近年来,石墨烯以其独特的结构和优异的材料性能而广泛应用于物理、化学及材料学等领域。参考了最新的参考文献资料,综述了石墨烯的制备方法,如外延生长、气相沉积、机械剥离、氧化还原等方法,并探讨了各种制备方法的研究进展及未来的发展方向。
Graphene has attracted much attention in fields such as physics,chemistry,and materials science,because of its unique properties and potential applications.This was a review of synthesis of graphene using different preparation methods,such as epitaxial growth,chemical vapor deposition,micromechanical exfoliation and chemical reduction of graphene oxide.The further prospects and improvement of strategies for synthesis of graphene have also been discussed.
参考文献
| [1] | Bolotin, KI;Sikes, KJ;Jiang, Z;Klima, M;Fudenberg, G;Hone, J;Kim, P;Stormer, HL .Ultrahigh electron mobility in suspended graphene[J].Solid State Communications,2008(9/10):351-355. |
| [2] | Morozov S;Novoselov K;Katsnelson M et al.Giant in- trinsic carrier mobilities in graphene and its bitayer[J].Physical Review Letters,2008,100(01):16602. |
| [3] | Yanwu Zhu;Shanthi Murali;Weiwei Cai;Xuesong Li;Ji Won Suk;Jeffrey R. Potts;Rodney S. Ruoff .Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Advanced Materials,2010(35):3906-3924. |
| [4] | 袁小亚.石墨烯的制备研究进展[J].无机材料学报,2011(06):561-570. |
| [5] | Geim A K .Graphene:status and prospects[J].Science,2009,324(5934):1530-1534. |
| [6] | Jishan Wu;Wojciech Pisula;Klaus Mullen .Graphenes as Potential Material for Electronics[J].Chemical Reviews,2007(3):718-747. |
| [7] | Rao C;Sood A;Voggu R et al.Some novel attributes of graphene[J].The Journal of Physical Chemistry Letters,2010,1(02):572-580. |
| [8] | Allen M J;Tung V C;Kaner R B .Honeycomb carbon:a review of graphene[J].Chemical Reviews,2009,110(01):132-145. |
| [9] | Jaemyung Kim;Franklin Kim;Jiaxing Huang .Seeing graphene-based sheets[J].Materials Today,2010(3):28-38. |
| [10] | Claire Berger;Zhimin Sonnnnng;Tianbo Li;Xuebin Li;Asmerom y.oGBAZGHI;Rui Feng;Zhenting Dai;Alexei N.Marchenkov;Edward H.Conrad;Philip N.First;Walt A.de Heer .Ultrathin Epitaxial Graphite:2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(52):19912-19916. |
| [11] | Berger, C;Song, ZM;Li, XB;Wu, XS;Brown, N;Naud, C;Mayo, D;Li, TB;Hass, J;Marchenkov, AN .Electronic confinement and coherence in patterned epitaxial graphene[J].Science,2006(5777):1191-1196. |
| [12] | Hass J;Feng R;Millfin-Otoya J et al.Structural properties of the multilayer graphene/4H-SiC(0001 [over^-])system as determined by surface X-ray diffraction[J].Physical Review B:Condensed Matter and Materials Physics,2007,75(21):214109. |
| [13] | Konstantin V. Emtsev;Aaron Bostwick;Karsten Horn .Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide[J].Nature materials,2009(3):203-207. |
| [14] | Shivaraman, S;Barton, RA;Yu, X;Alden, J;Herman, L;Chandrashekhar, MVS;Park, J;McEuen, PL;Parpia, JM;Craighead, HG;Spencer, MG .Free-Standing Epitaxial Graphene[J].Nano letters,2009(9):3100-3105. |
| [15] | Aristov, VY;Urbanik, G;Kummer, K;Vyalikh, DV;Molodtsova, OV;Preobrajenski, AB;Zakharov, AA;Hess, C;Hanke, T;Buchner, B;Vobornik, I;Fujii, J;Panaccione, G;Ossipyan, YA;Knupfer, M .Graphene Synthesis on Cubic SiC/Si Wafers. Perspectives for Mass Production of Graphene-Based Electronic Devices[J].Nano letters,2010(3):992-995. |
| [16] | May J .Platinum surface LEED rings[J].Surface Science,1969,17(01):267-270. |
| [17] | Shelton J;Patil H;Blakely J .Equilibrium segregation of carbon to a nickel(111)surface:a surface phase transition[J].Surface Science,1974,43(02):493-520. |
| [18] | Eizenberg M;Blakely J .Carbon monolayer phase condensation on Ni(111)[J].Surface Science,1979,82(01):228-236. |
| [19] | Diekmann W;Panzner G;Grabke H .The bonding state of nitrogen segregated on Fe(100)and on iron nitrides Fe4N and Fe2N[J].Surface Science,1989,218(2-3):507-518. |
