欢迎登录材料期刊网

材料期刊网

高级检索

制备了掺杂浓度分别为2.0mol%的Tm3+及Ho3+单掺的两种锗酸盐玻璃. 根据McCumber理论计算了Tm3+离子能级3H6←→3F4(1.8 μm)跃迁和Ho3+离子能级5I8←→5I7(2.0 μm)跃迁的吸收截面和受激发射截面. 同时,根据所获得的吸收截面、发射截面以及掺杂离子的浓度分别获得了Tm3+离子和Ho3+离子在两种不同锗酸盐玻璃基质中的增益截面函数, 从该函数可反映出材料的粒子数反转特性. 对于Tm3+离子掺杂的锗酸盐玻璃,其吸收截面、发射截面和增益截面的最大值大于在氟锆酸盐、氟化物和氟氧化物玻璃中; 对于Ho3+掺杂的锗酸盐玻璃,其吸收截面、发射截面和增益截面的最大值也大于在氟锆铝酸盐玻璃. 因此,Tm3+和Ho3+掺杂的两种锗酸盐玻璃在~1.8和~2.0 μm波段的中红外激光器中将有潜在的应用前景.

参考文献

[1] Yuen H. Tsang;Daniel J. Coleman;Terence A. King .High power 1.9 μm Tm~(3+)-silica fibre laser pumped at 1.09 μm by a Yb~(3+)-silica fibre laser[J].Optics Communications: A Journal Devoted to the Rapid Publication of Short Contributions in the Field of Optics and Interaction of Light with Matter,2004(1/6):357-364.
[2] 张云军,王月珠,鞠有伦,姚宝权.掺Tm3+光纤激光器的进展[J].激光与光电子学进展,2005(06):34-38,43.
[3] Wang Dawei,Huang Shihua,You Fangtian,Qi Shiqun,Zhang Guobin.Temperature-Dependent Emission of Pr3+-Doped LaB3O6 under Vacuum Ultraviolet Excitation[J].稀土学报(英文版),2007(02):139-142.
[4] Hayashi H.;Hanada T.;Tanabe S. .1.4 mu m band emission properties of Tm3+ ions in transparent glass ceramics containing PbF2 nanocrystals for S-band amplifier[J].Journal of Applied Physics,2001(2):1041-1045.
[5] 孙江亭,张家骅,陈宝玖,吕少哲,任新光,王笑军.新型掺铒钆硼硅酸盐玻璃的制备和光学性质的研究[J].中国稀土学报,2004(06):832-836.
[6] 夏海平,章践立,王金浩,张约品.Er3+单掺与Er3+/Yb3+双掺杂Bi2O3-GeO2-B2O3-ZnO玻璃的光谱研究[J].中国稀土学报,2005(05):524-528.
[7] Jayasankar C K;Devi A R .Optical properties of Tm3+ ions in lithium borate glasses[J].Optical Materials,1996,6:185.
[8] 祁长鸿.氟锆酸盐玻璃中Ho3+离子的光谱特性[J].光学学报,1994(06):583.
[9] Stoneman R C;Esterowitz L .Efficient,broadly tunable,laser-pumped Tm:YAG and Tm:YSGG CW lasers[J].OPTICS LETTERS,1990,15(09):486.
[10] Wu J F;Jiang S B;Luo T;Geng J H Peyghambarian N Barnes N P .Efficient thulium-doped ~2 μm germanate fiber laser[J].IEEE Photonics Technology Letters,2006,18(02):334.
[11] Feng L;Wang J;Tang Q;Liang LF;Liang HB;Su Q .Optical properties of Ho3+-doped novel oxyfluoride glasses[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2007(2):187-194.
[12] 何琛娟,陈晓波,N.Sawanobori,孙寅官,陈鸾.Ho3+在氟氧化物玻璃陶瓷中的光谱性质[J].量子电子学报,2002(02):109-114.
[13] Lande D;Orloy S S;Akella A;Inoue K .Spectral inversion with no wavelength shift based on four-wave mixing with orthogonal pump beams[J].Optics Letters,1997,22:1722.
[14] Walsh BM;Barnes NP;Reichle DJ;Jiang SB .Optical properties of Tm3+ ions in alkali germanate glass[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2006(50/51):5344-5352.
[15] Shi DM;Zhang QY;Yang GF;Jiang ZH .Spectroscopic properties and energy transfer in Ga2O3-Bi2O3-PbO-GeO2 glasses codoped with Tm3+ and Ho3+[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2007(16/17):1508-1514.
[16] McCumber D E .Theory of phonon-terminated optical masers[J].Physical Review,1964,134:A299.
[17] Zou X L;Izumitani;Teturo .Spectroscopic properties and mechanisms of excited state absorption and energy transfer upconversion for Er3+-doped glasses[J].Journal of Non-Crystalline Solids,1993,162:68.
[18] Doualan J L;Girard S;Haquin H;Adam J L,Montagne J .Spectroscopic properties and laser emission of Tm doped ZBLAN glass at 1.8 μm[J].Optical Materials,2003,24(02):563.
[19] Zou X;Toratani H .Spectroscopic properties and energy transfers in Tm3+ singly and Tm3+/Ho3+ doubly-doped glasses[J].Journal of Non-Crystalline Solids,1996,195:113.
[20] 李毛和.氟化物玻璃中Tm3+离子敏化Ho3+离子的红外发光性质[J].光学学报,1998(10):1454.
[21] Tikhomirov V K;Mendez-Ramos J;Rodriguez V D;Furniss D,Seddon A B.Gain cross-sections of transparent oxyfluoride glass-ceramics single-doped with Ho3+ (at 2.0 μm) and Tm3+ (at 1.8 μm)[J].Journal of Alloys and Compounds,2006
[22] Payne S.A.;Chase L.L. .Infrared cross-section measurements for crystals doped with Er/sup 3+/, Tm/sup 3+/, and Ho/sup 3+/[J].IEEE Journal of Quantum Electronics: A Publication of the IEEE Quantum Electronics and Applications Society,1992(11):2619-2630.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%