介绍了一种新型的杂化材料--桥联聚倍半硅氧烷(Bridged polysilsesquioxanes,BPS),该材料由于结构上的特殊性而表现出许多优异的性能.阐述了桥联聚倍半硅氧烷的研究现状及结构特性,重点综述了该材料的制备方法及其在光电、催化、吸附等材料领域内的应用,在此基础上展望了今后的发展趋势.
参考文献
[1] | Douglas A. Loy;Kenneth J. Shea .Bridged Polysilsesquioxanes. Highly Porous Hybrid Organic-Inorganic Materials[J].Chemical Reviews,1995(5):1431-1442. |
[2] | Loy D A;Shea K J .A mechanistic investigation of gelation.The sol-gel polymerization of bridged silsesquioxane monomers[J].Accounts of Chemical Research,2001,34(09):707. |
[3] | Ronald H. Baney;Maki Itoh;Akihito Sakakibara;Toshio Suzuki .Silsesquioxanes[J].Chemical Reviews,1995(5):1409-1430. |
[4] | Shea K J;Loy D A .Bridged polysilsesquioxanes.Molecular-engineered hybrid organic-inorganic materials[J].CHEMISTRY OF MATERIALS,2001,13:3306. |
[5] | Loy D A;Shea K J;Russick E M .Preparation of arylbridged polysilsesquioxane aerogels[J].Materials Research Society Symposium Proceedings,1992,271:699. |
[6] | Liu J L;Yan B .Lanthanide (Eu~(3+),Tb~(3+[J].Journal of Physical Chemistry B,2008,112:10898. |
[7] | Lin NN;Li HR;Wang YG;Feng Y;Qin DS;Gan QY;Chen SD .Luminescent Triazine-Containing Bridged Polysilsesquioxanes Activated by Lanthanide Ions[J].European journal of inorganic chemistry,2008(30):4781-4785. |
[8] | Corriu R J P;Leclercq D .Recent developments of molecular chemistry for sol-gel processes[J].Angewandte Chemie International Edition in English,1995,5(13-14):1420. |
[9] | Cerveau G et al.Tailor-made silicon-oxygen compounds from molecules to materials[J].Chemical Communications,1996,295-303:273. |
[10] | Loy D A;Baugher B M;Beugher C R et al.Substituent ffects on the sol-gel chemistry of organotrialkoxysilanes[J].Chemistry of Materials,2000,12:3624. |
[11] | Sharp K G;Scherer G W .Interaction of formic acid with the silica gel network[J].Journal of Sol-Gel Science and Technology,1997,8:165. |
[12] | C. Y. Yuan;S. Dai;Y. Wei;Y. W. Chen-Yang .An ionic liquid solvent method to prepare bridged polysilsesquioxane aerogels[J].Polymer Preprints,2003(2):772-773. |
[13] | Khiterer M;Shea KJ .Spherical, monodisperse, functional bridged polysilsesquioxane nanoparticles[J].Nano letters,2007(9):2684-2687. |
[14] | Cerveau G.;Framery E.;Corriu RJP. .Sol-gel process-influence of ageing on the textural properties of organosilsesquioxane materials[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2001(3):713-717. |
[15] | Genevieáve Cerveau et al.Sol-gel process:Influence of the temperature on the textural properties of organosilsesquioxane materials[J].Journal of Materials Chemistry,2000,10:1617. |
[16] | Luo Yan;Yang Piaoping;Lin Jun .Synthesis and characterization of urea bridged hybrid periodic mesoporous organosilica materials[J].Microporous and Mesoporous Materials,2008,111:194. |
[17] | Cerveau G.;Dabiens B.;Corriu RJP. .Polysilsesquioxane materials containing a dienic unit: unexpected reactivity of the organic unit[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(5):1113-1120. |
[18] | Boury B.;Delord P.;Le Strat V.;Corriu RJP. .Structure of silica-based organic-inorganic hybrid xerogel[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2000(1/2):41-50. |
[19] | Loy D A;Carpenter J P et al.Intramolecular condensation reactions of α,ω-Bis (triethoxysil-yl) alkanes.Formation of cyclic disilsesquioxanes[J].Journal of the American Chemical Society,1996,118:8501. |
[20] | Boury B;Corriu R J P .Organisation and reactivity of silicon-based hybrid materials with various cross-linking levels[J].New Journal of Chemistry,2002,26:981. |
[21] | Ben F;Boury B;Corriu R J P .Long-range order in nonporous hybrid organic-inorganic silicon-based materials by sol-gel processing[J].Advanced Materials,2002,14(15):1081. |
[22] | Vergnes A et al.Auto-organisation in silica-based organicinorganic gels obtained by sol gel process[J].Journal of Sol-Gel Science and Technology,2003,26:621. |
[23] | Alauzun J;Besson E;Mehdi A;Reye C;Corriu RJP .Reversible covalent chemistry of CO2: An opportunity for nano-structured hybrid organic-inorganic materials[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(2):503-513. |
