Antibacterial Property of Cu Modified Stainless Steel by Plasma Surface Alloying

钢铁研究学报(英文版), 2012, 19(4): 75-79.

Antibacterial Property of Cu Modified Stainless Steel by Plasma Surface Alloying

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

2.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

3.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

4.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

5.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

6.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

基金项目: Graduate Innovation Project of Shanxi Province of China(20103024) Item Sponsored by National Natural Science Foundation of China(51171125) Science and Technology Key Project of Shanxi Province of China(20110321051) Research Project Supported by Shanxi Scholarship Council of China(2011-038)

关键词：抗菌性能 , 不锈钢 , 金黄色葡萄球菌 , 离子渗 , 表面改性层 , X射线光电子能谱 , 大肠杆菌 , 修饰

Antibacterial Property of Cu Modified Stainless Steel by Plasma Surface Alloying

ZHANG Xiang-yu ^1, , HUANG Xiao-bo ^2, , JIANG Li ^3, , MA Yong ^4, , FAN Ai-lan ^5, , TANG Bin ^6,

1.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

2.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

3.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

4.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

5.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

6.Research Institute of Surface Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China

Keywords： plasma alloying , Cu , antimicrobial , AISI 304 stainless steel ,

Stainless steel（SS） is not recommended to be used in hospital environments for work surfaces and door furniture due to the lack of antibacterial properties.To this end,a novel SS surface modified layer with both a quick bacterial killing rate and relatively thick has been obtained by plasma surface alloying with Cu.The microstructure,elements distribution and phase identification were analyzed by SEM,GDS,XRD and XPS.A spread plate method was adopted for evaluation of antibacterial property of specimens against Escherichia coli（E.coli） and Staphylococcus aureus（S.aureus）.The experimental results demonstrate that the surface modified layer with the thickness of about 26 μm is uniform and dense.The layer is mainly composed of a mixture of pure Cu,expanded austenite phase and a few Fe3O4 phase.The Cu modified layer exhibits excellent antibacterial effects against E.coli and S.aureus within 1 h.No viable E.coli and S.aureus was found after 3 h（100% killed）.The modified layer is relatively thick,hence it is expected that the Cu modified SS will have a durable antibacterial function

