Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(Ⅲ), β-diketones and 1,10-phenanthroline

稀土学报(英文版), 2008, 26(6): 778-782.

^1, , ^2, , ^3,

1.School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China;Baotou Teacher's College, Baotou 014030, China

2.School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

3.School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

基金项目: Education Department of Inner Mongolia(NJ06002;NJcxy08124) 包头科学技术基金(2007G1013) 内蒙古自然科学基金(200508010210)

Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(Ⅲ), β-diketones and 1,10-phenanthroline

LIU Xingwang ^1, , WANG Na ^2, , SUO Quanling ^3,

1.School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China;Baotou Teacher's College, Baotou 014030, China

2.School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

3.School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

Keywords： β-diketone

Three novel β-diketones (HPPP, HTPP, and HFPP) ligands were synthesized by Sonogashira coupling reaction and Claisen con-densation. The structure of β-diketones was confirmed with elemental analysis, IR, NMR and MS spectra. Three new ternary complexes consisting of Eu(Ⅲ), β-diketones, and 1,10-phenanthroline(phen) were synthesized and characterized as ThL3phen (L=PPP, TPP, FPP) with elemental analysis, chemical analysis, and IR spectra, and their luminescence properties were studied.

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材料期刊网

Synthesis and luminescence properties of rare earth ternary complexes consisting of Eu(Ⅲ), β-diketones and 1,10-phenanthroline

参考文献