磺基水杨酸掺杂聚苯胺

功能材料, 2000, 31(5): 551-553.

磺基水杨酸掺杂聚苯胺

黄可龙 ^1, , 刘建生 ^2, , 刘素琴 ^3, , 桑商斌 ^4,

1.中南工业大学化学系,湖南,长沙,410083

2.中南工业大学化学系,湖南,长沙,410083

3.中南工业大学化学系,湖南,长沙,410083

4.中南工业大学化学系,湖南,长沙,410083

基金项目: 湖南省自然科学基金(JJY2060)

关键词：聚苯胺 , 磺基水杨酸 , 掺杂 , 电化学法

Synthesis and Property Study of Polyanaline Doped by Sulfosalicylic Acid

采用化学法及电化学法合成了磺基水杨酸掺杂的聚苯胺.通过UV-Vis光谱,XRD、FTIR及循环伏安法对其结构和性能进行表征;结果表明:相对于硫酸,磺基水杨酸(SSA)的掺入降低了聚苯胺的水解及氧化降解反应,并使之更稳定.掺杂SSA使PAN分子链上的电荷呈离域化.电化学法制备SSA掺杂PAN比化学法制备PAN更呈晶态.

参考文献

[1]	Macdiarmid AG. .POLYANILINE AND POLYPYRROLE - WHERE ARE WE HEADED[J].Synthetic Metals,1997(1/3):27-34.
[2]	Yang C Y;Cao Y;Smith P et al.[J].Synthetic Metals,1993,53:293.
[3]	Lee J Y;Su X H;Cui C Q et al.[J].Journal of Electroanalytical Chemistry,1994,367:71.
[4]	Pinto N J;Kahol P K;McCormick B J et al.[J].Physical Review B,1994,49:13983.
[5]	Cheudheri H K;Kelkar D S .[J].Polymer International,1997,42:380.
[6]	Kalakisla M;Sacal M;Erden E et al.[J].Journal of Applied Electrochemistry,1997,27:309.
[7]	Wang Y;Rubner M F .[J].Synthetic Metals,1992,47:255.
[8]	Cao Y;Smith P;Heeger A J .[J].Synthetic Metals,1992,48:91.
[9]	Emine Erdem;Mehmet;Sacak;Meral Karakisla .[J].Polymer International,1996,39:153.
[10]	Hongjun Y;Allen J B .[J].Journal of Electroanalytical Chemistry,1992,339:423.
[11]	Taka T;Laakso Levon K .[J].Solid State Communications,1994,92:393.
[12]	Mani A;Athinarayanasamy K;Kamaraj P et al.[J].Journal of Materials Science Letters,1995,14:1594.
[13]	Holland E R;Pomfret S J;Adams P N et al.[J].Journal of Physics:Condensed Matter,1996,8:2991.

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磺基水杨酸掺杂聚苯胺

Synthesis and Property Study of Polyanaline Doped by Sulfosalicylic Acid

参考文献