Long lasting phosphorescence (LLP) was observed in Eu2+, Ce3+ co-doped strontium borate glasses prepared under the reducing atmosphere due to the emission of both Eu2+ and Ce3+. The methods of photoluminescence, thermoluminescence and phosphorescence were used to study the samples, and possible mechanism was suggested. The co-doping of Ce3+ ions poisoned the phosphorescence emission of Eu2+ because of the competition to obtain the trapped electron. The phosphorescence of Ce3+ in the sample decays more quickly than that of Eu2+, which is suggested for the reason that the emission energy of Ce3+ is higher or the distance between Ce3+ and electron traps of the glasses is longer.
参考文献
[1] | Qiu JR.;Hirao K. .Long lasting phosphorescence in Eu2+-doped calcium aluminoborate glasses[J].Solid State Communications,1998(12):795-798. |
[2] | Qiu J.;Tanaka K.;Shimizugawa Y.;Hirao K.;Kawasaki M. .Phenomenon and mechanism of long-lasting phosphorescence in Eu2+-doped aluminosilicate glasses[J].The journal of physics and chemistry of solids,1998(9):1521-1525. |
[3] | Lin Yuanhua;Tang Zilong;Zhang Zhongtai et al.Preparation and properties of photoluminescent rare earth doped SrO-MgO-B2O3-SiO2 glass[J].Materials Science and Engineering,2001,B86:79. |
[4] | Kim J H;Holloway P H .Room-temperature photoluminescence and electroluminescence properties of sputter-grown gallium nitride doped with europium[J].Journal of Applied Physics,2004,95:4787. |
[5] | Tian Zifeng;Liang Hongbin;Lin Huihong et al.Luminescence of NaGdFPO4:Ln3+ after VUV excitation:A comparison with GdPO4:Ln3+ (Ln=Ce,Tb)[J].Journal of Solid State Chemistry,2006,179:1356. |
[6] | Zhang T;Su Q .Rare-earth materials for use in the dark[J].J of the SID,2000,8:27. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%