采用两种上浆剂对聚丙烯腈(PAN)基炭纤维进行表面上浆,利用扫描电子显微镜(SEM)、原子力显微镜(AFM)、X射线元素分析(XPS)和反向气相色谱(IGC)研究了未上浆、上浆炭纤维的表面形貌、化学组成及纤维表面能,测试了未上浆和上浆炭纤维所制备复合材料的层间剪切强度(ILSS)并用SEM观察其断面形貌.结果表明,上浆后炭纤维表面变平滑,纤维表面n(O)/n(C)明显提高,含氧官能团(羟基、羧基)增加,炭纤维表面能降低.上浆后,复合材料的ILLS有所提高.
参考文献
[1] | 贺福;王茂章.碳纤维及其复合材料[M].北京:科学出版社,1995:175. |
[2] | Kim K Y;Ye L .Interlaminar fracture toughness of CF/PEI composites at elevated temperatures:Roles of matrix toughness and fiber/matrix adhesion[J].Composites Part A:Applied Science and Manufacturing,2004,35(04):477. |
[3] | Afaghi K A;Ye L;Mai Y W .An experimental study of the influence of fiber-matrix interface on fatigue tensile strength of notched composite laminates[J].Composites Part B:Engineering,2001,32(04):371. |
[4] | Ying W;Thomas H H .AFM characterization of the interfacial properties of carbon fiber reinforced polymer composites subjected to hydrothermal treatments[J].Composites Science and Technology,2007,67:92. |
[5] | Marietaa C B;Schulzb E;Mondragona Ⅰ .Characterization of interfacial behavior in carbon fibre/cyanate composites[J].Composites Science and Technology,2002,62(02):299. |
[6] | 肇研,段跃新,肖何.上浆剂对碳纤维表面性能的影响[J].材料工程,2007(z1):121-126. |
[7] | Xu ZW;Chen L;Huang YD;Li JL;Wu XQ;Li XM;Jiao Y .Wettability of carbon fibers modified by acrylic acid and interface properties of carbon fiber/epoxy[J].European Polymer Journal,2008(2):494-503. |
[8] | Tamaki Naganuma;Kimiyoshi Naito;Jenn-Ming Yang;Junro Kyono;Daisuke Sasakura;Yutaka Kagawa .The effect of a compliant polyimide nanocoating on the tensile properties of a high strength PAN-based carbon fiber[J].Composites science and technology,2009(7/8):1319-1322. |
[9] | Hui Guo;Yudong Huang;Li Liu;Xiaohua Shi .Effect of epoxy coatings on carbon fibers during manufacture of carbon fiber reinforced resin matrix composites[J].Materials & design,2010(3):1186-1190. |
[10] | 杨禹,吕春祥,王心葵,苏小雷,贺福,李永红.纳米SiO2改性炭纤维乳液上浆剂的性能评价[J].复合材料学报,2007(02):38-43. |
[11] | Lavielle L;Schultz J .Surface properties of carbon fibers determined by inverse gas chromatography:Role of pretreat ment[J].Langmuir,1991,7(05):978. |
[12] | Donnet J B;Park S J;Balard H .Evaluation of specific interactions of solid surfaces by inverse gas chromatography a new approach based on polarizability of the probes[J].Cbromatographia,1991,31(9 10):434. |
[13] | Dilsiz Nursel;Wightman J.P. .Surface analysis of unsized and sized carbon fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(7):1105-1114. |
[14] | 石峰晖,代志双,张宝艳.碳纤维表面性质分析及其对复合材料界面性能的影响[J].航空材料学报,2010(03):43-47. |
[15] | Wu S.Polymer interface and adhesion[M].New York,USA:Marcel Dekker,Inc,1982:337. |
[16] | Sharpe L H.The interfacial interactions in polymeric composites[M].Kluwer:Netherlands,1993:1. |
[17] | Berg J;Jones F R .The role of sizing resins,couping agent and their blends on the formation of the interphase in glass fiber composites[J].Composites Part A:Applied Science and Manufacturing,1998,29(9-10):1261. |
[18] | Mallarino S;Chailan JF;Vernet JL .Glass fibre sizing effect on dynamic mechanical properties of cyanate ester composites - I. Single frequency investigations[J].European Polymer Journal,2005(8):1804-1811. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%