贵金属物料的溶解是贵金属分离提纯不可或缺的环节。现有贵金属物料溶解技术主要有常压酸溶、加压酸溶、活化溶解、电化学溶解、氯化溶解、碱熔等技术,但存在溶解周期长、试剂消耗量大、能耗高、操作过程复杂、返料多、环境污染严重和溶解效率低等缺点。因此,开发一种贵金属物料的高效清洁溶解技术一直是科研人员研究的重点。虽然目前已研发出一些高效清洁溶解技术,但大多数尚处在实验室研究阶段,且处理规模小、工业化应用难度大。综述了当前贵金属物料的溶解技术研究进展及其优缺点,并对今后贵金属溶解技术的发展动态进行了展望。
Dissolution of precious metals is one of indispensable steps for their following purification. The present dissolving techniques include atmospheric pressure-acid dissolution, high pressure-acid dissolution, active dissolution, electrochemical dissolution, chlorination dissolution, alkali fusion,etc. However, these techniques have some disadvantages, such as long period of dissolution, high consumption of acid and energy, complicated operations, a large number of retuning charge, severe environmental pollution and low efficiency of dissolution. Therefore, it is necessary to develop a new high efficiency and clean technique to dissolve precious metals. Although some high efficiency and clean dissolving techniques have been experimentally explored, they are still unacceptable for the large scale industrial application. In this article , the development of dissolving techniques for precious metals and their advantages and disadvantages are described and discussed. In addition, the development trend of the dissolving techniques in the future is also proposed.
参考文献
[1] | 刘时杰.铂族金属矿冶学[M].北京:冶金工业出版社,2001:289. |
[2] | 黎鼎鑫;王永录.贵金属提取与精炼[M].长沙:中南大学出版社,2003:248. |
[3] | 张苺 .世界铂族金属矿产资源及开发[EB/OL].http://www.lrn.cn/invest/inter-nationalres/200911t20091108_430682.htm,2009-09-30. |
[4] | 陈喜峰,彭润民.中国铂族金属资源形势分析及可持续发展对策探讨[J].矿产综合利用,2007(02):27-30. |
[5] | 汪云华,吴晓峰,童伟锋.铂族金属催化剂回收技术及发展动态[J].贵金属,2011(01):76-81. |
[6] | 陈景.铂族金属冶金化学[M].北京:科学出版社,2008:19-25. |
[7] | 王永录;刘正华.金、银及铂族金属再生回收[M].长沙:中南大学出版社,2007:122-141. |
[8] | Recovery of platinum from spent catalysts by liquid-liquid extraction in chloride medium[J].Journal of hazardous materials,2010(1/3):488. |
[9] | Luxton, T.P.;Eick, M.J.;Scheckel, K.G. .Characterization and dissolution properties of ruthenium oxides[J].Journal of Colloid and Interface Science,2011(1):30-39. |
[10] | 张蕾,唐应吉,王振宇,杨燕红,马晓迅.氯化铑制备工艺及其催化性能研究[J].化学工程,2011(12):73-76. |
[11] | Juodkazis K;Stalnionis G;Ebeka B et al.EQCM study of rhodium anodic dissolution in sulfuric acid[J].RUSSIAN JOURNAL OF ELECTROCHEMISTRY,2002,38(11):1157-1162. |
[12] | 彭红建,谢佑卿.金属铑的原子状态、物理性质和热力学性质的研究[J].稀有金属,2007(02):206-210. |
[13] | Mike Adams;Keith Liddell;Terry Holohan .Hydrometallurgical processing of Platreef flotation concentrate[J].Minerals Engineering,2011(6):545-550. |
[14] | 潘永雄;陆稼际;朱兰芳 .用氯化法溶解不纯铑粉[J].仪表材料,1984,15(3):77-83. |
[15] | 黄昆 .加压氰化法提取铂族金属新工艺研究[D].昆明理工大学,2004. |
[16] | 孙竹贤.含铂族金属物料加压溶解的新方法[J].金川科技,2010(6):91-95. |
