石墨烯是最近几年才发现的炭材料的新成员,其完美的二维结构和许多奇特的性质,引起了科学家的极大兴趣.石墨烯和氧化石墨烯的改性以及各种石墨烯/聚合物复合材料的制备成为当前研究的热点之一.与纯的聚合物相比,石墨烯的加入可赋予复合材料不同的功能性,不但表现出优异的力学和电学性能,且具有优良的加工性能,为复合材料提供了更广阔的应用空间.文中概述了石墨烯/聚合物复合材料的制备方法、结构及性能,并展望了石墨烯及其聚合物复合材料的研究前景.
参考文献
[1] | Evanoff D D,Chumanov G.Synthesis and optical properties of silver nanoparticles and arrays[J].Chem Phys Chem,2005,6(7):1221-1231. |
[2] | Matthew J A, Vincent C T, Richard B K. Honeycomb carbon:A review of graphene[J].Chem Rev,2010,110 (1):132-145. |
[3] | Rao C N R,Sood A K,Subrahmanyam K S,Govindaraj A.Graphene:The new two-dimensional nanomaterial[J].Angew Chem Int Ed,2009,48(42):7752-7778. |
[4] | Daniel R D,Sungjin P,Christopher W B,Rodney S R.The chemistry of graphene oxide[J].Chem Soc Rev,2010,39(1):228-240. |
[5] | Kato M,Usuki A,Okada A. Synthesis of polypropylene oligomer-clay intercalation compounds[J].J Appl Polym Sci,1997,66(9):1781-1785. |
[6] | Alexandre M, Dubois P. Polymer - layered silicate nanocomposites: Preparation, properties and uses of a new class of materials[J].Mater Sci Eng R,2000,28(1/2):1-63. |
[7] | Ray S S, Okamoto M. Polymer/layered silicate nanocomposites:A review from preparation to processing[J].Prog Polym Sci,2003,28(11): 1539-1641. |
[8] | Zhi Z,Shi Q,Peng J,et al.Partial delamination of the organomonmorillonite with surfactant containing hydroxyl groups in maleated poly(propylene carbonate)[J].Polymer,2006,47(26) :8548-8555. |
[9] | Peng L,Kim N H,Bhadra S,Lee J H.Electroresponsive property of novel poly (acrylate acryloyloxyethyl trimethyl ammoniumchloride)/clay nanocomposite hydrogels[J].Adv Mater Res,2009,79(15): 2263-2266. |
[10] | Peng L,Kim N H,Hui D,Rhee K Y,Lee J H.Improved mechanical and swelling behavior of the composite hydrogels prepared by ionic monomer and acid-activated laponite[J].Appl Surf Sci,2009,46(4) : 414-417. |
[11] | Leroux F,Besse J P. Polymer intercalated layered double hydroxide:A new emerging class of nanocomposites[J].Chem Mater,2001,13(10):3507-3515. |
[12] | Kuila T,Srivastava S K,Bhowmick A K,Saxena A K.Thermoplastic polyolefin based polymer-blend-layered double hydroxide nanocomposites[J].Compos Sci Technol,2008,68(15/16):3234-3239. |
[13] | Giannelis E P.Polymer layered silicate nanocomposites[J].Adv Mater,1996,8(1):29-35. |
[14] | Giannelis E P,Krishnamoorti R,Manias E.Polymer-silicate nanocomposites: Model systems for confined polymers and polymer brushes[J].Adv Polym Sci,1999,138(2),107-147. |
[15] | Zanetti M,Camino G,Reichert P,Mulhaupt R. Thermal behaviour of poly(propylene) layered silicate nanocomposites[J].Macromol Rapid Commun,2001,22(3):176-180. |
[16] | Pavlidou S,Papaspyrides C D.A review on polymer layered silicate nanocomposites[J].Prog Polym Sci,2008,33(12):1119-1198. |
[17] | Acharya H,Srivastava S K,Bhowmick A K. Synthesis of partially exfoliated EPDM/LDH nanocomposites by solution intercalation:Structural characterization and properties[J].Compos Sci Technol,2007,67(13):2807-2816. |
[18] | Costa F R,Satapathy B K,Wagenknechi U,Weidisch R,Heinrich G. Morphology and fracture behaviour of polyethylene/Mg-Al layered double hydroxide (LDH)nanocomposites[J].Eur Polym J,2006,42(9):2140-2152. |