| [20] | Xuesong Li;Weiwei Cai;Jinho An;Seyoung Kim;Junghyo Nah;Dongxing Yang;Richard Piner;Aruna Velamakanni;Inhwa Jung;Emanuel Tutuc;Sanjay K. Banerjee;Luigi Colombo;Rodney S. Ruoff .Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils[J].Science,2009(Jun.5 TN.5932):1281-1282. |
| [21] | Dervishi, E;Li, ZR;Watanabe, F;Biswas, A;Xu, Y;Biris, AR;Saini, V;Biris, AS .Large-scale graphene production by RF-cCVD method[J].Chemical communications,2009(27):4061-4063. |
| [22] | Reina A;Jia X;Ho J et al.Layer area,few-layer graphene films on arbitrary substrates by chemical vapor deposition[J].Nano Letters,2009,9(08):3087-3087. |
| [23] | Anchal Srivastava;Charudatta Galande;Lijie Ci .Novel Liquid Precursor-Based Facile Synthesis of Large-Area Continuous, Single, and Few-Layer Graphene Films[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(11):3457-3461. |
| [24] | Malesevic A;Vitchev R;Schouteden K;Volodin A;Zhang L;Van Tendeloo G;Vanhulsel A;Van Haesendonck C .Synthesis of few-layer graphene via microwave plasma-enhanced chemical vapour deposition[J].Nanotechnology,2008(30):305604-1-305604-6-0. |
| [25] | Zhen-Yu Juang;Chih-Yu Wu;Chien-Wei Lo .Synthesis of graphene on silicon carbide substrates at low temperature[J].Carbon,2009(8):2026-2031. |
| [26] | Bae, S.;Kim, H.;Lee, Y.;Xu, X.;Park, J.-S.;Zheng, Y.;Balakrishnan, J.;Lei, T.;Ri Kim, H.;Song, Y.I.;Kim, Y.-J.;Kim, K.S.;?zyilmaz, B.;Ahn, J.-H.;Hong, B.H.;Iijima, S. .Roll-to-roll production of 30-inch graphene films for transparent electrodes[J].Nature nanotechnology,2010(8):574-578. |
| [27] | X.Lu;M.Yu .Tailoring graphite with the goal of achieving single sheets[J].Nanotechnology,1999(3):269-272. |
| [28] | Yuanbo Zhang;Joshua P. Small;William V. Pontius;Philip Kim .Fabrication and electric-field-dependent transport measurements of mesoscopic graphite devices[J].Applied physics letters,2005(7):073104-1-073104-3-0. |
| [29] | Hao R;Qian W;Zhang LH;Hou YL .Aqueous dispersions of TCNQ-anion-stabilized graphene sheets[J].Chemical communications,2008(48):6576-6578. |
| [30] | Hamilton, CE;Lomeda, JR;Sun, ZZ;Tour, JM;Barron, AR .High-Yield Organic Dispersions of Unfunctionalized Graphene[J].Nano letters,2009(10):3460-3462. |
| [31] | Lee J H;Shin D W;Makotchenko V G et al.One step exfoliation synthesis of easily soluble graphite and transparent conducting graphene sheets[J].Advanced Materials,2009,21(43):4383-4387. |
| [32] | Khan, U.;O'Neill, A.;Lotya, M.;De, S.;Coleman, J.N. .High-concentration solvent exfoliation of graphene[J].Small,2010(7):864-871. |
| [33] | Bourlinos, AB;Georgakilas, V;Zboril, R;Steriotis, TA;Stubos, AK .Liquid-Phase Exfoliation of Graphite Towards Solubilized Graphenes[J].Small,2009(16):1841-1845. |
| [34] | Lotya, M;Hernandez, Y;King, PJ;Smith, RJ;Nicolosi, V;Karlsson, LS;Blighe, FM;De, S;Wang, ZM;McGovern, IT;Duesberg, GS;Coleman, JN .Liquid Phase Production of Graphene by Exfoliation of Graphite in Surfactant/Water Solutions[J].Journal of the American Chemical Society,2009(10):3611-3620. |
| [35] | Choucair, M;Thordarson, P;Stride, JA .Gram-scale production of graphene based on solvothermal synthesis and sonication[J].Nature nanotechnology,2009(1):30-33. |
| [36] | Janowska I;Chizari K;Ersen O et al.Microwave synthesis of large few-layer graphene sheets in aqueous solution of ammonia[J].Nano Research,2010,3(02):126-137. |
| [37] | Zhang, M.;Parajuli, R.R.;Mastrogiovanni, D.;Dai, B.;Lo, P.;Cheung, W.;Brukh, R.;Chiu, P.L.;Zhou, T.;Liu, Z.;Garfunkel, E.;He, H. .Production of graphene sheets by direct dispersion with aromatic healing agents[J].Small,2010(10):1100-1107. |
