介绍了原子转移自由基聚合法(ATRP)制备聚合物刷(平面刷、球形刷和分子刷)的研究进展及应用前景.聚合物刷子的奇异构象使其具有许多新奇的性质和潜在的应用前景.ATRP是制备具有可控结构的聚合物以及有机/无机杂化材料的一种较好的方法.通过ATRP制备聚合物刷,可以有效地改变聚合物刷的组成和聚合度,从而改变聚合物刷的表面性质,设计出具有新型结构及性能的材料.
参考文献
| [1] | ugALR;Cates M E;Afm S A et al.Theory of size distribution of associating polymer aggregates I[J].Spherical aggregates:J Chem Phys,1987,87:1824. |
| [2] | YangX;Shi J;Johnson S et al.Growth of ultrathin covalently attached polymer films: fniform thin films for chemical microsensors[J].Langmuir,1998,14:1505. |
| [3] | Husseman Marc;McNamara Molly;Mate Mathew;Mecerreyes David;Benoit Didier G.;Hedrick James L.;Mansky Paul;Huang E.;Russell Thomas P.;Hawker Craig J.;Malmstrom Eva E. .Controlled synthesis of polymer brushes by `living' free radical polymerization techniques[J].Macromolecules,1999(5):1424-1431. |
| [4] | ItoY;Park Y S;Imanishi Y .Visualization of critical hcontrolled gating of a porous membrane grafted with polyelectrolyte brushes[J].Journal of the American Chemical Society,1997,119:2739. |
| [5] | MinkoS;Sidorenko A;Stamm M et al.Influence of segmental swelling ratio of a symmetric block copolymer on the morphology of melt-mixed immiscible polymer blends[J].Macromolecules,1999,32:4562. |
| [6] | Ejaz M.;Ohno K.;Tsujii Y.;Fukuda T.;Yamamoto S. .Controlled graft polymerization of methyl methacrylate on silicon substrate by the combined use of the Langmuir-Blodgett and atom transfer radical polymerization techniques[J].Macromolecules,1998(17):5934-5936. |
| [7] | Pyun J.;Kowalewski T.;Matyjaszewski K. .Synthesis of polymer brushes using atom transfer radical polymerization [Review][J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2003(18):1043-1059. |
| [8] | Blomberg S.;Ostberg S.;Harth E.;Bosman AW.;Van Horn B.;Hawker CJ. .Production of crosslinked, hollow nanoparticles by surface-initiated living free-radical polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(9):1309-1320. |
| [9] | arner-KowollikC;Davis T P;Heuts J P A et al.Rafting down under: tales of missing radicals fancy architectures[J].J Polym Sci A Polym Chem,2003,41:365. |
| [10] | WangJS;Matyjaszewski K .Controlled/living radical polymerization, atom transfer radical polymerization in the presence of transition-metal complexes[J].Journal of the American Chemical Society,1995,117:5614. |
| [11] | Min K.;Hu JH.;Wang CC.;Elaissari A. .Surface modification of polystyrene latex particles via atom transfer radical polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(7):892-900. |
| [12] | Kotre T.;Nuyken O.;Weberskirch R. .ATRP of MMA in aqueous solution in the presence of an amphiphilic polymeric macroligand[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2002(15):871-876. |
| [13] | Hong SC.;Jia S.;Teodorescu M.;Kowalewski T.;Matyjaszewski K. Gottfried AC.;Brookhart M. .Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n-butyl acrylate)-graft-polyethylene through the combination of Pd-mediated living olefin polymerization and atom transfer radical polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(16):2736-2749. |
| [14] | Husemann M.;Benoit D.;Frommer KJ.;Mate CM.;Hinsberg WD. Hedrick JL.;Hawker CJ.;Morrison M. .Manipulation of surface properties by patterning of covalently bound polymer brushes[J].Journal of the American Chemical Society,2000(8):1844-1845. |
| [15] | Matyjaszewski Krzysztof;Miller Peter J. .Polymers at Interfaces: Using Atom Transfer Radical Polymerization in the Controlled Growth of Homopolymers and Block Copolymers from Silicon Surfaces in the Absence of Untethered Sacrificial Initiator[J].Macromolecules,1999(26):8716-8724. |
| [16] | PyunJ;Jia S;Kowalewski T et al.Synthesis of nanostructured organic/inorganic hybrid materials using controlled/living radical polymerization: spherical brushes core-shell colloids and block copolymer brushes[J].ACS Polymer Preprints,2002,43:328. |
| [17] | Savin DA.;Pyun J.;Patterson GD.;Kowalewski T.;Matyjaszewski K. .Synthesis and characterization of silica-graft-polystyrene hybrid nanoparticles: Effect of constraint on the glass-transition temperature of spherical polymer brushes[J].Journal of Polymer Science, Part B. Polymer Physics,2002(23):2667-2676. |
| [18] | PyunJ;Kowalewski T;Kowalewski T et al.Synthesis of well-defined block copolymers tethered to polysilsesquioxane nanoparticles and their nanoscale morphology on surfaces[J].Journal of the American Chemical Society,2001,123:9445. |
| [19] | Pyun J.;Jia SJ.;Kowalewski T.;Patterson GD.;Matyjaszewski K. .Synthesis and characterization of organic/inorganic hybrid nanoparticles: Kinetics of surface-initiated atom transfer radical polymerization and morphology of hybrid nanoparticle ultrathin films[J].Macromolecules,2003(14):5094-5104. |
| [20] | Kiriy A.;Gorodyska G.;Minko S.;Jaeger W.;Stepanek P.;Stamm M. .Cascade of coil-globule conformational transitions of single flexible polyelectrolyte molecules in poor solvent[J].Journal of the American Chemical Society,2002(45):13454-13462. |
| [21] | Djalali R.;Li SY.;Schmidt M. .Amphipolar core-shell cylindrical brushes as templates for the formation of gold clusters and nanowires[J].Macromolecules,2002(11):4282-4288. |
| [22] | ornerHG;Beers K;Matyjaszewski K .Synthesis of molecular brushes with block copolymer side chains using atom transfer radical polymerization[J].Macromolecules,2001,34:4375. |
| [23] | Borner HG.;Duran D.;Matyjaszewski K.;da Silva M.;Sheiko SS. .Synthesis of molecular brushes with gradient in grafting density by atom transfer polymerization[J].Macromolecules,2002(9):3387-3394. |
| [24] | Matyjaszewski K.;Qin SH.;Boyce JR.;Shirvanyants D.;Sheiko SS. .Effect of initiation conditions on the uniformity of three-arm star molecular brushes[J].Macromolecules,2003(6):1843-1849. |
| [25] | VeltenU;Tossati S;Shelden R A et al.Graft polymerization of styrene on mica: formation and behavior of molecular droplets and tin films[J].Langmuir,1999,15:6940. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%