对LaCo13基金属间化合物在磁致冷材料和储氢材料领域中的应用进行了综述, 总结了该系化合物的成相规律、替换元素对相稳定性的影响, 讨论了近期的研究进展及存在的问题. 作为磁致冷材料应用时, LaCo13基金属间化合物在室温具有巨大磁熵变, 而作为储氢合金时该系化合物表现出优异的高温电化学容量. 虽然在磁致冷和储氢材料领域尚未对LaCo13基金属间化合物进行实用开发, 但作为新型绿色能源材料已经展示出良好的应用前景.
参考文献
[1] | Buschow K H J .Intermetallic compounds of rare-earth and 3d transition metals[J].Reports on Progress in Physics,1977,40:1179. |
[2] | Buschow K H J .New developments in hard magnetic materials[J].Reports on Progress in Physics,1991,54:1123. |
[3] | Palstra T T M;Mydosh J A;Nieuwenhuys G J;van der KRAAN A M Buchow K H J .Study of the critical behaviour of the magnetization and electrical resistivity in cubic La(Fe,Si)13 compounds[J].Journal of Magnetism and Magnetic Materials,1983,36:290. |
[4] | Huang M.Q.;Zheng Y. .Magnetic properties and structure of nitrogenated La(Co/sub 1-x/Fe/sub x/)/sub 13/ compounds (x=0-0.4)[J].IEEE Transactions on Magnetics,1992(5):2859-2861. |
[5] | Buschow K H J;Velge W A J J .Phase relations and intermetallic compounds in the lanthanum-cobalt system[J].Journal of the Less-Common Metals,1967,13:11. |
[6] | Ray A E.A review of the binary rare earth-cobalt alloy systems[J].Cobalt,1974(01) |
[7] | Ido H;Sohn J G;Pourarian F;Cheng S F Wallace W E .Magnetic properties of LaCo13-based systems[J].Journal of Applied Physics,1990,67:4978. |
[8] | Palstra T T M;Nieuwenhuys G J;Mydosh J A;Buschow K H J .Micromagnetic,ferromagnetic,and antiferromagnetic transitions in La(FexAl1-x)13 intermetallic compounds[J].Physical Review B,1985,31:4622. |
[9] | 鄢晓华 .富过渡族元素-稀土化合物的晶体结构与磁性能研究[D].北京:中国科学院物理研究所,1993. |
[10] | 赵彦明 .Nd-Co-Si三元系相关系及稀土-富过渡族元素化合物晶体结构与磁性能研究[D].中国科学院物理研究所,1996. |
[11] | Weitzer F;Hiebl K;Grin Yu N;Rogl P Nol H .Magnetism and structure chemistry of ReCo13-xGax alloys (Re=La,Ce,Pr,Nd,and mischmetal MM)[J].Journal of Applied Physics,1990,68:3504. |
[12] | Rao G H;Liang J K;Zhang Y L;Cheng X R Tang W H Dong C .Phase relation,crystal structure,and magnetic properties of La-Co-Si alloys[J].Physical Review B,1995,51:60. |
[13] | 唐为华 .La-Fe-M三元系相关系以及LaFe13-xMx(M=Al,Si)的晶体结构与磁性[D].北京:中国科学院物理研究所 |
[14] | 郭永权 .La-Co-Al三元系相关系及一些LaCo<,13> 基金属间化合物的晶体结构和磁性[D].中国科学院物理研究所,1996. |
[15] | Contardi V;Zanicchi G;Marazza R;Ferro R .On some ternary La-Co-Zn alloys[J].Journal of the Less-Common Metals,1983,90:L25. |
[16] | Pearson W B.The Crystal Chemistry and Physics of Metals and Alloys[M].New York:Wiley-Interscience,1972:75. |
[17] | Nyman H;Andersson S .The stella quadrangula as a structure building unit[J].Acta Crystallographica,1979,A35:934. |
[18] | Min B I;Youn S J .Electronic structure of LaCo13[J].Physical Review B,1994,49:9697. |
[19] | Palstra T T M;Nieuwenhuys G J;Mydosh J A;Buschow K H J .Magnetic properties of cubic La(FexAl1-x)13 intermetallic compounds[J].Journal of Applied Physics,1984,55:2367. |
[20] | Mushnikov N V;Novikov S I;Andreev A V;Gaviko V S Lapina T P Bartashevich M I Maikov V V Ermakov A E .Magnetostriction of LaCo13-based alloys[J].Journal of Alloys and Compounds,1992,187:285. |
[21] | Liang Jingmei;Rao Guanghui;Tang Weihua;Zhang Yuling Cheng Xiangrong Dong Cheng Zhang Fulin .Subsolidus phase relations of the La-Co-Cu system and crystal structure of LaCoCu12[J].Journal of Alloys and Compounds,1995,223:45. |