| [38] | Lotya, M.;King, P.J.;Khan, U.;De, S.;Coleman, J.N. .High-concentration, surfactant-stabilized graphene dispersions[J].ACS nano,2010(6):3155-3162. |
| [39] | Dreyer D R;Park S;Bielawski C W et al.The chemistry of graphene oxide[J].Chemical Society Reviews,2009,39(01):228-240. |
| [40] | Compton, OC;Nguyen, ST .Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials[J].Small,2010(6):711-723. |
| [41] | Shaojun Guo;Shaojun Dong .Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications[J].Chemical Society Reviews,2011(5):2644-2672. |
| [42] | Nakajima T;Matsuo Y .Formation process and structure of graphite oxide[J].Carbon,1994,32(03):469-475. |
| [43] | C. N. R. Rao;A. K. Sood;K. S. Subrahmanyam .Graphene: The New Two-Dimensional Nanomaterial[J].Angewandte Chemie,2009(42):7752-7777. |
| [44] | 孙宇峰,刘少波,李会华,王萍,孟凡利,陈翌庆.氧化石墨烯的制备及其对NH3的敏感特性研究[J].功能材料,2012(06):712-714. |
| [45] | Brodie B .Sur le poids atomique du graphite[J].Annales de Chimie et de Physique,1860,59:466-472. |
| [46] | Staudenmaier L .Verfahren zur darstellung der graphits ure[J].Berichte der Deutschen Chemischen Gesell-schaft,1898,31(02):1481-1487. |
| [47] | William s;Hummers J R;Offeman R E .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(06):1339. |
| [48] | Marcano DC;Kosynkin DV;Berlin JM;Sinitskii A;Sun ZZ;Slesarev A;Alemany LB;Lu W;Tour JM .Improved Synthesis of Graphene Oxide[J].ACS nano,2010(8):4806-4814. |
| [49] | Becerril, H.A.;Mao, J.;Liu, Z.;Stoltenberg, R.M.;Bao, Z.;Chen, Y. .Evaluation of solution-processed reduced graphene oxide films as transparent conductors[J].ACS nano,2008(3):463-470. |
| [50] | Goki Eda;Yun-Yue Lin;Steve Miller;Chun-Wei Chen;Wei-Fang Su;Manish Chhowalla .Transparent and conducting electrodes for organic electronics from reduced graphene oxide[J].Applied physics letters,2008(23):233305-1-233305-3-0. |
| [51] | Li XL;Zhang GY;Bai XD;Sun XM;Wang XR;Wang E;Dai HJ .Highly conducting graphene sheets and Langmuir-Blodgett films[J].Nature nanotechnology,2008(9):538-542. |
| [52] | Mkhoyan, KA;Contryman, AW;Silcox, J;Stewart, DA;Eda, G;Mattevi, C;Miller, S;Chhowalla, M .Atomic and Electronic Structure of Graphene-Oxide[J].Nano letters,2009(3):1058-1063. |
| [53] | Kian Ping Loh;Qiaoliang Bao;Goki Eda .Graphene oxide as a chemically tunable platform for optical applications[J].Nature Chemistry,2010(12):1015-1024. |
| [54] | Hyeon-Jin Shin;Ki Kang Kim;Anass Benayad;Seon-Mi Yoon;Hyeon Ki Park;In-Sun Jung;Mei Hua Jin;Hae-Kyung Jeong;Jong Min Kim;Jae-Young Choi;Young Hee Lee .Efficient Reduction of Graphite Oxide by Sodium Borohydride and Its Effect on Electrical Conductance[J].Advanced functional materials,2009(12):1949-1961. |
| [55] | Zhu, Y.;Stoller, M.D.;Cai, W.;Velamakanni, A.;Piner, R.D.;Chen, D.;Ruoff, R.S. .Exfoliation of graphite oxide in propylene carbonate and thermal reduction of the resulting graphene oxide platelets[J].ACS nano,2010(2):1227-1233. |
| [56] | Sasha Stankovich;Dmitriy A. Dikin;Richard D. Piner .Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(7):1558-1565. |
| [57] | O. Akhavan;E. Ghaderi .Photocatalytic Reduction of Graphene Oxide Nanosheets on TiO2 Thin Film for Photoinactivation of Bacteria in Solar Light Irradiation[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(47):20214-20220. |
| [58] | Nguyen-Phan T D;Pham V H;Shin E W et al.The role of graphene oxide content on the adsorption-enhanced photoeatalysis of titanium dioxide/graphene oxide composites[J].Chemical Engineering Journal,2011,170(01):226-232. |
| [59] | Yanwu Zhu;Shanthi Murali;Meryl D. Stoller .Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(7):2118-2122. |