[24] | 杨东江,徐耀,张磊,翟尚儒,吴东,孙予罕.溶胶-凝胶法制备桥式聚倍半硅氧烷/SiO2光学防潮膜[J].化学学报,2005(15):1461-1464. |
[25] | 吴节莉,赵辉鹏,徐敏,陈群.超支化高分子桥联聚倍半硅氧烷复合物的NMR研究[J].波谱学杂志,2008(01):1-10. |
[26] | Yuen Siu-Ming et al.Morphological,electrical,and mechanical properties of multiwall carbon nanotube/poly-silsesquioxane composite[J].Journal of Applied Polymer Science,2008,109:2000. |
[27] | Dabrowski A et al.Bridged polysilsesquioxane xerogels functionalizated by amine-and thiol-groups:Synthesis,structure,adsorption properties[J].Adsorption-Journal of the International Adsorption Society,2005,11:501. |
[28] | Barczak M;Dabrowski A;Ryczkowski J;Pasieczna-Patkowska S .FT-IR/PAS studies of ethylene-bridged polysilses-quioxanes functionalized with different groups[J].The European physical journal: Special topics,2008(1):301-304. |
[29] | Yasuhiro Fujimoto;Masaru Heishi;Kazuyuki Kuroda;Atsushi Shimojima .Layered assembly of alkoxy-substituted bis(trichlorosilanes) containing various organic bridges via hydrolysis of Si-Cl groups[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(48):5151-5157. |
[30] | Liu Fengyi;Fu Lianshe;Wang Jun et al.Luminescent film with terbium-complex-bridged polysilsesquioxanes[J].New Journal of Chemistry,2003,27:233. |
[31] | Yuan CY;Chen SY;Tang JC;Yang HC;Chen-Yang YW .Physical and electrochemical properties of low molecular weight poly(ethylene glycol)-bridged polysilsesquioxane organic-inorganic composite electrolytes via sol-gel process[J].Journal of Applied Polymer Science,2007(4):2752-2758. |
[32] | Haehyun Nam;Bruno Boury;Soo Young Park .Anisotropic Polysilsesquioxanes with Fluorescent Organic Bridges:Transcription of Strong pi-pi Interactions of Organic Bridges to the Long-Range Ordering of Silsesquioxanes[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(24):5716-5721. |
[33] | Zhao L;Vaupel M;Loy DA;Shea KJ .Photoresponsive hybrid materials: Synthesis and characterization of coumarin-dimer-bridged polysilsesquioxanes[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(5):1870-1876. |
[34] | Khiterer M;Shea KJ .Spherical, monodisperse, functional bridged polysilsesquioxane nanoparticles[J].Nano letters,2007(9):2684-2687. |
[35] | Khiterer M;Loy DA;Cornelius CJ;Fujimoto CH;Small JH;McIntire TM;Shea KJ .Hybrid polyelectrolyte materials for fuel cell applications: Design, synthesis, and evaluation of proton-conducting bridged polysilsesquioxanes[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(16):3665-3673. |
[36] | B.P.Bandgar;S.P.Kasture;V.T.Kamble .Chemoselective acetylation of alcohols,amines,and thiols without catalyst and solvent[J].Synthetic Communications,2001(15):2255-2259. |
[37] | Shea K J;Small J H .Bridged polysilsesquioxanes xerogels[R].America:American Chemical Society,2004. |
[38] | Yonggang Yang;Miho Nakazawa .Formation of Helical Hybrid Silica Bundles[J].Chemistry of Materials,2004(20):3792-3793. |
[39] | Aliev A.;Ormsby B.;Sullivan AC.;Ou DL. .Porous silica and polysilsesquioxane with covalently linked phosphonates and phosphonic acids[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(12):2758-2764. |
[40] | Claude Chuit;Robert J. P. Corriu;Geraud Dubois;Catherine Reye .Hybrid organic-inorganic materials. Preparation and properties of dibenzo-18-crown-6 ether-bridged polysilsesquioxanes[J].Chemical communications,1999(8):723-724. |
[41] | Dai S.;Ju YH.;Gao HJ.;Lin JS.;Pennycook SJ.;Barnes CE. Xue ZL.;Burleigh MC. .Hierarchically imprinted sorbents for the separation of metal ions[J].Journal of the American Chemical Society,2000(5):992-993. |
[42] | Zub YL;Stolyarchuk NV;Melnyk IV;Chuiko AA;Dabrowski A;Barezak M .New adsorbents based on bridged polysilsesquioxanes containing 3-mercaptopropyl functional groups[J].Mendeleev Communications,2005(4):168-170. |
[43] | A. Dabrowski;M. Barczak;E. Robens;N.V. Stolyarchuk;G.R. Yurchenko;O.K. Matkovskii;Yu.L. Zub .Ethylene and phenylene bridged polysilsesquioxanes functionalized by amine and thiol groups as adsorbents of volatile organic compounds[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2007(13):5747-5751. |
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