[22] | Chang H.;Chen NX.;Liang JK.;Rao GG. .Theoretical study of phase forming of NaZn13-type rare-earth intermetallics[J].Journal of Physics. Condensed Matter,2003(2):109-120. |
[23] | Guo Yongquan;Liang Jingkui;Zhang Xinhui;Zhao Yanming Tang Weihua Rao Guanghui .Crystal structure and magnetic properties of LaCo13-xAlx compounds[J].Physica Status Solidi A,1997,159:297. |
[24] | Kittel C.Introduction to Solid State Physics[M].New York:John Wiley and Sons,Inc,1986:76. |
[25] | Wu Jianmin;Li Feng;Cui Liya;Tai Lichi .The magnetic entropy change properties of La1-zRz(Fe1-x-yCoxAly)13 Compounds[J].Journal of Applied Physics,1996,79:982. |
[26] | Hu Fengxia;Shen Baogen;Sun Jirong;Cheng Zhaohua .Large magnetic entropy change in La(Fe,Co)11.83Al1 17[J].Physical Review B,2001,64:012409-012401. |
[27] | Hu Fengxia;Shen Baogen;Sun Jirong;Cheng Zhaohua, Rao Guanghui, Zhang Xixiang .Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1 6[J].Applied Physics Letters,2001,78:3675. |
[28] | Hu Fengxia;Shen Baogen;Sun Jirong;Cheng Zhaohua, Zhang Xixiang .Magnetic entropy change in La(Fe0.98Co0 02)11 7Al1 3[J].Journal of Physics:Condensed Matter,2000,12:L691. |
[29] | Wang F;Chen Y F;Wang G J;Sun J R, Shen B G .The large magnetic entropy change and the change in the magnetic ground state of the antiferromagnetic compound LaFe11.5Al1 5 caused by carbonization[J].Journal of Physics:Condensed Matter,2004,16:2103. |
[30] | X. X. Zhang;G. H. Wen;F. W. Wang .Magnetic entropy change in Fe-based compound LaFe_(10.6)Si_(2.4)[J].Applied physics letters,2000(19):3072-3074. |
[31] | 陈远富,王芳,王光军,孙继荣,沈保根.LaFe11.6Si1.4C0.5间隙化合物的磁性、磁相变和磁熵变[J].中国稀土学报,2003(04):478-480. |
[32] | 陈远富,王芳,沈保根,胡凤霞,成昭华,王光军,孙继荣.Large magnetic entropy change near room temperature in the LaFe11.5Si1.5H1.3 interstitial compound[J].中国物理(英文版),2002(07):741-744. |
[33] | 陈远富;沈保根;王芳;胡凤霞 .具有大磁熵变的稀土-铁基化合物磁致冷材料及其制备方法[P].CN 03121051.1 |
[34] | Fujita A.;Fujieda S.;Hasegawa Y.;Fukamichi K. .Itinerant-electron metamagnetic transition and large magnetocaloric effects in La(FexSi1-x)(13) compounds and their hydrides - art. no. 104416[J].Physical review, B. Condensed matter and materials physics,2003(10):4416-0. |
[35] | 吴卫,冯再,郭立君.关于室温磁制冷材料的评价[J].中国稀土学报,2005(01):48-52. |
[36] | 张宏伟,孙继荣,胡凤霞,王芳,沈保根.La-Fe基NaZn13型化合物的磁场诱导熵变研究[J].中国稀土学报,2005(04):385-393. |
[37] | Wu Jianmin;Li Rong;Su Hang;Wang Xinlin .Structure and electrochemical properties of LaCo13-xNix compounds[J].Journal of Alloys and Compounds,1999,289:251. |
[38] | 李蓉 .LaCo<,13-x>M<,x>系和高容量AB<,5>型储氢合金的储氢特性研究[D].钢铁研究总院,2007. |
[39] | Irisawa K;Fujita A;Fukamichi K;Yamazaki Y, Iijima Y, Matsubara E .Change in the magnetic state of antiferromagnetic La(Fe0.88Al0 12)13 by hydrogenation[J].Journal of Alloys and Compounds,2001,316:70. |
[40] | Wu Jianmin;Li Rong;Wang Xinlin;Zhou Shaoxiong .Structure and electrochemical properties of LaCo11-xFexNi2 compounds[J].Journal of Alloys and Compounds,2003,359:221. |
[41] | Li Rong;Wu Jianmin;Zhou Shaoxiong .Structure and electrochemical properties of LaCo11-x-yNixMy (M=Fe,Mn and Al)compounds[J].Journal of Alloys and Compounds,2006,422:288. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%