with fullerenes.Electrochemical Society 2000[R].,2000-1. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%