参考文献

[1]	Noyce JO;Michels H;Keevil CW .Potential use of copper surfaces to reduce survival of epidemic meticillin-resistant Staphylococcus aureus in the healthcare environment.[J].The Journal of hospital infection,2006(3):289-297.
[2]	Mehtar S;Wiid I;Todorov SD .The antimicrobial activity of copper and copper alloys against nosocomial pathogens and Mycobacterium tuberculosis isolated from healthcare facilities in the Western Cape: an in-vitro study.[J].The Journal of hospital infection,2008(1):45-51.
[3]	Hong IT;Koo CH .Antibacterial properties, corrosion resistance and mechanical properties of Cu-modified SUS 304 stainless steel[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):213-222.
[4]	Z.X.Zhang;G. Lin;L.Z.Jiang;Z.Xu .Beneficial Effects Of Nitrogen On Austenite Antibacterial Stainless Steels[J].Materials Chemistry and Physics,2008(2/3):238-243.
[5]	Soloviev, M.;Gedanken, A. .Coating a stainless steel plate with silver nanoparticles by the sonochemical method[J].Ultrasonics sonochemistry,2011(1):356-362.
[6]	Wan YZ;Raman S;He F;Huang Y .Surface modification of medical metals by ion implantation of silver and copper[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2007(9):1114-1118.
[7]	Dan ZG;Ni HW;Xu BF;Xiong J;Xiong PY .Microstructure and antibacterial properties of AISI 420 stainless steel implanted by copper ions[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1/2):93-100.
[8]	Tian XB;Wang ZM;Yang SQ;Luo ZJ;Fu RKY;Chu PK .Antibacterial copper-containing titanium nitride films produced by dual magnetron sputtering[J].Surface & Coatings Technology,2007(19/20):8606-8609.
[9]	Kuo YC;Lee JW;Wang CJ;Chang YJ .The effect of Cu content on the microstructures, mechanical and antibacterial properties of Cr-Cu-N nanocomposite coatings deposited by pulsed DC reactive magnetron sputtering[J].Surface & Coatings Technology,2007(4/7):854-860.
[10]	Xu Z;Liu X;Zhang P et al.Double Glow Plasma Surface Alloying and Plasma Nitriding[J].Surface and Coatings Technology,2007,201(9/10/11):4822.
[11]	Xu J;Tao J;Chen ZY;Zhu WH;Jiang SY;Xu Z .Preparation of Ni-Cu-Mo-Cr film deposited on AZ31 magnesium alloy by double glow sputtering with Cu interlayer[J].Surface & Coatings Technology,2007(3):577-582.
[12]	FAN Ailan,QIN Lin,TIAN Linhai,TANG Bin.Corrosion Resistance of Molybdenum Nitride Modified Ti6Al4V Alloy in HCl Solution[J].武汉理工大学学报（材料科学版）（英文版）,2008(03):358-361.
[13]	Tang B.;Wu PQ.;Li XY.;Fan AL.;Xu Z.;Celis JP. .Tribological behavior of plasma Mo-N surface modified Ti-6Al-4V alloy[J].Surface & Coatings Technology,2004(2/3):333-339.
[14]	Akhavan, O.;Ghaderi, E. .Cu and CuO nanoparticles immobilized by silica thin films as antibacterial materials and photocatalysts[J].Surface & Coatings Technology,2010(1):219-223.
[15]	Pardo A;Merino MC;Coy AE;Arrabal R;Viejo F;M'hich A .Corrosion behaviour of AISI 304 stainless steel with Cu coatings in H2SO4[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(23):9164-9176.
[16]	Wei Zhang;Yi-He Zhang;Jun-Hui Ji .Antimicrobial properties of copper plasma-modified polyethylene[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(21):7441-7445.
[17]	Sudha VB;Singh KO;Prasad SR .Killing of enteric bacteria in drinking water by a copper device for use in the home: laboratory evidence.[J].Transactions of the Royal Society of Tropical Medicine and Hygiene,2009(8):819-822.
[18]	J. O. Noyce;H. Michels;C. W. Keevil .Inactivation of Influenza A Virus on Copper versus Stainless Steel Surfaces[J].Applied and Environmental Microbiology,2007(8):2748-2750.
[19]	Kyung-Hwan Cho;Jong-Eun Park;Tetsuya Osaka;Soo-Gil Park .The study of antimicrobial activity and preservative effects of nanosilver ingredient[J].Electrochimica Acta,2005(5):956-960.
[20]	Kumar VS;Nagaraja BM;Shashikala V;Padmasri AH;Madhavendra SS;Raju BD;Rao KSR .Highly efficient Ag/C catalyst prepared by electro-chemical deposition method in controlling microorganisms in water[J].Journal of molecular catalysis, A. Chemical,2004(1/2):313-319.
[21]	Feng Q.L.;Wu J. .A mechanistic study of the antibacterial effect of silver ions on Escherichia coli and Staphylococcus aureus[J].Journal of biomedical materials research, Part B. Applied biomaterials,2000(4):662-668.
[22]	Cioffi N;Ditaranto N;Torsi L et al.Analytical Characterization of Bioactive Fluoropolymer Ultra-Thin Coatings Modified by Copper Nanoparticles[J].Analytical Biochemistry,2005,381(03):607.
[23]	Lin YSE.;Stout JE.;McCartney CA.;Yu VL.;Vidic RD. .Inactivation of Mycobacterium avium by copper and silver ions[J].Water research: A journal of the international water association,1998(7):1997-2000.

上一张下一张

计量

下载量()
访问量()

作者相关

在本站搜索
在百度学术搜索
在万方数据库搜索
在CNKI搜索

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

Antibacterial Property of Cu Modified Stainless Steel by Plasma Surface Alloying

Antibacterial Property of Cu Modified Stainless Steel by Plasma Surface Alloying

参考文献