[17] | Benguerel E;Demopoulos G;Harris P .Speciation and separation of rhodium(III)from chloride solutions:a critical review[J].HYDROMETALLURGY,1996,40(2):135-152. |
[18] | 赵家春;汪云华;范兴祥 等.一种高纯铑物料快速溶解方法[P].中国,CN101319278A,2008-07-21. |
[19] | Styrkas AD.;Styrkas D. .ELECTROCHEMICAL DISSOLUTION OF METALS OF THE PLATINUM GROUP BY ALTERNATING CURRENT[J].Journal of Applied Electrochemistry,1995(5):490-494. |
[20] | Paul C J;Lim L L .Recovery of precious metals by an electrochemical deposition method[J].CHEMOSPHERE,2005,60(10):1384-1392. |
[21] | Lim Kim;Chul Goo Chung;Yong Wook Sung;Jong Shik Chung .Dissolution And Migration Of Platinum After Long-term Operation Of A Polymer Electrolyte Fuel Cell Under Various Conditions[J].Journal of Power Sources,2008(2):524-532. |
[22] | Yadav A P;Nishikata A;Tsuru T .Effect of halogen ions on platinum dissolution under potential cycling in 0.5 M H2SO4 solution[J].Electrochimica Acta,2007,52(26):7444-7452. |
[23] | Z.X. Liang;T.S. Zhao;J.B. Xu .Stabilization Of The Platinum-ruthenium Electrocatalyst Against The Dissolution Of Ruthenium With The Incorporation Of Gold[J].Journal of Power Sources,2008(1):166-170. |
[24] | Lukaszewski M;Czerwinski A .Dissolution of noble metals and their alloys studied by electrochemical quartz crystal microbalance[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2006(1):38-45. |
[25] | Hsu M;Wen Y .Method of electrochemical dissolution of ruthenium-cobalt-based alloy[P].EP,2377955,2011-10-19. |
[26] | 吕顺丰;秦燕璜 .贵金属的电化学溶解方法[P].中国,CN1579605A,2005-02-16. |
[27] | 张健.铂铑合金电化学溶解工艺研究[J].稀有金属材料与工程,1997(04):45-48. |
[28] | G. Benke;W. Gnot .The electrochemical dissolution of platinum[J].Hydrometallurgy,2002(3):205-218. |
[29] | Péron Jennifer;Nedellec Yannig;Jones Deborah J .The effect of dissolution,migration and precipitation of platinum in nafion-based membrane electrode assemblies during fuel cell operation at high potential[J].Journal of Power Sources,2008,185(2):1209-1217. |
[30] | G?gy Inzelt;Balázs Berkes;ákos Kriston .Temperature dependence of two types of dissolution of platinum in acid media[J].Electrochimica Acta,2010,55(16):4742-4749. |
[31] | Bakos I;Szabo S .Electrochemical adsorption of rhodium on platinum[J].Journal of Electroanalytical Chemistry,2003,547(1):103-107. |
[32] | Marie-Celine C;Didier M;Jean-Pierrt P .Electrochemical process for recovering metallic rhodium from aqueous solutions of spent catalysts[P].USA,US4795538,1989-01-03. |
[33] | Shigenori Mitsushima;Yuki Koizumi;Shunsuke Uzuka;Ken-Ichiro Ota .Dissolution of platinum in acidic media[J].Electrochimica Acta,2008(2):455-460. |
[34] | 薛光,于永江,邬旭然,刘永明.微波加热技术在贵金属分析中的应用[J].黄金科学技术,2012(04):85-89. |
[35] | K. Boch;M. Schuster;G. Risse;M. Schwarzer .Microwave-assisted digestion procedure for the determination of palladium in road dust[J].Analytica chimica acta,2002(2):257-265. |