[19] | Li Q,Park O K,Lee J H. Positive temperature coefficient behavior of HDPE/EVA blends filled with carbon black[J].Adv Mater Res,2009,79(1/2):2267-2270. |
[20] | Jeevananda T, Jang Y K, Lee J H, Siddaramaiah,Ranganathaiah C. Investigation of multi-walled carbon nanotube reinforced high-density polyethylene/carbon black nanocomposites using electrical DSC and positron lifetime spectroscopy techniques[J].Polym Int,2009,58(7):755-780. |
[21] | Li Q,Siddaramaiah,Kim N H,Yoo G H,Lee J H.Positive temperature coefficient characteristic and structure of graphite nanofibers reinforced high-density polyethylene/carbon black nanocomposites[J].Compos Part B,2009,40(3):218-224. |
[22] | Renukappa N M, Siddaramaiah, Sudhaker Samuel R D,Sundara Rajan J,Lee J H. Dielectric properties of carbon black:SBR composites[J].J Mater Sci,2009,20(7):648-656. |
[23] | Wang H,Zhang H,Zhao W,Zhang W,Chen G.Preparation of polymer/oriented graphite nanosheet composite by electric field inducement[J].Compos Sci Technol,2008,68(1):238-243. |
[24] | Yu A,Ramesh P,Itkis M E,Elena B,Haddon R C.Graphite nanoplatelet-epoxy composite thermal interface materials[J].J PhysChemC,2007,111(21):7565-7569. |
[25] | Debelak B, Lafdi K. Use of exfoliated graphite filler to enhance polymer physical properties[J].Carbon,2007,45(9):1727-1734. |
[26] | Chen X,Zheng Y P,Kang F,Shen W C. Preparation and structure analysis of carbon/carbon composite made from phenolic resin impregnation into exfoliated graphite[J]. J Phys Chem Solids,2006,67(5/6):1141-1144. |
[27] | Pan H,Qiu Z B.Biodegradable poly (L-lactide)/polyhedral oligomeric silsesquioxanes nanoconposites: Enhanced crystallization, mechanical properties, and hydrolytic degradation[J].Macromolecules,2010,43(3): 1499-1506. |
[28] | Xu D H,Wang Z G.Role of multi-wall carbon nanotube network in composites to crystallization of isotactic polypropylene matrix[J].Polymer,2007,49(1):330-338. |
[29] | Li Y J, Zhao L P, Shimizu H. Electrically conductive polymeric materials with high stretchability and excellent elasticity by a surface coating method[J]. Macromol Rapid Commun,2011,32(3):289-294. |
[30] | Peng H S,Sun X M,Cai F J,et al.Electrochromatic carbon nanotube/polydiacetylene nanocomposite fibres [J]. Nat Nanotechnol,2009,4(11):738-741. |
[31] | Khanna V, Bakshi B R. Carbon nanofiber polymer composites: Evaluation of life cycle energy use[J].Environ Sci Technol,2009,43(6):2078-2084. |
[32] | Tibbetts G G,Lake M L,Strong K L,Rice B P.A review of the fabrication and properties of vapor-grown carbon nanofiber/polymer composites[J]. Compos Sci Technol,2007,67(7/8):1709-1718. |
[33] | Chipara M,Lozano K, Hernandez A,Chipara M. TGA analysis of polypropylene-carbon nanofibers composites[J].Polym Degrad Stabil,2008,93(4):871-876. |
[34] | Kotov N A.Materials science:Carbon sheet solutions[J].Nature,2006,442(7100):254-255. |
[35] | Tapas K,Sambhu B,Dahu Y,Nam H K,Saswata B,Joong H L.Recent advances in graphene based polymer composites[J].Prog Polym Sci,2010,35(11): 1350-1375. |
