采用溶胶-凝胶技术与PS微球模板相结合,在铝基板上成功制备了亚微米连续蜂窝网状LiFePO4薄膜.采用XRD、SEM等测试手段对薄膜的组成及显微形貌进行了表征,研究了成膜工艺、涂膜方法及模板球直径等因素对薄膜形貌的影响规律,并对薄膜形成机理进行了初步探讨.结果表明,成膜过程中模板表面溶胶层与模板之间的作用力是影响薄膜结构的关键因素;对于600 nm PS球模板和200 nm PS球模板获得完好LiFePO4薄膜的最佳方法分别为浸渍提拉法和旋涂法.
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