研究了纳米晶复合物Mg-Ni-V2O5的吸放氢性能及其在充放氢过程中的温度变化规律.该复合物是在氢气作为保护气的条件下,用机械合金化方法从镁粉、镍粉和五氧化二钒直接通过球磨制备而成的.试样在球磨过程中能发生吸氢反应(MAR),经过较长时间球磨之后,试样基本能完全吸氢.该试样具有很好的充放氢性能,放氢温度也有所降低.例如该复合材料在200℃可以在60s内充氢达6.2%(质量分数)以上;在300℃、0.1MPa下,可以在700s内使放氢量达到6.0%(质量分数)以上.
参考文献
[1] | 张允什.[J].南开大学学报(自然科学版),1991(01):93-98. |
[2] | Zaluska A;Zaluski L;Strom-Olsen J O .[J].Journal of Alloys and Compounds,1999,288:217-225. |
[3] | Liang G;Huot J;Boily S et al.[J].Journal of Alloys and Compounds,1999,291:295-299. |
[4] | Liang G;Huot J;Boily S et al.[J].Journal of Alloys and Compounds,2000,305:239-245. |
[5] | Sun D;Enoki H;Bououdina M et al.[J].Journal of Alloys and Compounds,1999,282:252-257. |
[6] | Liang G.;Huot J. .Hydrogen storage in mechanically milled Mg-LaNi_5 and MgH_2-LaNi_5 composites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):261-265. |
[7] | Sai Raman S S;Srivastava O N .[J].Journal of Alloys and Compounds,1996,241:167-174. |
[8] | Liang G.;Huot J.;Van Neste A.;Schulz R.;Boily S. .Hydrogen absorption properties of a mechanically milled Mg-50wt%LaNi5 composite[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):302-307. |
[9] | Terzieva M.;Peshev P.;Khrussanova M. .Hydriding and dehydriding characteristics of Mg-LaNi5 composite materials prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):235-239. |
[10] | Hampton M D;Lomness J K .[J].International Journal of Hydrogen Energy,1999,24:175-187. |
[11] | Tessier P.;Bououdina M.;Akiba E.;Enoki H. .Ball-milling of Mg2Ni under hydrogen[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):285-289. |
[12] | Schlaphbach L et al.[J].Materials Research Bulletin,1978,13:697-706. |
[13] | Dutta K;Mandal P;Ramakrishna K et al.[J].International Journal of Hydrogen Energy,1994,19:253-257. |
[14] | Zaluska A;Zaluski L;Strom-Olsen J O .[J].Journal of Alloys and Compounds,1999,289:197-206. |
[15] | Peshev P;KhrussanovaM;Chakarov D et al.[J].Materials Research Bulletin,1989,24:207-212. |
[16] | KhrussanovaM;TerzievaM;Eeshev P et al.[J].Materials Research Bulletin,1991,26:1291-1298. |
[17] | 吴越.催化化学[M].北京:科学出版社,1998:1179. |
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