[36] | 赵远,黄伟九.石墨烯及其复合材料的制备及性能研究进展[J].重庆理工大学学报:自然科学版,2011,25(7):64-70.Zhao Yuan,Huang Weijiu.Research progress on preparation and performance of graphene and its composite[J]. J Chongqing Uni Technol : Natural Science,2011,25 (7) : 64-70. |
[37] | 徐超,陈胜,汪 信.基于石墨烯的材料化学进展[J].应用化学,2011,28(1):2-9.Xu Chao,Chen Sheng,Wang Xin.Progress in the chemistry of materials based on graphene[J].Chinese J Appl Chem,2011, 28(1): 2-9. |
[38] | 杨永岗,陈成猛,温月芳,杨全红,王茂章.氧化石墨烯及其与聚合物的复合[J].新型炭材料,2008,23(3):194-200.Yang Yonggang, Chen Chengmeng, Wen Yuefang, Yang Quanhong,Wang Maozhang.Oxidized graphene and graphene based polymer composites[J].New Carbon Mater,2008,23(3):194-200. |
[39] | 周俊文,马文石.石墨烯及其纳米复合材料的研究[J].化工新型材料,2010,38(3):26-28.Zhou Junwen,Ma Wenshi.Research progress on preparation of graphene and its nanocomposite[J]. New Chem Mater,2010,38(3):26-28. |
[40] | 吕 晴,于杰,秦军,罗 筑,谢普.改性石墨烯的制备及对石墨烯/HDPE非等温结晶动力学的影响[J].复合材料学报,2011,28(4):70-76.Lü Qing,Yu Jie,Qin Jun,Luo Zhu,Xie Pu.Preparation of modified graphene and its effect on non- isothermal crystallization kinetics of graphene/HDPE[J].Acta Materiae Compositae Sinica,2011,28(4):70-76. |
[41] | Yu M,Lourie O,Dyer M J,Kelly T F,Ruoff R S.Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load[J].Science,2000,287(5453):637-640. |
[42] | Li Yijun,Wang Kunlin,Wei Jinquan,et al.Tensile properties of long aligned double-walled carbon nanotube[J].Carbon,2005,43(1):31-35. |
[43] | Yuen S M,Ma C M,Chiang C L,et al. Silane-modified MWCNT/PMMA composites: Preparation, electrical resistivity,thermal conductivity and thermal stability[J].Composites Part A,2007,38(12):2527-2535. |
[44] | Itkis M E,Borondics F,Yu A,Haddon R C. Thermal conductivity measurements of semitransparent single- walled carbon nanotube films by a bolometric technique[J].Nano Lett,2007,7(4):900-904. |
[45] | Park S,Rouff S.Chemical methods for the production of graphenes[J].Nat Nanotechnol,2009,4(4):217-224. |
[46] | Li D,Muller M B,Gilje S,Kaner R B,Wallac G G.Processable aqueous dispersions of graphene nanosheets[J].Nat Nanotechnol,2007,3(2):101-105. |
[47] | Rao C N R,Sood A K,Subrahmanyam K S,Govindaraj A.Graphene:The new two-dimensional nanomaterial[J].Angew Chem Int Ed,2009,48(42):7752-7777. |
[48] | Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669. |
[49] | Eizenberg M, Blakely J M. Carbon monolayer phase condensation on Ni(Ⅲ)[J].SurfSci,1979,82(1):228-236. |
[50] | Aizawa T, Souda R, Otani S, Ishizawa Y, Oshima C.Anomalous bond of monolayer graphite on transition metal carbide surfaces[J].Phys Rev Lett,1990,64(7):768-771. |
[51] | Berger C,Song Z,Li X,et al.Electronic confinement and coherence in patterned epitaxial graphene[J].Science,2006,312(5777):1191-1196. |
[52] | Reddy C D, Rajendran S, Liew K M. Equilibrium configuration and continuum elastic properties of finite sized graphene[J].Nanotechnology,2006,17(3):864-870. |
[53] | Boukhvalov D W,Katsnelson M I,Lichtenstein A I.Hydrogen on graphene:Electronic structure,total energy,structural distortions and magnetism from first-principles calculations[J].Phys Rev B,2008,77(3):035427-1-035427-6. |
