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  4. 高折射率光学树脂的结构设计

材料导报, 2010, 24(13): 118-122.

高折射率光学树脂的结构设计

李志斌 1, , 王跃川 2,

1.四川大学高分子科学与工程学院高分子材料工程国家重点实验室,成都,610065

2.四川大学高分子科学与工程学院高分子材料工程国家重点实验室,成都,610065

基金项目:   国家自然科学基金(20974067)  

关键词： 光学树脂 , 光学材料 , 光学性能 , 折射率 , 色散

Structure Design of High Refractive Index Optical Resins

从分子设计的基本原理入手,总结了分子结构时树脂折射率和色散的影响,指出含有脂环、硫、溴、碘、磷、砜基及部分重金属元素的树脂既具有较高的折射率又具有较低的色散,并按树脂结构与官能团特征对高折射率材料进行分类,分析了各类树脂的优缺点.

参考文献

[1] 郑武城;韩亚娟.新型光学塑料--EA光学塑料[J].光学技术,1992(05):36.
[2] 徐炽焕 .聚碳酸酯及光学塑料的应用开发[J].江苏化工,2000,28(05):26.
[3] 吴秀丽 .光学玻璃和光学塑料的种类及特性[J].光机电信息,1998,15(09):4.
[4] Matsuda T.;Yoshida M.;Yamamoto T.;Takaya T.;Funae Y. .OPTICAL MATERIAL HAVING HIGH REFRACTIVE INDEX, LOW SPECIFIC GRAVITY, AND EXCELLENT IMPACT RESISTANCE PREPARED BY UNSATURATED NITRILE-POLYFUNCTIONAL METHACRYLATE-STYRENIC MONOMER COPOLYMERIZATION[J].Journal of Applied Polymer Science,1997(11):2247-2255.
[5] Morford R;Mercado R;Planje C et al.High refractive in-dex photocurable resins[J].PROCEEDINGS OF THE SPIE,2005,5724:34.
[6] 黎新章.CR39光学树脂及其制品[J].应用化学,1989(04):53.
[7] 李悦生;翁志学;潘祖仁.N-取代马来酰亚胺改性的MMA树脂[J].化工新型材料,1994(05):20.
[8] 关成 .新型透明无机/有机聚合物纳米复合材料的制备[D].长春:吉林大学,2007.
[9] MATSUDA TATSUHITO;FUNAE YASUAKI .Optical Material of High Refractive Index Resin Composed of Sulfur-Containing Aliphatic and Alicyclic Methacrylates[J].Journal of Applied Polymer Science,2000(1):45-49.
[10] Nagata T;Okazaki T;Miura T .Lens comprising a resin having a large refractive index and process for preparing the lens[P].EP,0351073,1990-01-17.
[11] Gao CY.;Shen JC.;Yang B. .Study on syntheses and properties of 2,2 '-mercaptoethylsulfide dimethacrylate transparent homo- and copolymer resins having high refractive index[J].Journal of Applied Polymer Science,2000(12):1474-1479.
[12] Hoyle CE;Lee TY;Roper T .Thiol-enes: Chemistry of the past with promise for the future[J].Journal of Polymer Science, Part A. Polymer Chemistry,2004(21):5301-5338.
[13] Nakayarna Y;Fukai T;Nagai Y .Aromatic polysulfide sul-fone resin[P].Japan,07252359,1995-03-10.
[14] Moghaddam FM;Bardajee GR;Oskui AA .A mild and chemoselective dithioacetalization of aldehydes in the presence of anhydrous copper (II) sulfate[J].Phosphorus, Sulfur, and Silicon and the Related Elements,2006(6):1445-1450.
[15] Neeta Srivastava;Swapan K.Dasgupta;Bimal K.Banik .A remarkable bismuth nitrate-catalyzed protection of carbonyl compounds[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2003(6):1191-1193.
[16] Sinananwanich W;Ueda M .Synthesis of a hyperbranched degree of branching[J].Journal of Polymer Science, Part A. Polymer Chemistry,2008(8):2689-2700.
[17] Cossar B C;Fournier J O;Fields D L et al.Preparation of thiols[J].Journal of Organic Chemistry,1962,27(01):93.
[18] Verma RP;Kapur S;Barberena O;Shusterman A;Hansch CH;Selassie CD .Synthesis, cytotoxicity, and QSAR analysis of x-thiophenols in rapidly dividing cells.[J].Chemical research in toxicology,2003(3):276-284.
[19] de Boer B.;Meng H.;Perepichka DF.;Zheng J.;Frank MM.;Chabal YJ.;Bao ZN. .Synthesis and characterization of conjugated mono- and dithiol oligomers and characterization of their self-assembled monolayers [Review][J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(10):4272-4284.
[20] Miyazaki K .The thermal rearrangement of thionocarba-ma-tes to thiolcarbamates[J].Tetrahedron Letters,1968,9(23):2793.
[21] haw J E .Preparation of thiophenols from unactivated aryl chlorides and sodium alkanethiolates in N-methyl-2-pyrroli-done[J].Journal of Organic Chemistry,1991,56(11):3728.
[22] Martin D J;Greco C C .Thiol synthesis[J].Journal of Organic Chemistry,1968,33(03):1275.
[23] Patai S.The chemistry of the thiol group[M].London:John Wiely & Sons,Ltd,1974:1.
[24] Oae S.Organic chemistry of sulfur[M].New York and London:Plenum Press,1977:119.
[25] MATSUDA TATSUHITO;FUNAE YASUAKI .Optical Material of High Refractive Index Resin Composed of Sulfur-Containing Aromatic Methacrylates[J].Journal of Applied Polymer Science,2000(1):50-54.
[26] Mitsubishi T Y;Mitsubishi W F .Diethylenically unsatura-ted monomer and use thereof[P].EP,0424144 A1,1991-04-24.
[27] Keiji T;Tatsuya O .Resin composition for optical material[P].Japan,03265613,1991-11-26.
[28] Tadanori F;Genzaburo N .Sulfur-containing aromatic poly-ester resin[P].Japan,02245030,1990-09-28.