[36] | 刘能生,彭金辉,张利波,张泽彪.微波技术在稀贵金属冶金中的研究应用进展[J].贵金属,2009(04):48-51,62. |
[37] | 张文朴.微波在稀贵金属冶金中的应用研究进展[J].稀有金属与硬质合金,2008(02):49-53. |
[38] | 冯建华,兰新哲,宋永辉.微波辅助技术在湿法冶金中的应用[J].湿法冶金,2008(04):211-215. |
[39] | Djingova R.;Heidenreich H.;Kovacheva P.;Markert B. .On the determination of platinum group elements in environmental materials by inductively coupled plasma mass spectrometry and microwave digestion[J].Analytica chimica acta,2003(2):245-251. |
[40] | WANG Shixing,PENG Jinhui,CHEN Anran,ZHANG Zebiao.Progress in Microwave Technology Applied to the Recovery of Precious Metals from the Secondary Resources[J].贵金属,2012(z1):33-39. |
[41] | 朱利亚,杨光宇,李楷中,胡秋芬,马媛,赵辉,陈景,杨项军.微波密闭消解技术在处理Rh、Ir粉及其试样中的应用[J].贵金属,2008(01):40-45,52. |
[42] | 微波消解技术在分析难处理贵金属及其物质中铑、铱、铂、钯的研究与应用[J].冶金分析,2005(05):11-14. |
[43] | 董海刚;王云华;范兴祥 等.一种难溶贵金属铑物料高效溶解的方法[P].中国,CN102181659A,2011-09-14. |
[44] | 钱东强;刘时杰 .低品位及难处理贵金属物料的富集活化溶解方法[P].中国,CN1136595,1996-03-06. |
[45] | 吕顺丰;张秀英;吴秀香 等.一种三氯化铑的制备方法[P].中国,CN101100756A,2008-01-09. |
[46] | HE Xiaotang,WANG Huan,WU Xilong,LI Yong,ZHAO Yu,HAN Shouli,LI Kun,GUO Junmei.Study on the Recovery of Rhodium from Spent Organic Rhodium Catalysts of Acetic Acid Industry Using Pyrometallurgical Process[J].贵金属,2012(z1):24-27. |
[47] | 文永忠;潘丽娟;张之翔 等.一种三氯化铑的制备方法[P].中国,CN101503220A,2009-08-12. |
[48] | Liu Jun;Yu Haibin;Li Jixia et al.Technical progress on recovery and preparation of rhodium trichloride from the spent rhodium catalyst waste[J].Chemical Industry and Engineering Progress,2010,29(1):566-572. |
[49] | 张邦安,李富荣.废铱坩埚提纯铱工艺研究[J].中国资源综合利用,2006(10):5-9. |
[50] | 贺小塘,韩守礼,吴喜龙,王欢.从铂-铱合金废料中回收铂铱的新工艺[J].贵金属,2010(03):56-59. |
[51] | 贺小塘,韩守礼,吴喜龙,王欢.从铂-铱合金废料中回收铂铱的新工艺[J].贵金属,2010(03):56-59. |
[52] | WU Xiaofeng,DONG Haigang,TONG Weifeng,ZHAO Jiachun,ZENG Rui.High Efficient Enrichment and Activated Dissolution of Refractory Low Grade Rh-containing Material[J].贵金属,2012(z1):40-44. |
[53] | 郭廷杰.铂族金属的气相处理回收法[J].资源再生,2007(06):30-32. |
[54] | Kayanuma Y;Okabe T H;Mitsuda Y et al.New recovery process for rhodium using metal vapor[J].Journal of Alloys and Compounds,2004,365(1/2):212-220. |
[55] | Yoshihiro Kayanuma;Toru H. Okabe;Masafumi Maeda .Metal Vapor Treatment for Enhancing the Dissolution of Platinum Group Metals from Automotive Catalyst Scrap[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2004(5):817-824. |
[56] | Jung-Chul Park .Purification and Recovery of Rhodium Metal by the Formation of Intermetallic Compounds[J].Bulletin of the Korean Chemical Society,2008(9):1787-1789. |
[57] | 董海刚;王云华;范兴祥 等.一种贵金属物料溶解的方法[P].中国,CN102212704A,2011-10-12. |
[58] | 余建明 .关于铑铱富集和分离[J].贵金属,1993,14(2):59-65. |
[59] | 杨春吉.从废铑催化剂中提取铑粉[J].贵金属,2002(04):6-8. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%