| [60] | Scott Gilje;Song Han;Minsheng Wang .A Chemical Route to Graphene for Device Applications[J].Nano letters,2007(11):3394-3398. |
| [61] | Wu, Z.-S.;Ren, W.;Gao, L.;Zhao, J.;Chen, Z.;Liu, B.;Tang, D.;Yu, B.;Jiang, C.;Cheng, H.-M. .Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation[J].ACS nano,2009(2):411-417. |
| [62] | Park S;An J;Potts J R et al.Hydrazine-reduction of graphite-and graphene-oxide[J].Carbon,2011,49(09):3019-3023. |
| [63] | Ma W S;Zhou J W;Lin X D .X-ray photoelectron spectroscopy study on reduction of graphene oxide with hydrazine hydrate[J].Current Advances in Materials and Processes,2011,287:539-543. |
| [64] | Tapas Kuila;Saswata Bose;Partha Khanra .A green approach for the reduction of graphene oxide by wild carrot root[J].Carbon: An International Journal Sponsored by the American Carbon Society,2012(3):914-921. |
| [65] | Buglione L;Chng E L K;Ambrosi A.Graphene materials preparation methods have dramatic influence upon their capacitance[J].Electrochemistry Communications,2011 |
| [66] | Zhang J;Yang H;Shen G et al.Reduction of graphene oxide vial-ascorbic acid[J].Chemical Communications,2009,46(07):1112-1114. |
| [67] | Jian Gao;Fang Liu;Yiliu Liu .Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(7):2213-2218. |
| [68] | Uhm, S.;Tuyen, N.H.;Lee, J. .Controlling oxygen functional species of graphene oxide for an electro-oxidation of L-ascorbic acid[J].Electrochemistry communications,2011(7):677-680. |
| [69] | Yong Zhou;Qiaoliang Bao;Lena Ai Ling Tang .Hydrothermal Dehydration for the "Green" Reduction of Exfoliated Graphene Oxide to Graphene and Demonstration of Tunable Optical Limiting Properties[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(13):2950-2956. |
| [70] | Omer O. Van der Biest;Luc J. Vandeperre .ELECTROPHORETIC DEPOSITION OF MATERIALS[J].Annual review of materials research,1999(0):327-352. |
| [71] | Songfeng Pei;Jinhong Du;You Zeng;Chang Liu;Hui-Ming Cheng .The fabrication of a carbon nanotube transparent conductive film by electrophoretic deposition and hot-pressing transfer[J].Nanotechnology,2009(23):235707:1-235707:7. |
| [72] | Seunghyun Hong;Sehun Jung;Sunjung Kang;Youngjin Kim;Xinqi Chen;Sasha Stankovich;S. Rodney Ruoff;Seunghyun Baik .Dielectrophoretic Deposition of Graphite Oxide Soot Particles[J].Journal of nanoscience and nanotechnology,2008(1):424-427. |
| [73] | Vincent Lee;Luisa Whittaker;Cherno Jaye .Large-Area Chemically Modified Graphene Films: Electrophoretic Deposition and Characterization by Soft X-ray Absorption Spectroscopy[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(16):3905-3916. |
| [74] | Park, S;Ruoff, RS .Chemical methods for the production of graphenes[J].Nature nanotechnology,2009(4):217-224. |
| [75] | Hernandez Y;Nicolosi V;Lotya M;Blighe FM;Sun ZY;De S;McGovern IT;Holland B;Byrne M;Gun'ko YK .High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,2008(9):563-568. |
| [76] | Dachao Luo;Guoxin Zhang;Junfeng Liu .Evaluation Criteria for Reduced Graphene Oxide[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(23):11327-11335. |
| [77] | Shu Jun Wang;Yan Geng;Qingbin Zheng .Fabrication of highly conducting and transparent graphene films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(6):1815-1823. |
| [78] | Wei Gao;Lawrence B. Alemany;Lijie Ci .New insights into the structure and reduction of graphite oxide[J].Nature Chemistry,2009(5):403-408. |
| [79] | Dato A;Radmilovic V;Lee ZH;Phillips J;Frenklach M .Substrate-free gas-phase synthesis of graphene sheets[J].Nano letters,2008(7):2012-2016. |
| [80] | Nan Li;Zhiyong Wang;Keke Zhao .Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(1):255-259. |
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