欢迎登录材料期刊网

材料期刊网

高级检索

将链式硬球模型流体方程用于计算实际高密度流体的自扩散系数,并与流体的试验数据或模拟数据相比较.使用该方程计算碳链长度在150以下压力在200 MPa以下,平均温度在100 K以上时,非极性自扩散系数的平均绝对偏差多为5%左右.

参考文献

[1] Hirschfelder J O C F;Bird R B.Molecular Theory of Gases and Liquidds[M].New York: John Wiley & Sons; Inc,1954
[2] Dymond J H .Hard Sphere Theories of Transport Properties[J].Journal of the Chemical Society Rev,1985,14(02):317-359.
[3] Yang-Xin Yu;Guang-Hua Gao .Self-diffusion Coefficient Equation for Polyatomic Fluid[J].Fluid Phase Equilibria,1999(1):111-124.
[4] Yu YX.;Gao GH.;Han MH. .Self-diffusion in a fluid of square-well spheres[J].Physical chemistry chemical physics: PCCP,2001(3):437-443.
[5] Smith S W;Hall C K;Freeman B-D .Molecular Dynamics Study of Transport Coefficients for Hard-Chain Fluids[J].Journal of Chemical Physics,1995,102(02):1057-1073.
[6] Harris KR;Trappeniers NJ .Self-Diffusion in the Com pressed Fluid Lower Alkanes[J].PHYSICA A,1980,104(01):262-280.
[7] Wappmann S;Has M;Ludemann HD .Self-Diffusion in the Compressed Fluid Lower Alkanes: Methane, Ethane and Propane[J].Journal of Chemical Physics,1991,94(12):5643-5649.
[8] K R Harris .Temperature and Density Dependence of the Self-diffusion Coefficient of n-Hextane from 223 to 333 K and up to 400 MPa[J].Journal of the Chemical Society,Faraday Transactions 1,1982,78(05):2265-2274.
[9] Dymond JH;Harris KR .The Temperature and Den sity Dependenve of the Self-Diffusion Coefficient of n Hexadecane[J].Molecular Physics,1992,75(02):461-466.
[10] Lang EW;Prielmeier FX;Radkowitsch H et al.High Pressure NMIR Study of the Modecular Dynamics of Liquid Methylfluoride and Deutero-Methylfluoride[J].Berichte der Bunsengesellschaft fuer Physikalische Chemie,1987,91(10):1017-1025.
[11] Lang EW;Prielmeier FX;Radkowitsch H et al.High Pressure NMR Study of the Modecular Dynamics of Liquid Fluoroform and Deutero-Fluoroform[J].Berichte der Bunsen Gesellschaft physical Chemistry Chemical Physics,1987,91(10):1025-1033.
[12] Ertl H;Dullien FAL .Self-diffusion and Viscosity of Some Liquids as a Function of Temperature[J].AICHE Journal,1973,19(10):1217-1223.
[13] Gross T.;Ludemann HD.;Buchhauser J. .Self-diffusion in fluid carbon dioxide at high pressures[J].The Journal of Chemical Physics,1998(11):4518-4522.
[14] Vardag T;Karger N;Ludemann HD .Temperature and Pressure Depandence of Self Diffusion in Long Liquid n Alkanes[J].Berichte der Bunsengesellschaft fuer Physikalische Chemie,1991,95(08):859-865L.
[15] Prielmeier FX;Ludemann HD .Self-Diffusion in Com pressed Liquid Chloromethane and Dichloromethane and Trichloromethane[J].Molecular Physics,1986,58(03):593-604.
[16] Woolf A .Self-diffusion in Carbon Disulfide under Pres sure Polymerization with Styrene Erusion Droplets[J].Journal of the Chemical Society,Faraday Transactions 1,1982,78(03):583-590.
[17] Wappmann S;Has M;Ludemann HD .Self-Diffusion in Long Liquid n-Alkanes[J].Berichte der Bunsen Gesellschaft physical Chemistry Chemical Physics,1991,94(09):5643-5649.
[18] Etesse P;Zega JA;Kobayashi R .High Pressure Nuclear Magnetic Resonance Meaurement of Spin-Lattice Relaxation and Self-Diffusion in Carbon Dioxide[J].Journal of Chemical Physics,1992,97(03):2022-2029.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%