[54] | Andres P L,Ramirez R,Verges J A.Strong covalent bonding between two graphene layers[J].Phys Rev B,2008,77(4):045403-1-045403-5. |
[55] | Bekyarova E, Itkis M E, Ramesh P, et al. Chemical modification of epitaxial graphene:Spontaneous grafting of aryl groups[J].J AmChem Soc,2009,131(4):1336-1337. |
[56] | Shah C,Yang H,Han D,Zhang Q,Ivaska A,Niu L.Water soluble graphene covalently functionalized by biocompatible polylysine[J].Langmuir,2009,25(20):12030-12033. |
[57] | Schniepp H C,Li J L,McAllister M J,et al.Functionalized single graphene sheets derived from splitting graphite oxide[J].J Phys Chem C,2006,110(17):8535-8539. |
[58] | Bai Hua, Xu Yuxi, Zhao Lu, et al. Non- covalent functionalization of graphene sheets by sulfonated polyaniline[J].ChemCommun,2009,13:1667-1669. |
[59] | Salavagione H J, Gomez M A, Marttinez G. Polymeric modification of graphene through esterification of graphite oxide and poly(vinyl alcohol)[J].Macromoleeules,2009,42(17):6331-6334. |
[60] | Stankovich S,Piner R D,Chen X,Wu N,Nguyen S T,Ruoff R S.Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate)[J].J Mater Chem,2006,16(2):155-158. |
[61] | Liu N,Luo F,Wu H,Liu Y,Zhang C,Chen J.One step ionic-liquid assisted electrochemical synthesis of ionic-liquidfunctionalized graphene sheets directly from graphene[J].Adv Funct Mater,2008,18(10):1518-1525. |
[62] | Stankovich S,Dikin D A,Dommett G H B,et al.Graphenebased composite materials[J]. Nature,2006,442(7100):282-286. |
[63] | Ansafi S,Giannelis E P.Functionalized graphene sheet/poly (vinylidene fluoride) conductive nanocomposites[J].J Polym Sci Part B:Polym Phys,2009,47(9):888-897. |
[64] | Wu H,Zhao W F,Hu H W,Chen G H.One-step in situ ball milling synthesis of polymer functionalized graphene nanocomposites[J].J Mater Chem,2011,21(24):8626-8632. |
[65] | Liang J J, Huang Y, Zhang L, et al. Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites[J].Adv Funct Mater,2009,19(14):2297-2302. |
[66] | Zhou T N,Chen F,Tang C Y,Bai H W,Zhang Q,Deng H,Fu Q.The preparation of high performance and conductive poly (vinyl alcohol)/graphene nanocomposite via reducing graphite oxide with sodium hydrosulfite[J]. Compos Sci Technol,2011,71(9):1266-1270. |
[67] | Zhang H B,Zheng W G,Yan Q,et al.Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding[J].Polymer,2010,51(5):1191-1196. |
[68] | Kim H,Macosko C W.Processing-property relationships of polycarbonate/graphene nanocomposites[J].Polymer,2009,50(15):3797-3809. |
[69] | Hu H T,Wang X B,Wang J C,et al.Preparation and properties of graphene nanosheets-polystyrene nanocomposites via in situ emulsion polymerization[J].Chem Phys Lett,2010,484(4-6):247-253. |
[70] | Xu Z,Gao C.In situ polymerization approach to graphene-reinforced nylon-6 composites[J],Macromolecules,2010,43(16):6716-6723. |
[71] | Zou Y H,Wu J,Liu H B,et al. Preparation of polyaniline intercalated graphite oxide composite and its application in detecting DNA[J].New Carbon Materials,2005,20(4):360-364. |
[72] | Han Y Q,Lu Y.Preparation and characterization of graphite oxide/polypyrrole composites[J].Carbon,2007,45 (12):2394-2399. |
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