[29] Koju O;Chitohshi S;Mamoru T et al.Durable polysulfide composition for optical material[P].EP,0742244 A2,1996-11-13.
[30] Yoshinibu K;Katsuyoshi S;Masao I et al.Polysulfide-based resin and lens consisting of the same resin[P].Japan,0384031,1991-04-09.
[31] 杨淑丽;阎恒梅.塑料透镜应用技术及其发展动向[J].光学技术,1990(01):34.
[32] 杨柏;吕长利;沈家骢.高性能聚合物光学材料[M].北京:化学工业出版社,2005:109.
[33] Toshiyuki S;Katsuyoshi S;Masso I .High surface hardness transparent resin and polymerizahle monomer[P].EP,0385456A2,1990-09-05.
[34] 王德中.环氧树脂生产与应用[M].北京:化学工业出版社,2001:4.
[35] Su WF.;Fu YC.;Pan WP. .Thermal properties of high refractive index epoxy resin system[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2002(special issue si):385-389.
[36] Eicher T;Siegfried H;Speicher A.The chemistry of hete-rocycles[M].Germany:Wiley-VCH GmbH & Co KgaA,2003:24.
[37] Zhanchen Cui;Changli Lu;Bai Yang;Jiacong Shen;xiaoping Su;Hai Yang .The research on sytheses and properties of novel epoxy/poymercaptan[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(26):10095-10100.
[38] Lu CL.;Cui ZC.;Wang YX.;Yang B.;Shen JC. .Studies on syntheses and properties of episulfide-type optical resins with high refractive index[J].Journal of Applied Polymer Science,2003(9):2426-2430.
[39] Katsumasa Y;Kenichi W;Naoko S .isulfide compound and its compound[P].Japan,11012273,1999-01-19.
[40] Akikazu A;Nobuyuki U;Motoharu T et al.Isulfide com-pound[P].EP,0785194 A1,1997-07-23.
[41] 大久保毅;高松健 .硫醇化合物,制备该化合物的方法和含该化合物的光学产品[P].中国,1421444 A,2003-06-04.
[42] 金村芳信;笹川勝好;今井雅夫 .一种巯基化合物的制备方法[P].中国,1043498 A,1990-07-04.
[43] Teruyuki N;Koju O;Tohru M .Lens comprising a resin having a large refractive index and process for praring the lens[P].EP,0351073 A2,1990-01-17.
[44] 高长有;沈家骢;张安震 .一种制备聚硫代氨基甲酸酯光学塑料的方法[P].中国,1405198 A,2003-03-26.
[45] Russell T P;Gugger H;Swalen J D .In-plane orientation of polyimide[J].Journal of Polymer Science Part B:Polymer Physics,1983,21(09):1745.
[46] Liu JG;Nakamura Y;Shibasaki Y;Ando S;Ueda M .Synthesis and characterization of highly refractive polyimides from 4,4 '-thiobis[(p-phenylenesulfanyl)aniline] and various aromatic tetracarboxylic dianhydrides[J].Journal of Polymer Science, Part A. Polymer Chemistry,2007(23):5606-5617.
[47] Liu JG;Nakamura Y;Shibasaki Y;Ando S;Ueda M .High refractive index polyimides derived from 2,7-bis(4-aminophenylenesulfanyl)thianthrene and aromatic dianhydrides[J].Macromolecules,2007(13):4614-4620.
[48] Jin-gang Liu;Yasuhiro Nakamura;Tomohito Ogura .Optically Transparent Sulfur-Containing Polyimide-TiO2 Nanocomposite Films with High Refractive Index and Negative Pattern Formation from Poly (amic acid)-TiO2 Nanocomposite Film[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(1):273-281.
[49] M.Hasegawa;K.Horie .Photophysics,photochemistry,and optical properties of polyimides[J].Progress in Polymer Science,2001(2):259-335.
[50] Yongbin Zhao;Qi Fu;Wenfang Shi;Feng Wang .Synthesis and characterization of ZnS/hyperbranched polyester nanocomposite and its optical properties[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(10):2853-2859.
[51] Zimmermann L;Weibel M;Caseri W et al.High refractive index films of polymer nanocomposites[J].Journal of Materials Research,1993,8(07):1742.
[52] Kypriandou L T;Ahhaus H J;Wyser Y et al.High re-fractive index materials of iron sulfides and poly (ethylene oxide)[J].Journal of Materials Research,1997,12(08):2198.
[53] Papadimitrakopoulos F;Wisniecki P;Bhagwagar D E .Me-chanically attrited silicon for high refractive index nanocom-posites[J].Chemistry of Materials,1997,9(12):2928.
[54] Lu CL.;Cui ZC.;Li Z.;Yang B.;Shen JC. .High refractive index thin films of ZnS/polythiourethane nanocomposites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(3):526-530.
[55] Lu CL.;Cui ZC.;Wang Y.;Li Z.;Guan C.;Yang B.;Shen JC. .Preparation and characterization of ZnS-polymer nanocomposite films with high refractive index[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(9):2189-2195.
[56] Ullah M H;Kim J H;Ha C S .Highly transparent o-PDA functionalized ZnS-polymer nanocomposite thin films with high refractive index[J].Materials Letters,2008,62(16):2249.
[57] Li YQ;Fu SY;Yang Y;Mai YW .Facile synthesis of highly transparent polymer nanocomposites by introduction of core-shell structured nanoparticles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(8):2637-2643.
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